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MSDS Material Safety Data Sheet
CAS

77-92-9

File Name: nugentec_com---citric_acid_50%.asp
NuGenTec
NuGeneration Technologies, LLC
7200 C.E. Dixon Street
Stockton, CA 95206
(209) 234-5930, Fax 209-234-5931

For Emergency Assistance involving chemicals call - CHEMTREC (800) 424-9300

The Version Date for this MSDS is: 1/22/2005


I. PRODUCT IDENTIFICATION:

PRODUCT NAME........: Citric Acid Solution, 50% Liquid

MSDS NUMBER: HX17030

CHEMICAL FAMILY.....: Organic Acid

CHEMICAL NAME.......: 2-Hydroxy-1,2,3 Propanetricarboxylic Acid, Aqueous
Solution
FORMULA.............: C6H8O7 - 50% WT/WT Aqueous Solution


II. HAZARDOUS INGREDIENTS:

INGREDIENT NAME
/CAS NUMBER EXPOSURE LIMITS CONCENTRATION (%)

2-Hydroxy-1,2,3 Propanetricarboxylic Acid
77-92-9 OSHA : Not Established 50.000 %
ACGIH: Not Established


III. PHYSICAL PROPERTIES:

PHYSICAL FORM.............: Liquid
COLOR.....................: Clear white
ODOR......................: Essentially odorless to very slight sugar odor
BOILING POINT.............: 219 F (104 C)
MELTING/FREEZING POINT....: Not Established
VISCOSITY.................: Not Established
SOLUBILITY IN WATER ......: Completely miscible
SOLUBILITY (NON AQUEOUS)..: Methyl alcohol: completely miscible
SPECIFIC GRAVITY .........: 1.24 at 59 F (15 C)
BULK DENSITY..............: Not Established
% VOLATILE BY VOLUME......: 50%
EVAPORATION RATE .........: Less than 1 (Butyl acetate = 1)
VAPOR PRESSURE ...........: 16 mmHg at 68 F (20 C)
VAPOR DENSITY ............: 0.62 (Air = 1)


IV. FIRE AND EXPLOSION DATA:

FLASH POINT.....................: Not Applicable
EXTINGUISHING MEDIA.............: Material is not combustible. Use
extinguishing media suitable for other
combustible materials in the area.


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SPECIAL FIRE FIGHTING PROCEDURES: None

UNUSUAL FIRE / EXPLOSION HAZARDS: None known.


V. HUMAN HEALTH DATA:

ROUTE(S) OF ENTRY.......: Skin Contact; Eye Contact

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE:

ACUTE SKIN CONTACT............: This product is irritating to the skin
resulting in reddening, stinging, and swelling.

ACUTE EYE CONTACT.............: This product is irritating to the eyes
resulting in stinging, reddening, tearing, and swelling.

CHRONIC EFFECTS OF EXPOSURE...: No applicable information was found concerning
any adverse chronic health effects from overexposure to this product.

CARCINOGENICITY...............: The components of this product are not listed
by NTP, IARC or regulated as a carcinogen by OSHA.

MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE......: Persons with pre-existing eye or skin disorders
may be more susceptible to the effects of this product.


VI. EMERGENCY AND FIRST AID PROCEDURES:

FIRST AID FOR EYES......: In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Call a physician.

FIRST AID FOR SKIN......: Flush skin with plenty of soap and water for at
least 15 minutes. Remove contaminated clothing. Wash clothing before reuse.
Call a physician.

FIRST AID FOR INHALATION: If inhaled, remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Call
a physician.

FIRST AID FOR INGESTION.: If swallowed, call a physician.


VII. EMPLOYEE PROTECTION RECOMMENDATIONS:

EYE PROTECTION REQUIREMENTS........: Chemical safety goggles or face shield

SKIN PROTECTION REQUIREMENTS.......: Rubber or vinyl gloves and long sleeved
shirts and pants to minimize skin contact. Employees should wash their hands
and face before eating, drinking or using tobacco products.

RESPIRATOR REQUIREMENTS............: Under normal conditions of use,
respirator protection is not required.

VENTILATION REQUIREMENTS...........: Use local exhaust ventilation to maintain


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air levels below the recommended exposure limits.

ADDITIONAL PROTECTIVE MEASURES.....: Emergency showers and eye wash stations
should be made available. Educate and train employees in the safe use and
handling of this product.


VIII. REACTIVITY DATA:

STABILITY..................: This is a stable material.

HAZARDOUS POLYMERIZATION...: Will not occur.

INCOMPATIBILITIES..........: Reaction with caustic can create heat (strong
exotherm)

INSTABILITY CONDITIONS.....: None known.

DECOMPOSITION PRODUCTS.....: None known.


