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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: KILZ庐 Odorless
Product Number: 1004 NFPA
Manufacturer Name: Masterchem Industries LLC
Address: 3135 Old Highway M
Imperial MO 63052-2834
2
1 0
U.S. Contact Info.:
Business Phone: (636) 942-2510
Technical Service Phone: (800) 325-3552
Business Fax: (636) 942-3663
HMIS
Canadian Contact Info.:
Business Phone: (800) 661-1591 HEALTH 1
Technical Service Phone: (800) 661-1591
FIRE 2
Business Fax: (403) 273-1128
REACTIVITY 1
For emergencies in the US, call CHEMTREC: 800-424-9300
PPE
In Canada, call CANUTEC: (613) 996-6666 (call collect)
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Product No.
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS 1004
Chemical Name CAS# Lower Percent Upper Percent
Heavy Hydrotreated Naphtha (Petroleum) 64742-48-9 10 30
Nepheline Syenite 37244-96-5 10 30
Titanium dioxide 13463-67-7 5 10
Acrylic polymer Proprietary 5 10
Resin Proprietary 1 5
Triethylene glycol bis(2-ethylhexanoate) 94-28-0 1 5
Palygorskite 12174-11-7 0.1 1
Non-hazardous ingredients 30 60
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Product No.
SECTION 3: HAZARDS IDENTIFICATION 1004
Emergency Overview: Combustible. Irritant.
Applies to all Ingredients
Potential Health Effects:
Eye Contact: May cause irritation.
Skin Contact: May cause irritation.
Skin Absorption: May be absorbed through the skin in harmful amounts.
Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation.
Ingestion: Harmful if swallowed. Ingestion can cause nausea, vomiting, diarrhea and
gastrointestinal irritation.
Chronic Skin Contact: Prolonged or repeated contact can result in defatting and drying of the
skin, which may result in skin irritation and dermatitis (rash).
Chronic Inhalation: Repeated or prolonged inhalation may cause toxic effects.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Central nervous system.
Kidney.
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Aggravation of Pre-Existing May aggravate pre-existing respiratory disorders, allergy, eczema, or skin
Conditions: conditions.
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Product No.
SECTION 4: FIRST AID MEASURES 1004
Eye Contact: Immediately flush eyes with plenty of water for 15 to 20 minutes. Get
medical attention, if irritation or symptoms of overexposure persists.
Skin Contact: Immediately wash skin with soap and plenty of water. Get medical
attention if irritation develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or
give oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious
person.
Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if
ingested. Provide a glass of water to dilute the material in the stomach. If
vomiting occurs naturally, have the person lean forward to reduce the risk
of aspiration.
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Product No.
SECTION 5: FIRE FIGHTING MEASURES 1004
Fire: Combustible liquid.
Flash Point: 104掳F (40掳C)
Flash Point Method: TCC
Upper Flammable or Explosive 7%
Limit:
Lower Flammable or Explosive 1%
Limit:
Extinguishing Media: Use alcohol foam, carbon dioxide, dry chemical, or water fog or spray
when fighting fires involving this material.
Fire Fighting Instructions: Combustible. Cool fire-exposed containers using water spray.
Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Unusual Fire Hazards: Combustible liquid. At elevated temperatures, vapors can form an ignitable
mixture with air. Vapors can flow along surfaces to distant ignition sources
and flash back.
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Product No.
SECTION 6: ACCIDENTAL RELEASE MEASURES 1004
Personal Precautions: Use proper personal protective equipment as listed in section 8.
Spill Cleanup Measures: Remove all sources of ignition. Absorb spill with inert material (e.g., dry
sand or earth), then place in a chemical waste container. Provide
ventilation. Collect spill with a non-sparking tool. Place into a suitable
container for disposal.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
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Product No.
SECTION 7: HANDLING AND STORAGE 1004
Handling: Use with adequate ventilation. Avoid breathing vapor and contact with
eyes, skin and clothing. Material will accumulate static charges which may
cause an electrical spark (ignition source). Use proper grounding
procedures.
Storage: Store in a cool, dry, well ventilated area away from sources of heat,
combustible materials, and incompatible substances. Keep container tightly
closed when not in use.
Work Practices: To reduce potential for static discharge, bond and ground containers when
transferring material.
Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid
inhaling vapor or mist.
Special Handling Procedures: Do not reuse containers without proper cleaning or reconditioning.
Important Storage and DANGER! Rags, steel wool and waste soaked with this product may
Disposal: spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool
or waste in a sealed, water-filled, metal container. Do not store unused
product inside the home. For disposal guidance, contact your household
refuse collection service, fire department, county or state government
environmental control agency.
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Product No.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION 1004
Engineering Controls: Use appropriate engineering control such as process enclosures, local
exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits. Good general ventilation should be
sufficient to control airborne levels. Where such systems are not effective
wear suitable personal protective equipment, which performs satisfactorily
and meets OSHA or other recognized standards. Consult with local
procedures for selection, training, inspection and maintenance of the
personal protective equipment.
Skin Protection Description: Chemical-resistant gloves and chemical goggles, face-shield and synthetic
apron or coveralls should be used to prevent contact with eyes, skin or
clothing.
Hand Protection Description: Wear appropriate protective gloves. Consult glove manufacturer's data for
permeability data.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29
CFR 1910.133, OSHA eye and face protection regulation, or the European
standard EN 166.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge
or canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided
by air purifying respirators is limited. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release, exposure
levels are not known, or any other circumstances where air purifying
respirators may not provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
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Ingredient Guidelines Guideline Type Guideline Information
Titanium dioxide
ACGIH TLV-TWA 10 mg/m3
OSHA PEL-TWA 15 mg/m3
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Product No.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 1004
Physical State/Appearance: Liquid
pH: No Data
Vapor Density: Greater than 1 (Air = 1)
Density: 12 - 14 Lbs./gal.
