LL137 Lead Dioxide
SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET LL 137
Threshold Limited Value
ALDON ACGIH PEL; TWA 0.15 mg/m3 (as Pb).
1533 W.Henrietta Rd.
LL 137
Avon, New York 14414 MSDS No.
庐
CORPORATION October 30, 1995
Effective Date
(716) 226-6177
Effects of Overexposure Toxic by inhalation or ingestion. Symptoms of lead poisoning include abdominal pain
and spasms, nausea, vomiting and headache. Acute poisoning can lead to muscle
weakness, "lead line" on the gums, metallic taste, loss of appetite, insomnia, dizziness,
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE high levels of lead in blood and urine. Extreme cases can result in shock, coma and
death. Less toxic than soluble lead compounds. Irritating to eyes. Reproductive
LEAD DIOXIDE
Product hazards cited, not known to be carcinogenic.
CHEMTREC 3
Health
800-424-9300
Chemical Emergency and
Lead (IV) Oxide, Lead Peroxide
Synonyms EYES: Flush thoroughly with water for at least 15 minutes, lifting lower and
0
Fire
Day 716-226-6177
First Aid Procedures upper eyelids occasionally. Get immediate medical attention. SKIN: Flush
PBO2
Formula 3
Reactivity thoroughly with water, then wash with mild soap and water. INHALATION:
NFPA
Remove to fresh air. If not breathing, give artificial respiration. If breathing
HAZARD RATING HMIS *
Unit(s) Size up to 2.5 Kg.
is difficult, give oxygen. Get medical attention. INGESTION: If swallowed,
LEAST SLIGHT MODERATE HIGH EXTREME
C.A.S. No. 0 1 2 3 4 if conscious, give water or milk to drink. Induce vomiting. Get immediate
1309-60-0
medical attention. Never give anything by mouth to an unconscious person.
SECTION II HAZARDOUS INGREDIENTS OF MIXTURES
Principal Hazardous Component(s) SECTION VI REACTIVITY DATA
% TLV Units
Stability Unstable Conditions to Avoid Excessive temperature, heat, sparks, flame,
Lead Dioixde 97.0% min. See Section V.
ignition sources.
Stable X
Incompatibility
Reducing agents or combustibles.
(Materials to Avoid)
DANGER! STRONG OXIDIZER! HARMFUL IF SWALLOWED
Hazardous
OR INHALED. MAY CAUSE IRRITATION. Thermal decomposition may yield oxygen gas and other oxides of lead.
Decomposition Products
SECTION III PHYSICAL DATA
Hazardous Polymerization Conditions to Avoid
Melting Point (掳F) Specific Gravity (H2 O = 1)
290掳C (554掳F) decomposes 9.375
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Not applicable. 0
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Not applicable. Not applicable.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) 9.38
Wear protective safety equipment and use adequate ventilation.
material is released or spilled
Solubility in Water Avoid making dust. Sweep up and place in a suitable container
Insoluble.
for disposal.
Appearance & Odor Dark brown to black powder; odorless.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
SECTION IV FIRE AND EXPLOSION HAZARD DATA Waste Disposal Method These disposal guidelines are intended for the disposal of catalog-size quantities only.
Flash Point Lower
Flammable Limits in Air Upper
(Method Used) % by Volume
Non-flammable. NA -------- -------- Dispose of in accordance with local, state and federal regulations.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Use any media suitable for extinguishing supporting fire.
Media
Respiration Protection None needed in normal laboratory handling. If dusty conditions prevail, work in
(Specify Type)
SPECIAL FIREFIGHTING ventilation hood or wear a NIOSH/MSHA-approved dust mask or respirator.
Recommended. No.
Local Exhaust Special
PROCEDURES
Ventilation Mechanical (General) Other
Recommended. No.
If involved in fire situation, wear a NIOSH/MSHA-approved
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
self-contained breathing apparatus and full protective
clothing. Other Protective
Lab coat, apron, eye wash station, proper gloves, ventilation hood.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool place, dry place away from combustible material.
in Handling & Storing
EXPLOSION HAZARDS Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
Oxidizing material; will react with combustibles and reducing
Avoid contact with skin, eyes and clothing. Avoid breathing dust.
agents and may cause fire.
Use with adequate ventilation. Remove and wash contaminated
clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Date
Rev. No. 10/30/95 Michael Raszeja
No. 1 MR
Coordinator
D.O.T. LEAD DIOXIDE, 5.1, UN 1872 The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered
by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these materials and the
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 safety and health of employees. * Hazardous Materials Industrial Standards.
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