MATERIAL SAFETY DATA SHEET
The Anchor MSDS information provided on this site is updated on a monthly basis and complies with
OSHA鈥檚 Hazard Communication Standard (CFR 1910.1200) and the American National Standards Institute
(ANSI) Standard for Material Safety Data Sheets (ANSI Z400.1).
Finished Goods Catalog
20315 - EMERALD(R) PREMIUM HBR ACID FOUNTAIN SOLUTION
Manufacturer Name
ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT
SECTION 1 - COMPANY IDENTIFICATION
Catalog / Sub-assembly Number: 20315
ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT
50 Industrial Loop North TRANSPORTATION EMERGENCIES (24HR)
Orange Park, FL 32073 Inside US/Canada 800-424-9300
Outside US/Canada 703-527-3887
(accepts collect calls)
MEDICAL EMERGENCIES (24HR)
Prosar 877-935-7387
NON-EMERGENCY
EHS Info 904-264-3500
General Info 800-354-2300
FOR INDUSTRIAL USE ONLY......USE ONLY AS DIRECTED......DO NOT TAKE INTERNALLY!
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients CAS Number Wt.% OSHA PEL ACGIH
(mg/m3) (mg/m3)
Ammonium Nitrate 6484-52-2 0.5-1.5% NE NE
Ethylene Glycol 107-21-1 1-5% 125 C 100 C
Butyl Cellosolve 111-76-2 10-20% 240 skin 96.6 skin
Gum Arabic 9000-01-5 3-7% NE NE
Nonionic Surfactant 2687-94-7 0.5-1.5% NE NE
Propylene Glycol 57-55-6 7-15% NE NE
Water 7732-18-5 50-70% NE NE
NE=Not Established STEL=Short Term Exposure Limit C=Ceiling Limits
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
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Appearance: Clear, green, aqueous liquid
Odor: Mild odor
Avoid contact with eyes, skin or clothing. Avoid breathing mist or vapor. Do
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ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT - 20315 - EMERALD(R) PREMIUM HBR ACID FOUNTAIN SOL
not swallow. Wear chemical safety goggles & neoprene gloves and apron. Wash
thoroughly after handling. Keep container closed when not in use. Use only
with adequate ventilation. May produce hazardous gases under fire
conditions. During emergencies, wear equipment to protect eyes, skin and
respiratory tract. Dike or absorb spills to keep material and run-off from
entering sewer or waterways. Use water spray to cool containers and disperse
vapors. Box may contain multiple containers having multiple components.
Consult all MSDSs.
HMIS: Health: 2 Flammability: 1 Reactivity: 0 Protection: B
NFPA: Health: 2 Flammability: 1 Reactivity: 0 Spec. Haz.: None
Hazard Rating: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
A = Gloves B = Gloves & Goggles C = Gloves, Goggles & Apron
D = Face Shield, Gloves, Goggles & Apron
UN NO: None
DOT GUIDE: ERG Guide 111
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Potential Health Effects:
Skin: Contact causes irritation.
Eyes: Causes irritation.
Inhalation: Irritant to respiratory tract and mucous membranes.
Ingestion: Ingestion of product may cause nausea and vomiting.
Conditions aggravated by exposure:
Allergic reaction to gum arabic may cause respiratory distress and
sensitivity.
N
SECTION 4 - FIRST AID MEASURES
Eye Contact: Immediately flush with COOL water for 15 minutes. Call a physician.
Skin Contact: In case of skin contact; wash with soap and water for 15 minutes. Call a
physician.
Ingestion: In case of ingestion; induce vomiting upon medical advice. Call a physician.
Inhalation: Immediately remove victim to fresh air. Call a physician for further
recommendations.
SECTION 5 - FIRE FIGHTING MEASURES
Flammable Properties
Flash Point: >200 Deg F TCC
Autoignition Temperature: N/A deg F (CC)
Explosion Limits: Lower: N/A vol.%: Not Tested
Upper: N/A vol.%:
Extinguishing Media:
Choose extinguishing media suitable for the surrounding materials, such as
water spray, dry chemical, alcohol foam or carbon dioxide.
Unsuitable Extinguishing Media:
No restrictions on media based on knowledge of this material.
Fire Fighting Instructions:
Water spray should be used to cool fire exposed containers and to disperse
un-ignited vapors. Use NIOSH/MSHA approved positive pressure self-contained
breathing apparatus when material has ignited or becomes involved in a fire.
Try to remove material containers from fire area if can be accomplished
without risk to personnel.
