SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET MM 150
Threshold Limited Value
ALDON None established by (ACGIH 1992-93).
1533 W.Henrietta Rd.
TXDS: Oral rabbit: 75 mg/kg.
MM 150
Avon, New York 14414 MSDS No.
庐
CORPORATION January 23, 1996
Effective Date
(716) 226-6177 Details unknown. Toxicity studies are variable. Allergic responses to aniline
Effects of Overexposure
dyes have been known to occur. May be harmful by inhalation, ingestion or
skin absorption. May cause irritation. To the best of our knowledge, the
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE chemical, physical and toxicological properties have not been thoroughly
investigated. Exercise appropriate procedures to minimize opportunities for
Product MALACHITE GREEN HYDROCHLORIDE
CHEMTREC direct contact with skin or eyes and to prevent inhalation of dust.
2
Health
800-424-9300
Chemical
Emergency and
Basic Green 4; C. I. No. 42000
Synonyms 1 SKIN: Flush thoroughly with water, then wash with mild soap and water.
Fire
Day 716-226-6177
First Aid Procedures EYES: Flush thoroughly with water for at least 15 minutes, lifting upper and
Formula C H N Cl 1
Reactivity
23 25 2
NFPA lower eyelids occasionally. Get immediate medical attention. INGESTION:
HAZARD RATING HMIS * If swallowed, if conscious, give one or two glasses of water or milk to drink.
Unit Size up to 2.5 Kg.
LEAST SLIGHT MODERATE HIGH EXTREME
Call physician immediately. Never give anything by mouth to an unconscious
0 1 2 3 4
C.A.S. No. 569-64-2 person. INHALATION: Remove to fresh air. Treat symptomatically. Get
medical attention if symptoms develop or persist.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Protect from light, excessive temperature and
Malachite Green Hydrochloride, Biological Stain/pH Indicator 90% min. None established.
heat.
Stable X
WARNING! MAY BE HARMFUL BY INHALATION, Incompatibility
Strong oxidizing materials.
(Materials to Avoid)
INGESTION, OR SKIN ABSORPTION. MAY
Hazardous When heated to decomposition, emits toxic fumes of oxides of
CAUSE EYE AND SKIN IRRITATION.
Decomposition Products nitrogen (NO ) and chlorine.
x
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Data not listed. Greater than 1.
Melting Point (掳F)
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Decomposes. Non-volatile (NA).
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Negligible as solid. Non-volatile (NA).
=1)
(
Steps to be taken in case
Data not listed.
Vapor Density (Air=1) Wearing suitable protective clothing, avoid making dust. Sweep
material is released or spilled
material onto paper. Place in a suitable container for disposal by
Solubility in Water Very soluble in water.
incineration. Wash spill area well with soap and water.
Appearance & Odor Green crystalline powder with metallic luster; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved incinerator equipped with an afterburner and
% by Volume
Non-flammable (NA). NA -------- --------
(Method Used)
scrubber.
Extinguisher
Water spray; carbon dioxide (CO2); dry chemical (ABC). SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None should be needed in normal laboratory handling. If dusty conditions prevail,
Respiration Protection
work in ventilation hood or wear a NIOSH/MSHA-approved dust mask.
(Specify Type)
SPECIAL FIREFIGHTING
Not needed. No.
Local Exhaust Special
PROCEDURES Ventilation Recommended. No.
Mechanical (General) Other
In fire conditions, wear a NIOSH/MSHA-approved self-contained
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
breathing apparatus and protective clothing.
Other Protective
Lab coat, apron, ventilation hood, proper gloves, eye wash station.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry place away from oxidizing materials and
in Handling & Storing
EXPLOSION HAZARDS protect from light. Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
Dangerous when heated to decomposition, it emits highly toxic fumes of
aniline and oxides of nitrogen; can react with strong oxidizing materials. Do not get in eyes, on skin, on clothing. Avoid breathing dust.
Strong dye. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date Michael Raszeja MR
1/23/96
No. 3 Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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