Part No.: 19-0782-03
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand ULD庐 BP-50 Contact Insecticide Formula 1
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SECTION 5. FIRE FIGHTING MEASURES
Product Name: Prescription Treatment brand ULD BP-50
庐 庐
FIRE AND EXPLOSION
Contact Insecticide Formula 1 Flash Point (TCC): 191掳F
EPA Reg. No.: 499-453 Explodibility Limits in Air (% by volume) for petroleum distillate:
Product Codes: 02-4912 (4 x 1 gal) Lower (LEL) = 1.3% Upper (UEL) = 8.1%
02-4915 (2 x 2.5 gal) UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
02-4914 (1 x 55 gal) Material can accumulate static charges which can cause an incendiary electrical discharge. Liq-
EPA Signal Word: CAUTION uid runoff to sewers may create fire/explosion hazard.
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc.
IN CASE OF FIRE
3568 Tree Court Industrial Blvd. Extinguisher Media: Foam, Dry Chemical, Water
St. Louis MO 63122-6682 Special Fire Fighting Procedures: Treat as an oil fire. Use water spray to cool fire exposed
surfaces and to protect personnel. Isolate 鈥渇uel鈥? supply from fire. Use foam, dry chemical or
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS water spray to extinguish fire. Avoid spraying water directly into storage container due to dan-
ger of boil over. This liquid is volatile and gives off invisible vapors. Either the liquid or vapor
may settle in low areas or travel some distance along the ground or surface to ignition sources
COMPOSITION INFORMATION
where they may ignite or explode.
ACTIVE INGREDIENTS (5.5%) % CAS NO.
Pyrethrins 0.50 8003-34-7
SECTION 6. ACCIDENTAL RELEASE MEASURES
Piperonyl Butoxide, Technical 5.00 51-03-6
OTHER INGREDIENTS* (94.5%) % CAS NO. IN CASE OF SPILL OR LEAK
If container begins to leak (through puncture, etc.), eliminate all ignition sources. Do not let
Petroleum Distillate > 10.00 64742-47-8
spilled or leaking material enter watercourse. May be toxic to aquatic life. Absorb with oil-dry
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the
or similar inert material. Sweep or scrape up and containerize.
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200.
This product contains the Comprehensive Environmental Response, Compensation and Lia-
EXPOSURE INFORMATION
bility Act (CERCLA) listed chemical Pyrethrins which has a reportable quantity (RQ) of 1 lb. A
OSHA PEL ACGIH TLV release of more than 200 lbs of this product (approx. 30 gal) is reportable to the National
MATERIAL STEL TWA STEL TWA Response Center (800-424-8802).
Pyrethrins NE NE 10 mg/m3 5 mg/m3 Emergency Telephone Number of Chemtrec: 800-424-9300 (for transportation spills)
Piperonyl Butoxide, Technical NE NE NE NE
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Petroleum Distillate* NE 500 ppm NE NE
Eyes: Use proper protection 鈥? safety glasses are recommended.
* TWA recommended by ingredient supplier = 166 ppm Skin: Wear chemical-resistant gloves. (Good practice requires that gross amounts of any chem-
ical be removed from the skin as soon as practical, especially before eating or smoking.)
SECTION 3. HAZARDS IDENTIFICATION Inhalation: Use of a respirator may be appropriate when working with spills in enclosed or
confined spaces, or when prolonged exposure to product vapor or spray mist may occur. When
using a respirator, wear a NIOSH approved respirator with an organic vapor (OV) cartridge or
NOTES TO PHYSICIAN
canister with any R or P prefilter. See 29 CFR 1910.134 for respiratory protection, training and
Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
testing requirements.
SIGNS/SYMPTOMS OF EXPOSURE
WASTE DISPOSAL METHOD
Direct contact with eyes can cause irritation. Prolonged or repeated contact with skin may cause
Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leaking
irritation. Product spray mist, fog or vapor may cause irritation to nose, throat and lungs. If taken
containers to a local disposal company for biological treatment or incineration. Review all
internally, aspiration of liquid product may cause pneumonitis.
local, state and federal regulations concerning health and pollution to determine approved
ROUTES OF ENTRY disposal procedures. NEVER PLACE WASTES DOWN ANY INDOOR OR OUTDOOR DRAIN
Primary: Skin Secondary: Ingestion Tertiary: Inhalation OR SEWER.
