Part No.: 19-0784-04
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand ULD庐 BP-300 Contact Insecticide Formula 1
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SECTION 5. FIRE FIGHTING MEASURES
Product Name: Prescription Treatment庐 brand ULD庐 BP-300 FIRE AND EXPLOSION
Contact Insecticide Formula 1 Flash Point (TCC): 191掳F
EPA Reg. No.: 499-450 Explodibility Limits in Air (% by volume):
Product Code(s): 02-4939 (12 x 24 oz) 02-4933-1 (1 x 2.5 gal) Lower (LEL) = NE Upper (UEL) = NE
02-4937 (12 x 34 oz) 02-4933 (2 x 2.5 gal) UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
Material can accumulate static charges which can cause an incendiary electrical dis-
02-4931 (4 x 1 gal) 02-4934 (1 x 55 gal)
charge. Liquid runoff to sewers may create fire/explosion hazard.
EPA Signal Word: CAUTION
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc. IN CASE OF FIRE
3568 Tree Court Industrial Blvd. Extinguisher Media: Foam, Dry Chemical, Water
St. Louis MO 63122-6682 Special Fire Fighting Procedures: Treat as an oil fire. Use water spray to cool fire
exposed surfaces and to protect personnel. Isolate 鈥渇uel鈥? supply from fire. Use foam, dry
chemical or water spray to extinguish fire. Avoid spraying water directly into storage con-
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS
tainers due to danger of boilover. This liquid is volatile and gives off invisible vapors.
COMPOSITION INFORMATION Either the liquid or vapor may settle in low areas or travel some distance along the ground
ACTIVE INGREDIENTS (19.0%) % CAS NO. or surface to ignition sources where they may ignite or explode.
Pyrethrins 3.0 8003-34-7
Piperonyl Butoxide, Technical 6.0 51-03-6
SECTION 6. ACCIDENTAL RELEASE MEASURES
n-Octyl bicycloheptene dicarboximide 10.0 113-48-4
IN CASE OF SPILL OR LEAK
OTHER INGREDIENTS* (81.0%) % CAS NO.
If container begins to leak (through puncture, etc.), eliminate all ignition sources and
Petroleum Distillate > 10.0 64742-47-8 absorb with oil-dry or similar inert material. Sweep or scrape up and containerize. Do not
*All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the OSHA let spilled or leaking material enter watercourse. May be toxic to aquatic life. This prod-
Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200. uct contains the Comprehensive Environmental Response, Compensation and Liability
Act (CERCLA) listed chemical Pyrethrins which has a reportable quantity (RQ) of 1 lb. A
EXPOSURE INFORMATION release of more than 4.2 gal of this product is reportable to the National Response Center
OSHA PEL ACGIH TLV (800-424-8802).
MATERIAL STEL TWA STEL TWA Emergency Telephone Number of Chemtrec: 800-424-9300 (for transportation spills)
Pyrethrins NE NE 10 mg/m鲁 5 mg/m鲁 PROTECTIVE EQUIPMENT
Piperonyl Butoxide, Technical NE NE NE NE Eyes: Use proper protection 鈥? safety glasses are recommended.
n-Octyl bicycloheptene NE NE NE NE Skin: Wear chemical-resistant gloves. (Good practice requires that gross amounts of any
dicarboximide chemical be removed from the skin as soon as practical, especially before eating
Petroleum Distillate* NE NE NE NE or smoking.)
* TWA recommended by ingredient supplier = 166 ppm. Inhalation: Use of a respirator may be appropriate when working with spills in enclosed
or confined spaces, or when prolonged exposure to product vapor or spray mist may
SECTION 3. HAZARDS IDENTIFICATION occur. When using a respirator, wear a NIOSH approved respirator with an organic vapor
(OV) cartridge or canister with any R, P or HE prefilter.
NOTES TO PHYSICIAN
WASTE DISPOSAL METHOD
Contains petroleum distillate - vomiting may cause aspiration pneumonia.
Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leak-
SIGNS/SYMPTOMS OF EXPOSURE ing containers to a local disposal company for biological treatment or incineration.
