SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET HH 183
Threshold Limited Value TWA: 1 ppm, 1.5 mg/m3 (Air);
ALDON 1533 W.Henrietta Rd. 3
STEL: 2 ppm, 3 mg/m (ACGIH 1983-84).
HH 183
Avon, New York 14414 MSDS No.
庐
CORPORATION August 3, 1995
Effective Date
(716) 226-6177 Skin irritation with discomfort or rash, eye irritation with discomfort, tearing,
Effects of Overexposure
or blurring of vision, or irritation of the upper respiratory passages. Higher
exposures may lead to these effects: Eye corrosion with corneal or
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE conjunctival ulceration, skin burns or ulceration, or temporary lung irritation
effects with cough, discomfort, difficulty breathing, or shortness of breath.
Product HYDROGEN PEROXIDE, 35% CHEMTREC There are inconclusive or unverified reports of human sensitization.
0 3
Health
800-424-9300
Chemical
Emergency and
2 1
Hydrogen Peroxide
Synonyms 0
Fire
Day 716-226-6177
oxy First Aid Procedures EYES: Immediately flush eyes with water for at least 15 minutes, lifting
Formula H O /H O 2 lower and upper eyelids occasionally. Get immediate medical attention.
Reactivity
22 2
NFPA SKIN: Flush thoroughly with water, then wash with mild soap and water.
HAZARD RATING HMIS *
Unit Size up to 55 gal.
INGESTION: If swallowed, do NOT induce vomiting. If conscious, give
LEAST SLIGHT MODERATE HIGH EXTREME
large quantities of water to drink. Call physician immediately. Never give
0 1 2 3 4
C.A.S. No. 7722-84-1
anything by mouth to an unconscious person.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
X Unstable with heat or contamination. May result in
Hydrogen Peroxide 35% See Section V.
dangerous pressures due to liberation of oxygen gas.
Stable
Water: (CAS No. 7732-18-5) 65% None established. Incompatibility Incompatible with cyanides, hexavalent chromium compounds, nitric acid, potassium
permanganate, reducing agents, and many other oxidizing agents and flammables.
(Materials to Avoid)
DANGER! STRONG OXIDIZER! CAUSES
Contamination from any source may cause rapid decomposition, oxygen gas
Hazardous release and dangerous pressures. May react dangerously with rust, dust, dirt,
BURNS. HARMFUL IF SWALLOWED.
iron, copper, heavy metals or their salts 鈥渟uch as mercuric oxide or chloride鈥? and
Decomposition Products
SECTION III PHYSICAL DATA with organic materials 鈥渆specially vinyl monomers鈥?.
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) -26掳C to -52掳C (-18 to -62掳F) 1.112 at 20掳C
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 106掳C (222掳F) @ 760 mm Hg 50-70 @ 21掳C (70掳F) X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 25 @ 30掳C (86掳F) >1
( n-Butyl Acetate =1)
Steps to be taken in case
Vapor Density (Air=1) 0.8 to 1.0 (calculated)
For quantities covered by this MSDS, dilute spill with large
material is released or spilled
quantities of water and flush to sewer with copious amounts
Solubility in Water 100%
of water.
Appearance & Odor Clear, colorless liquid; slightly pungent irritating odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
% by Volume
Non-flammable (NA). None -------- --------
(Method Used) Flush to sewer with copious amounts of water.
Extinguisher
Use water in large quantities for extinguishing supporting fire. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None needed in normal laboratory handling. If misty conditions prevail, work in ventilation
Respiration Protection
hood or wear a NIOSH-approved respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Yes. No.
Local Exhaust Special
PROCEDURES Ventilation
Flood with water. Cool tanks or containers. In fire conditions, wear a Recommended. No.
Mechanical (General) Other
NIOSH-approved self-contained breathing apparatus and full
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
protective clothing with eye protection.
Other Protective
Smock, apron, eye wash station, proper gloves, goggles, face shield, fire extinguisher.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 45)
Precautions to be Taken STORE UNDER REFRIGERATION TO PROLONG SHELF LIFE AND STABILITY. Use extreme
UNUSUAL FIRE AND in Handling & Storing care when attempting any reactions because of fire and explosion potential 鈥渋mmediate or
EXPLOSION HAZARDS delayed鈥?. Conduct all initial experiments on a small scale and protect personal with adequate
Powerful oxidizing material. May cause spontaneous combustion if Keep container tightly closed when not in use.
shielding as the reactions are unpredictable, being affected by impurities, contaminants, etc.
allowed to remain in contact with readily oxidizable materials. Somewhat
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
unstable, but commercially available product is usually inhibited against
Avoid contact with skin, eyes, mucous membranes and combustible material.
decomposition. Violent decomposition may be caused by contact with
Remove and wash contaminated clothing. Drying of this material on clothing or
iron, copper, chromium, brass, bronze, lead, silver, manganese and their
combustible materials may cause fire.
salts. If containers are sealed, high pressure may develop due to
released oxygen, resulting in explosion or rupture. For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 2 8/3/95 Michael Raszeja MR
Coordinator
D.O.T. HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1, UN 2014, PG II The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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