HAZARDOUS DECOMPOSITION PRODUCTS
SECTION 7. HANDLING AND STORAGE
When exposed to fire, produces normal products of combustion.
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Material can accumulate static charges which can cause an incendiary electrical discharge.
Keep out of reach of children. CAUTION 鈥? Harmful if swallowed or absorbed through the skin.
Liquid runoff to sewers may create fire/explosion hazard.
Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Prolonged or
frequently repeated skin contact may cause allergic reaction in some individuals. Wash thor-
SECTION 4. FIRST AID MEASURES oughly with soap and water after handling. Remove pets, birds, cover fish aquariums and turn
off air pump motor before spraying.
Have the product container or label with you when calling a poison control center or doctor or
going for treatment. Describe any symptoms and follow the advice given. OTHER PRECAUTIONS
Some furniture finishes, and particularly plastics, can be damaged by petroleum based insec-
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting unless
ticides. To avoid damage, cover those items and do not spray directly. If in doubt, test by apply-
told to do so by a poison control center or doctor. Do not give ANY liquid to the person. Do
ing this material to an inconspicuous area before spraying.
not give anything by mouth to an unconscious person.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance,
PHYSICAL OR CHEMICAL HAZARDS
then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison con-
Do not use or store near heat or open flame.
trol center or doctor for further treatment advice.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for STORAGE
15 - 20 min. Call a poison control center or doctor for treatment advice. Do not contaminate water, food or feed. Keep container tightly closed. Store in a cool, dry area
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 min. Remove inaccessible to children.
contact lenses, if present, after the first 5 min, then continue rinsing eyes. Call a poison con-
trol center or doctor for treatment advice.
Note to Physician: Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
Medical Conditions Generally Aggravated by Exposure: None known
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand ULD庐 BP-50 Contact Insecticide Formula 1
SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION SECTION 13. DISPOSAL CONSIDERATION
Do not contaminate water, food or feed by disposal of container or waste. Dispose of container and
PERSONAL PROTECTIVE EQUIPMENT (PPE)
waste in accordance with all federal, state and local regulations.
Respiratory Protection: For prolonged exposure or if used in enclosed or confined areas,
Container Disposal: 鈮? 2.5 GAL BOTTLE: Empty container by using the product according
a NIOSH approved respirator with an organic vapor (OV) cartridge or canister with any R or P
to label directions. Do not reuse this container! Place empty container in trash or offer for recy-
prefilter may be used. See 29 CFR 1910.134 for respiratory protection, training and testing
cling if available. If container is partly filled, call your local solid waste agency for disposal
requirements.
instructions. 55 GAL DRUMS: Empty container by using the product according to label direc-
Protective Gloves: Chemical-resistant gloves are recommended if prolonged or repeated
tions. Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dis-
skin contact is likely. (Good practice requires that gross amounts of any chemical be removed
pose of in a sanitary landfill or by other procedures approved by state and local authorities.
from the skin as soon as practical, especially before eating or smoking.)
NEVER PLACE UNUSED PRODUCT DOWN ANY INDOOR OR OUTDOOR DRAIN OR SEWER.
Eye Protection: Use proper protection - safety glasses are recommended. Waste Disposal: Wastes resulting from the use of this product may be disposed of on site
Other Protective Equipment: None required or at an approved waste disposal facility. NEVER PLACE WASTES DOWN ANY INDOOR OR
VENTILATION OUTDOOR DRAIN OR SEWER.
Local Exhaust: None required
Mechanical: None required SECTION 14. TRANSPORT INFORMATION
Special: None required
Other: Ventilate area before reentering. Do not remain in enclosed areas without appropriate DOT, IMDG & ICAO/IATA CLASSIFICATION (4 x 1 GAL & 2 x 2.5 GAL)
respiratory protection. Proper Shipping Description: Liquid Insecticide (Not Regulated)
Package Marking: NA
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Package Labeling: NA
Certified Packaging: Not required
Appearance: Clear yellow liquid Odor: Mild solvent odor DOT, IMDG & ICAO/IATA CLASSIFICATION (55 GAL)
Solubility in Water: Negligible Vapor Pressure: < 0.1 mmHg @ 70掳F Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S.