Direct contact with eyes can cause irritation. Prolonged or repeated contact of product with Review all local, state and federal regulations concerning health and pollution to deter-
skin may cause irritation. Product spray mist, fog or vapor may cause irritation to nose, mine approved disposal procedures. NEVER PLACE WASTES DOWN ANY INDOOR OR
throat and lungs. If taken internally, aspiration of liquid product may cause pneumonitis. OUTDOOR DRAIN OR SEWER.
ROUTES OF ENTRY
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
SECTION 7. HANDLING AND STORAGE
HAZARDOUS DECOMPOSITION PRODUCTS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
When exposed to fire, produces normal products of combustion.
Keep out of reach of children. CAUTION 鈥? Harmful if swallowed or absorbed through
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
skin. Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Prolonged
Material can accumulate static charges which can cause an incendiary electrical dis-
or frequently repeated skin contact may cause allergic reaction in some individuals. Wash
charge. Liquid runoff to sewers may create fire/explosion hazard.
thoroughly with soap and water after handling. Do not remain in enclosed areas after use.
Remove pets, birds, cover fish aquariums and turn off air pump motor before spraying.
SECTION 4. FIRST AID MEASURES OTHER PRECAUTIONS
Have the product container or label with you when calling a poison control center or doctor In health care facilities, remove patients prior to treatment. Thoroughly ventilate treated
or going for treatment. Describe any symptoms and follow the advice given. area for 2 hr before returning patients. Some furniture finishes, and particularly plastics,
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting can be damaged by petroleum based insecticides. To avoid damage, cover those items
unless told to do so by a poison control center or doctor. Do not give ANY liquid to the and do not spray directly. If in doubt, test by applying this material to an inconspicuous
person. Do not give anything by mouth to an unconscious person. area before spraying.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water PHYSICAL OR CHEMICAL HAZARDS
for 15 - 20 min. Call a poison control center or doctor for treatment advice. Do not use or store near heat or open flame.
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 min. STORAGE
Remove contact lenses, if present, after the first 5 min, then continue rinsing eyes. Call Do not contaminate water, food or feed. Keep container tightly closed. Store in a cool, dry
a poison control center or doctor for treatment advice. area inaccessible to children.
Note to Physician: Contains petroleum distillate - vomiting may cause aspiration pneumonia.
Medical Conditions Generally Aggravated by Exposure: None known
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand ULD庐 BP-300 Contact Insecticide Formula 1
SECTION 13. DISPOSAL CONSIDERATION
SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION
Do not contaminate water, food or feed by disposal. Dispose of container and wastes in
PERSONAL PROTECTIVE EQUIPMENT (PPE)
accordance with all federal, state and local regulations.
Respiratory Protection: None required for typical use exposure. See section 6 for
Container Disposal (鈮? 1 gal): Dispose of container in accordance with all federal, state and
atypical exposures.
local regulations. Do not reuse empty container. Wrap container and put in trash.
Protective Gloves: Chemical-resistant gloves are recommended if prolonged or
Container Disposal (> 1 gal): Triple rinse (or equivalent). Then offer for recycling or
repeated skin contact is likely. (Good practice requires that gross amounts of any chem-
reconditioning, or puncture and dispose of in a sanitary landfill or by other procedures
ical be removed from the skin as soon as practical, especially before eating or smoking.)
approved by state and local authorities.
Eye Protection: Use proper protection 鈥? safety glasses are recommended.
Waste Disposal: Wastes resulting from the use of this product may be disposed of on site
Other Protective Equipment: Rubber boots, full legged pants, long sleeved shirt.
or at an approved waste disposal facility. NEVER PLACE WASTES DOWN ANY INDOOR
Launder contaminated equipment or clothing before reuse.
OR OUTDOOR DRAIN OR SEWER.
VENTILATION
Local Exhaust: Do not remain in enclosed areas without appropriate respiratory protection.
SECTION 14. TRANSPORT INFORMATION
Mechanical: Provide adequate ventilation of treatment area.
Special: None required DOT, IMDG & ICAO/IATA CLASSIFICATION (鈮? 4 GAL)
Other: Ventilate area before reentering Proper Shipping Description: Liquid Insecticide (Not Regulated)
Hazard Class: NA
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES DOT, IMDG & ICAO/IATA CLASSIFICATION (> 4 GAL)
Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S.