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: 104掳F (40掳C)
VOC: Material VOC: 329gm/l (Includes Water)"
"Coating VOC: 329 gm/l (Excludes Water)
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Product No.
SECTION 10: STABILITY AND REACTIVITY 1004
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Heat, flames, ignition sources, and sparks. Incompatible materials.
Freezing or temperatures below 32 deg. F.
Incompatibilities with Other Oxidizing agents. Strong acids and alkalis.
Materials:
Hazardous Polymerization: Not reported.
Hazardous Decomposition Incomplete combustion may produce carbon monoxide and other toxic
Products: gases.
Note Refer to Section 7
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Product No.
SECTION 11: TOXICOLOGICAL INFORMATION 1004
Triethylene glycol bis(2-ethylhexanoate)
Skin Effects: Skin - Guinea pig; LD50: >20 mL/kg - Details of toxic effects not reported
other than lethal dose value. (RTECS)
Ingestion Effects: Ingestion - Rat LD50: 31 gm/kg - Behavioral - somnolence (general
depressed activity) Gastrointestinal - other changes Kidney, Ureter,
Bladder - other changes]
Ingestion - Mouse LD50: >3200 mg/kg - Details of toxic effects not
reported other than lethal dose value. (RTECS)
Palygorskite
Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans
Titanium dioxide
Skin Effects: Skin - Rabbit; Standard Draize : 300 ug/3D; (Intermittent) Mild. (RTECS)
Ingestion Effects: Ingestion - Rat TDLo: 60 gm/kg; Gastrointestinal - hypermotility, diarrhea
Gastrointestinal - other changes. (RTECS)
Carcinogenicity: IARC: Group 3: Unclassifiable as to carcinogenicity to humans
Notes Not all of the toxicological studies for the ingredients contained in this
product are displayed. For additional information, please consult the
references listed in Section 16 of this MSDS.
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Product No.
SECTION 12: ECOLOGICAL INFORMATION 1004
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
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Product No.
SECTION 13: DISPOSAL CONSIDERATIONS 1004
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult
with your state and local waste requirements or guidelines, if applicable, to
ensure compliance. Arrange disposal in accordance to the EPA and/or state
and local guidelines.
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool
or waste in a sealed, water-filled, metal container. Do not store unused
product inside the home. For disposal guidance, contact your household
refuse collection service, fire department, county or state government
environmental control agency.
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Product No.
SECTION 14: TRANSPORT INFORMATION 1004
DOT Shipping Name: Paint.
DOT UN Number: UN1263
DOT Hazard Class: 3
DOT Identification Number: UN1263
DOT Packing Group: III
DOT Packing Authorization: 3
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Product No.
SECTION 15: REGULATORY INFORMATION 1004
Heavy Hydrotreated Naphtha (Petroleum)
TSCA 8(b): Inventory Status: Listed
Canada DSL: Listed
Nepheline Syenite
TSCA 8(b): Inventory Status: Not listed
Canada DSL: Listed
Non-hazardous ingredients
TSCA 8(b): Inventory Status: Contains calcium carbonate (CAS:1317-65-3), which is listed in the TSCA
inventory.
Triethylene glycol bis(2-ethylhexanoate)
TSCA 8(b): Inventory Status: Listed
Canada DSL: Listed
Palygorskite
TSCA 8(b): Inventory Status: Not listed
Canada DSL: Not listed
Titanium dioxide
TSCA 8(b): Inventory Status: Listed
State: Listed in the New Jersey State Right to Know list.
Listed in the Pennsylvania Hazardous Subsatnces list.
Canada DSL: Listed
Proposition 65: WARNING: This product contains a chemical known to the State of
California to cause cancer and birth defects or other reproductive harm.
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Product No.
SECTION 16: ADDITIONAL INFORMATION 1004
MSDS Revision Date: "06/26/2006"
MSDS Author: Actio Corporation
Disclaimer:
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific materials designated. Refer to individual
product safety Data sheets when using more than one product in combination with another.
References:
1. OSHA Hazard Communication Standard, 1910.1200 and Z Tables.
2. NIOSH Registry of Toxic Effects of Chemical Substances (RTECS) and Pocket Guide to Chemical Hazards.
3. Sax Dangerous Properties of Industrial Materials. Tenth Edition.
4.Hawleys Condensed Chemical Dictionary, Thirteenth Edition
5. IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, WHO International
Research on Cancer, 2004.
6. Industrial Hygiene and Toxicology, by F.A. Patty.
7. National Library of Medicine, Department of Health and Human Services, Hazardous Substances Data
Bank (HSDB).
8. National Toxicology Program (NTP) Tenth Report on Carcinogens, 2002.
9. Brethericks Reactive Chemical Hazards Database. Version 2.
10. Gassarett and Doulls Toxicology, The Basic Science of Poisons.
11. The Merck Index: An Encyclopedia of Chemicals and Drugs. Merck and Company. Twelfth Edition 1998.
12. Threshold Limit Values for Chemical Substances and Physical Agents in the Work Environmental and
Biological Exposure Indices. TLV Booklet, 2003.
Copyright漏 1996-2006 Actio Software Corporation. All Rights Reserved.
The trademarks, service marks, graphics and logos used on this MSDS are registered or unregistered
trademarks of MasterChem Corporation. All Rights Reserved.
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