Viscosity: 3.04 cps @ 68掳F Vapor Density: 6 (air = 1.0) Hazard Class: 9
Boiling Point: > 200掳F Freezing/Melting Point: NE UN I.D. NO.: UN 3082
pH: NE Density: 0.8 g/ml @ 70掳F Packing Group: III
Proper Shipping Description: Environmentally Hazardous Substance, Liquid, NOS(Py-
SECTION 10. STABILITY AND REACTIVITY rethrin), 9, UN 3082, PG III, RQ
Package Labeling: Class 9 (Misc. Hazard)
Package Marking: Environmentally Hazardous Substance, Liquid, NOS (Pyrethrin), UN 3082, RQ
REACTIVITY
Certified Packaging: UN approved packaging required.
Stability: Stable
Other Requirements or Instructions: Product is not a marine pollutant. For air shipment,
Conditions to Avoid: None known
complete air bill with packing instruction 鈥?914, ERG code 9L鈥?.
Incompatibility (Material to Avoid): Strong oxidizing agents
Hazardous Polymerization: Will not occur Product in unopened original packaging is compliant with all regulations for ground shipment
within the U.S. WMG disclaims any liability for claims or damages that may result from ship-
HAZARDOUS DECOMPOSITION PRODUCTS
ment by other means. Consult appropriately trained shipping professional before offering for
When exposed to fire, produces normal products of combustion.
shipment by water or air.
SECTION 11. TOXICOLOGICAL INFORMATION
SECTION 15. REGULATORY INFORMATION
ROUTES OF ENTRY
CERCLA
Primary: Skin Secondary: Ingestion Tertiary: Inhalation
This product contains the CERCLA listed chemical Pyrethrins which has a reportable quantity
ACUTE (RQ) of 1 lb.
Eyes: Direct contact with eyes can cause irritation. Product produced minimal irritation in albi-
SARA TITLE III SECTION 311/312 HAZARD CLASS
no rabbits reversible in 24 hr.
This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated under
Skin: Prolonged or repeated contact of product with skin may cause irritation. Acute dermal
Section 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title
LD50 > 2,000 mg/kg (rabbits).
III) and is considered, under applicable definitions, to meet the following categories:
Ingestion: If taken internally, aspiration of liquid product can cause chemical pneumonitis.
Acute Health Hazard
Acute oral toxicity LD50 > 5,000 mg/kg (rats).
Flammability Hazard
Inhalation: Product spray mist, fog or vapor may cause irritation to nose, throat and lungs if
adequate ventilation is not employed. Acute inhalation LC50 > 7.0 mg/L (rats). SARA TITLE III SECTION 313 CHEMICALS
CHRONIC / CARCINOGENICITY This product contains the following substances subject to the reporting requirements of Title III
Neither this product nor any of its ingredients are classified as carcinogens by the National of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) and/or 40 CFR
Toxicity Program (NTP), the International Agency for Research on Cancer (IARC) or the Occu- Part 372:
pational Safety and Health Administration (OSHA). Piperonyl Butoxide, Technical (CAS #51-03-6) 5.0% by weight
TSCA
SECTION 12. ECOLOGICAL INFORMATION All components of this product are listed or excluded from listing on the US Toxic Substance
Control Act (TSCA) Chemical Substance Inventory.
This product is toxic to fish. Keep out of lakes, streams or ponds. Do not apply where runoff is like-
ly to occur. Do not apply when weather conditions favor drift from areas treated. Do not contaminate
SECTION 16. OTHER INFORMATION
water when disposing of equipment washwaters. Apply this product only as specified on the label.
KEY: 4 = Severe
NFPA HEALTH RATING INFORMATION
3 = Serious
HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 0
2 = Moderate
HMIS HAZARD RATING INFORMATION 1 = Slight
HEALTH - 1 FLAMMABILITY - 2 REACTIVITY - 0 0 = Minimal
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the
information contained herein. For automatic MSDS updates, register at www.wmmg.com.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Effective Date: 09/12/06
WHITMIRE MICRO-GEN
NE - Not Established Review Date: 09/12/06
PEL - Permissible Exposure Limit Supersedes: 01/27/04
RESEARCH LABORATORIES, INC.
TLV - Threshold Limit Value Code #: 191-003
STEL - Short Term Exposure Limit (15 min) Text ID: 070511-3
TWA - Time Weighted Average (8 hr) Part Number: 19-0782-03
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