Evacuate area and fight fire from a safe distance. Call your local fire
department. Wear positive pressure, breathing apparatus and protect eyes
and skin. Use water to cool fire-exposed containers, to protect personnel
and to disperse vapors and spills. Fire media run-off can damage the
environment. Dike and collect media used to fight fire.
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ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT - 20315 - EMERALD(R) PREMIUM HBR ACID FOUNTAIN SOL
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Small Spills:
For small incidental spills and leaks wear chemical safety goggles, and
neoprene gloves and apron or coveralls. Isolate area of spill by diking.
Stop source of leak. Add dry absorbent. Clean up and place in an approved
D.O.T. container and seal. Wash all contaminated clothing before reuse, and
discard contaminated leather shoes.
Large Spills:
For larger spills requiring emergency response, neoprene boots and respiratory
protection may also be required. Follow OSHA regulations and NIOSH
recommendations for respirator use (29 CFR 1910.134 and NIOSH Pub. 87-108) and
emergency response (see 29 CFR 1910.120). Isolate area of spill by diking.
Stop source of leak. Add dry absorbent. Clean up and place in an approved
D.O.T. container and seal. Wash all contaminated clothing before reuse, and
discard contaminated leather shoes. Call the emergency telephone number
shown on the front of this sheet.
SECTION 7 - HANDLING / STORAGE
Handling:
Avoid contact with eyes, skin or clothing. Avoid breathing mist or vapor.
Do not swallow. Wear chemical safety goggles and neoprene gloves and apron.
Wash thoroughly after handling. Keep container closed when not in use. Use
only with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from all sources of ignition.
Keep containers closed when not in use.
SECTION 8 - EXPOSURE CONTROL AND PERSONAL PROTECTION
Ventilation:
Good general ventilation should be sufficient for most processing operations.
Vent work area to ensure airborne concentrations are below the current
occupational exposure limits. Ten (10) or more room air changes per hour
containing a minimum of 15% fresh air will meet these requirements. Consult
ASHRAE 62-1989 for further requirements.
Personal Protective Equipment
Respiratory Protection: If used under normal operating conditions and with adequate ventilation,
respiratory protection is not required. However, refer to OSHA 29 CFR 1910.13
4.
Skin Protection: Chemical resistant gloves
Eye Protection: Chemical safety goggles
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, green, aqueous liquid
Odor: Mild odor
Change in Physical State:
Boiling Point: >100 deg C
Melting Point: N/D deg F
Specific Gravity: 1.04 Water=1
Vapour Pressure: ~17 mmHg @ 20C
Viscosity: N/A
Solubility in Water: 100%
pH Value: 4.35
VOC (lbs/gal): 2.92 (USEPA Method 24)
SECTION 10 - STABILITY AND REACTIVITY
Hazardous Polymerization:
Hazardous polymerization WILL NOT occur if product is used and stored as
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ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT - 20315 - EMERALD(R) PREMIUM HBR ACID FOUNTAIN SOL
directed. Product is stable if used and stored as directed.
Hazardous Decomposition Products:
Oxides of Sulfur; Oxides of Carbon; Oxides of Nitrogen; Ammonia
Materials and Conditions to Avoid:
This product contains an ammonia compound. Do not allow this solution to
come in contact with household or industrial bleaches (Sodium
Hypochlorite). Mixing of these chemicals can result in the release of
hazardous or toxic gases. Inhalation of these gases may cause severe
respiratory irritation. Keep containers and liquids away from all
potential sources of ignition. Keep away from excess heat. Avoid contact
with strong oxidizers, strong acids and strong bases.
SECTION 11 - TOXICOLOGICAL INFORMATION
Product Information
LD50 (oral, rat): No Data Available
Acute Overexposure:
Skin, eye, mucous membrane and respiratory tract irritant.
Chronic Overexposure:
Prolonged or repeated skin contact may cause allergic reaction and
dermatitis.
Ingredient information:
Chronic overexposure to Butyl Cellosolve in high concentrations has caused
anemia, liver and blood abnormalities, and kidney and lung damage in
laboratory animals; may cause maternal toxicity.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity Data: No Data Available
Chemical Fate Data: No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Hazardous Waste Characteristic:
None
Recommendation:
Dispose of contaminated product, empty containers and materials used in
cleaning up spills or leaks in a manner approved for this material. Consult
appropriate federal, state and local regulatory agencies to ascertain proper
disposal procedures. Discharge of processing effluent to the sewer may
require a permit. DO NOT discharge effluent solutions to septic systems.