IX. SPILL AND LEAK PROCEDURES:

SPILL OR LEAK PROCEDURES....: Utilize recommended protective clothing. Spills
should be taken up with an appropriate absorbent and placed in approved
containers. Spill area can be washed with water. Collect wash water for
approved disposal.

WASTE DISPOSAL METHOD.......: Cover with soda ash or sodium bicarbonate to
neutralize. Flush with residual water into approved sewer. Prevent bulk,
concentrated material from entering sewer or open waterways. Waste disposal
should be in accordance with existing federal, state and local environmental
control regulations.

X. SPECIAL PRECAUTIONS & STORAGE DATA:

STORAGE TEMPERATURE(MIN/MAX): 4 C / 49 C
SHELF LIFE..................: 5 years at 4 C and 3 years at 49 C
SPECIAL SENSITIVITY.........: None Known

X. SPECIAL PRECAUTIONS & STORAGE DATA (Continued)

HANDLING/STORAGE PRECAUTIONS: Avoid breathing mist and vapors. Avoid contact
with eyes and skin. Wash thoroughly after handling. Store in a dry place
away from excessive heat, in original or similar waterproof containers.
Reseal containers immediately after use. Keep from freezing.

XI. SHIPPING INFORMATION:

TECHNICAL SHIPPING NAME........: Organic Acid
FREIGHT CLASS BULK.............: Chemicals, NOI
FREIGHT CLASS PACKAGE..........: Chemicals, NOI, (NMFC 60000)

DOT (HM-181) (DOMESTIC SURFACE)
-------------------------------
HAZARD CLASS OR DIVISION ......: Non-Regulated




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IMO / IMDG CODE (OCEAN)
-----------------------
HAZARD CLASS DIVISION NUMBER...: Non-Regulated

ICAO / IATA (AIR)
-----------------
HAZARD CLASS DIVISION NUMBER...: Non-Regulated


XII. ANIMAL TOXICITY DATA:


NO ANIMAL TOXICITY INFORMATION AVAILABLE


XIII. FEDERAL REGULATORY INFORMATION:

OSHA STATUS.................: This product is hazardous under the criteria of
the Federal OSHA Hazard Communication Standard
29 CFR 1910.1200.

TSCA STATUS.................: On TSCA Inventory

CERCLA REPORTABLE QUANTITY..: None

SARA REPORTABLE QUANTITY....: Exempt from SARA Title III reporting; contains
no section 313 toxic chemical.

RCRA STATUS.................: If discarded in its purchased form, this product
would not be a hazardous waste either by listing
or by characteristic. However, under RCRA, it
is the responsibility of the product user to
determine, at the time of disposal, whether a
material containing the product or derived from
the product should be classified as a hazardous
waste. (40 CFR 261.20-24)


XIV. OTHER REGULATORY INFORMATION:

The following chemicals are specifically listed by individual states; other
product specific health and safety data in other sections of the MSDS may also
be applicable for state requirements. For details on your regulatory
requirements you should contact the appropriate agency in your state.


COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE

2-Hydroxy-1,2,3 Propanetricarboxylic Acid
77-92-9 50.000 % PA3, NJ4
Water
50.000 % PA3, NJ4

NJ4 = New Jersey Other - included in 5 predominant ingredients > 1%

PA3 = Pennsylvania Non-hazardous present at 3% or greater.


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HMIS RATINGS: Health Flammability Reactivity
1 0 0

0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe


XV. APPROVALS:
For Additional Information:
Contact: MSDS Coordinator - NuGeneration Technologies, LLC
During business hours, Pacific Time - (209) 234-5930

NOTICE
NuGeneration Technologies, LLC expressly disclaims all express or implied
warranties of merchantability and fitness for a particular purpose, with respect
to the product or information provided herein, and shall under no circumstances
be liable for incidental or consequential damages.

Do not use ingredient information and/or ingredient percentages in this MSDS as
a product specification. For product specification information refer to a
Product Specification Sheet and/or a Certificate of Analysis. These can be
obtained from your local NuGeneration Technologies Sales Office.

All information appearing herein is based upon data obtained from the
manufacturer and/or recognized technical sources. While the information is
believed to be accurate, NuGeneration Technologies makes no representations as
to its accuracy or sufficiency. Conditions of use are beyond NuGeneration
Technologies鈥? control and therefore users are responsible to verify this data
under their own operating conditions to determine whether the product is
suitable for their particular purposes and they assume all risks of their use,
handling, and disposal of the product, or from the publication or use of, or
reliance upon, information contained herein. This information relates only to
the product designated herein, and does not relate to its use in combination
with any other material or in any other process.

END OF MSDS




Citric Acid MSDS Page 5 of 5 www.nugentec.com

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