Appearance: Clear yellow liquid Odor: Mild solvent odor
Hazard Class: 9
Solubility in Water: Negligible Vapor Pressure: < 0.1 mmHg @ 70掳F
UN I.D. NO.: UN 3082
Viscosity: 3.97 cps Vapor Density: 6.0 (air = 1.0)
Packing Group: III
Boiling Point: > 200掳F Freezing/Melting Point: NE
Proper Shipping Description: Environmentally Hazardous Substance, Liquid, NOS
pH: NE Density: 0.83 g/ml @ 20掳C (Pyrethrin), 9, UN 3082, PG III, RQ
Package Labeling: Class 9 (Misc. Hazard)
SECTION 10. STABILITY AND REACTIVITY Package Marking: Environmentally Hazardous Substance, Liquid, NOS (Pyrethrin),
UN 3082, RQ
REACTIVITY
ICAO / IATA Packaging Instructions: 914, ERG code 9L and Cargo only.
Stability: Stable
Other Requirements: UN approved packaging required.
Conditions to Avoid: None known
Product in unopened original packaging is compliant with all regulations for ground shipment within
Incompatibility (Material to Avoid): Strong oxidizing agents
the U.S. WMG disclaims any liability for claims or damages that may result from shipment by other
Hazardous Polymerization: Will not occur
means. Consult appropriately trained shipping professional before offering for shipment by water or air.
HAZARDOUS DECOMPOSITION PRODUCTS
When exposed to fire, produces normal products of combustion.
SECTION 15. REGULATORY INFORMATION
SECTION 11. TOXICOLOGICAL INFORMATION CERCLA
This product contains the CERCLA listed chemical Pyrethrins which has a reportable
ROUTES OF ENTRY
quantity (RQ) of 1 lb.
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
SARA TITLE III SECTION 311/312 HAZARD CLASS
ACUTE
This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated
Eyes: Direct contact with eyes can cause irritation.
under Section 311 and 312 of the Superfund Amendment and Reauthorization Act of
Skin: Prolonged or repeated contact of product with skin may cause irritation. Acute der-
1986 (SARA Title III) and is considered, under applicable definitions, to meet the follow-
mal toxicity LD50 > 2,000 mg/kg (rabbits).
ing categories:
Ingestion: If taken internally, aspiration of liquid product can cause chemical pneu-
Acute Health Hazard
monitis. Acute oral toxicity LD50 > 5,000 mg/kg (rats).
Flammability Hazard
Inhalation: Product spray mist, fog or vapor may cause irritation to nose, throat and
SARA TITLE III SECTION 313 CHEMICALS
lungs if adequate ventilation is not employed. Acute inhalation LC50 > 7.7 mg/L (rats).
This product contains the following substances subject to the reporting requirements of
CHRONIC / CARCINOGENICITY
Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III)
Neither this product nor any of its ingredients are classified as carcinogens by the
and/or 40 CFR Part 372:
National Toxicity Program (NTP), the International Agency for Research on Cancer (IARC)
Piperonyl Butoxide, Technical 6.0% by weight
or the Occupational Safety and Health Administration (OSHA).
TSCA
All components of this product are listed or excluded from listing on the US Toxic
SECTION 12. ECOLOGICAL INFORMATION Substance Control Act (TSCA) Chemical Substance Inventory.
This product is toxic to fish. For terrestrial uses, do not apply directly to water, or to areas
where surface water is present or to intertidal areas below the mean high water mark. Do not
SECTION 16. OTHER INFORMATION
apply where runoff is likely to occur. Do not apply when weather conditions favor drift from
NFPA HEALTH RATING INFORMATION KEY: 4 = Severe
areas treated. Do not contaminate water when disposing of equipment washwaters.
HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 0 3 = Serious
2 = Moderate
HMIS HAZARD RATING INFORMATION 1 = Slight
HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 0 0 = Minimal
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with
respect to the information contained herein. For automatic MSDS updates, register at www.wmmg.com.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Part No. 19-0784-04
NE - Not Established Effective Date: 08/12/05
WHITMIRE MICRO-GEN
PEL - Permissible Exposure Limit Review Date: 08/12/05
TLV - Threshold Limit Value Supersedes: 01/28/03
RESEARCH LABORATORIES, INC.
STEL - Short Term Exposure Limit (15 min) Text ID: 070501-4
TWA - Time Weighted Average (8 hr) Code #: 191-005
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