SECTION 14 - TRANSPORTATION INFORMATION
Ground Shipping Information
Proper Shipping Name: Chemicals, N.O.I., Not D.O.T. regulated.
Hazard Class: None
UN/NA Number: None
Packing Group: None
Air (ICAO/IATA) Shipping Information
Proper Shipping Name: Chemicals, N.O.I., Not D.O.T. regulated.
Hazard Class: None
UN No: None
Packing Group: None
Subsidiary Risk: None
UN/DOT Labels Needed: None
International Maritime Organization (IMO) Additional Shipping Class:
IMDG Code: Not Applicable
Amdt. Code: Amdt. N/A
HTS Code: Not Applicable
Product is labeled in accordance with US D.O.T. 49 CFR.
Revision Date - 02/01/2005 Page 4
ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT - 20315 - EMERALD(R) PREMIUM HBR ACID FOUNTAIN SOL
Further information:
Please call (904) 264-3500 for further D.O.T. information.
SECTION 15 - REGULATORY INFORMATION
**Note: The ingredient information listed in this section is provided for
reporting requirements as dictated by USEPA, state and local regulation. If
ingredient is listed in this section but not in Section 2, then the
concentration of this ingredient is below de minumis (less than 0.1%).
U.S. FEDERAL REGULATIONS:
313 = SARA Title III Section 313 (40 CFR 372 -- Toxic Release Inventory)
355 = SARA Title III Section 302 (40 CFR 355 -- Extremely Hazardous Substance)
302 = SARA Title III Section 304 (40 CFR 302 -- Hazardous Substance List)
CWA = Clean Water Act Priority Pollutants List
CAA = Clean Air Act 1990 Hazardous Air Contaminants
HAP = Clean Air Act - HON Rule - HAPs
Ingredients CAS Number 313 355 302 CWA CAA HAP
Ammonium Nitrate 6484-52-2 Y Y Y N N N
Ethylene Glycol 107-21-1 Y N Y N Y Y
Butyl Cellosolve 111-76-2 Y N Y N Y Y
Gum Arabic 9000-01-5 N N N N N N
Nonionic Surfactant 2687-94-7 N N N N N N
Propylene Glycol 57-55-6 N N N N N N
Water 7732-18-5 N N N N N N
TSCA 12(b) Export Notification
CAS NUMBER CHEMICAL NAME
107-21-1 ETHYLENE GLYCOL
26172-55-4 5-CHLORO-2-METHYL-3-ISOTHIAZOLONE
2682-20-4 2-METHYL-3-ISOTHIAZOLONE
TOXICITY INFORMATION:
IRC1 = IARC Group 1 Human Carcinogens List
IRC2 = IARC Group 2 Human Carcinogens List (limited human data)
IRC3 = IARC Group 2B Human Carcinogens List (sufficient animal data)
NTP = NTP Known Carcinogens List
OSHA = OSHA Known Carcinogens List
Ingredients CAS Number IRC1 IRC2 IRC3 NTP OSHA
Ammonium Nitrate 6484-52-2 N N N N N
Ethylene Glycol 107-21-1 N N N N N
Butyl Cellosolve 111-76-2 N N N N N
Gum Arabic 9000-01-5 N N N N N
Nonionic Surfactant 2687-94-7 N N N N N
Propylene Glycol 57-55-6 N N N N N
Water 7732-18-5 N N N N N
STATE REGULATIONS:
FL = Florida Hazardous Substance List MA = Massachusetts Right-To-Know List
MI = Michigan Critical Materials List MN = Minnesota Hazardous Substance List
NJ = New Jersey Right-To-Know List PA = Pennsylvania Right-To-Know List
Ingredients CAS Number PA NJ MN MI MA FL
Ammonium Nitrate 6484-52-2 Y Y Y N Y Y
Ethylene Glycol 107-21-1 Y Y Y N Y Y
Butyl Cellosolve 111-76-2 Y Y Y N Y Y
Gum Arabic 9000-01-5 N Y N N N N
Nonionic Surfactant 2687-94-7 N N N N N N
Propylene Glycol 57-55-6 Y N Y N N N
Water 7732-18-5 N N N N N N
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ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT - 20315 - EMERALD(R) PREMIUM HBR ACID FOUNTAIN SOL
The following designation is used only for those facilities that have air
permits in nonattainment areas for ozone:
Non-Photochemically Reactive
SECTION 16 - OTHER INFORMATION
This information is provided without warranty. The information is believed
to be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.
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