SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET IX 140
Threshold Limited Value None established for this solution. (ACGIH 1992-93).
ALDON 1533 W.Henrietta Rd.
Toxicity: Oral-human LDLO: 2000 mg/kg.
IX 140
Avon, New York 14414 MSDS No.
庐
CORPORATION December 10, 1996
Effective Date
(716) 226-6177
Effects of Overexposure Contact as fumes or solution is intensely irritating to eyes, skin and mucous
membranes. May cause delayed lung injury. INGESTION: Of large
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE quantities causes abdominal pain, vomiting and diarrhea. In severe cases
purging, excessive thirst and circulatory failure may develop.
Product IODINE SOLUTION, 0.1 NORMAL
CHEMTREC 3
Health
800-424-9300
Chemical
Emergency and INGESTION: If swallowed, if conscious, give one or two glasses of milk,
Iodine-Iodide Solution
Synonyms 0
Fire
Day 716-226-6177 followed by a starch, flour or egg white, as a water solution. Get immediate
First Aid Procedures
Mixture.
Formula medical attention. Never give anything by mouth to an unconscious person.
1
Reactivity
NFPA EYES: Flush thoroughly with water for at least 15 minutes, lifting lower and
HAZARD RATING HMIS *
up to 4 Lt.
Unit Size upper eyelids occasionally. Get immediate medical attention. INHALATION:
LEAST SLIGHT MODERATE HIGH EXTREME
Remove to fresh air. If breathing has stopped, give artificial respiration. If
0 1 2 3 4
C.A.S. No. Mixture. breathing is difficuolt, give oxygen. Get immediate medical attention. SKIN:
SECTION II INGREDIENTS OF MIXTURES Wash with mild soap and water.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
3 Excessive temperature or heat.
Iodine: (CAS No. 7553-56-2) 1.34% TWA: C 0.1 ppm; 1 mg/m
Stable X
Potassium Iodide: (CAS No. 7681-11-0) 4.22% None established. Incompatibility Contact of gaseous ammonia or its solutions with free iodine should be avoided to prevent the
formation of the explosive 鈥渘itrogen iodide鈥?. Acetaldehyde, Sodium Azide, Sodium Hydride.
(Materials to Avoid)
Water: (CAS No. 7732-18-5) 94.44% None established.
Hazardous
WARNING! CORROSIVE! HARMFUL IF INHALED OR SWALLOWED.
CAUSES IRRITATION TO SKIN, EYES AND MUCOUS MEMBRANES. Free iodine.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) May freeze at 0掳C (32掳F) 1.0
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Approx. 100掳C (212掳F) (Water) 96% X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Iodine 1 mm @ 38.7掳C Ether Greater than 1.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) 0.7 (water)
Absorb spill in vermiculite, sand, earth, paper towel and place in a
material is released or spilled
suitable container for disposal. Wash floor or spill area with a 5-10%
Solubility in Water Complete.
Sodium thiosulfate solution.
Appearance & Odor Deep-amber color liquid; iodine odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point Work in a ventilation hood and wearing proper safety equipment, collect waste iodine in a large beaker.
Non-flammable. N/A
% by Volume
(Method Used) Cover with a large volume of water. Slowly add, while stirring soda ash or sodium thiosulfate till all of the
iodine has been dissolved and solution is colorless. Flush to sewer with copious amounts of water.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Use any media suitable for extinguishing supporting fire.
Media
None should be needed in normal laboratory handling at room temperature. If needed,
Respiration Protection
work in a fume hood.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation Recommended. No.
Mechanical (General) Other
In fire conditions, wear a NIOSH/MSHA-approved self-contained
Protective Gloves Eye Protection
breathing apparatus and full protective clothing. Use flooding Rubber. Chemical safety glasses.
amounts of water in early stages of fire. Other Protective
Smock, apron, eye wash station, goggles, ventilation hood, proper gloves.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry, well-ventilated area. Remove all contaminated clothing
in Handling & Storing
EXPLOSION HAZARDS and shoes. Wash before reuse. Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
When heated, emits toxic and corrosive, violet in color, fumes of
Avoid contact with skin and eyes. Contact with skin will leave yellow
iodine. Iodine is corrosive to metals and to all body tissues.
iodine stain.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date MR
No. 5 12/10/96 Michael Raszeja Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
|