MATERIAL SAFETY
DATA SHEET
1. COMPANY AND PRODUCT IDENTIFICATION
DUNCAN ENTERPRISES EMERGENCY TELEPHONE NUMBERS
5673 East Shields Avenue Health Emergency: 559-291-4444 7:00 am 鈥? 3:30 pm
Fresno, CA 93727 Pacific Standard Time
559-291-4444 Spill and Off-Hour
559-291-9444 (Fax) Health Emergencies: 800-424-9300 U.S. and Canada
703-527-3887 Outside U.S. and
Canada (Collect)
Product Name: DUNCAN OG 805 PREMIUM GOLD
Product Category: Solvent - Based Metallic Overglaze
2. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Components OSHA PEL ACGIH TLV CAS # Weight %
Camphor 2 ppm 2 ppm 76-22-2 10 - 15
Organo Chromium
0.5 mg/m3 0.5 mg/m3
Compound (as Cr)* ------------ <1
Cyclohexanol 50 ppm (skin) 50 ppm (skin) 108-93-0 1-5
Cyclohexanone 50 ppm 25 ppm 108-94-1 1-5
*o-Dichlorobenzene 50 ppm (C) 25 ppm 95-50-1 1-5
Turpentine 100 ppm 100 ppm 8006-64-2 5 - 10
Other Information
*Withheld as a trade secret
(C) Ceiling Limit Value
3. HAZARDS IDENTIFICATION
HMIS Hazard Ratings for Product
Health: 3* 0 = Minimal
Flammability: 4 1 = Slight
Reactivity: 0 2 = Moderate
Personal Protection: See Section 8 3 = Serious
4 = Severe
* = Chronic Effects
Routes of Exposure
Exposure may be by inhalation and / or skin or eye contact, depending on conditions of use. To minimize
exposure, follow recommendations for proper use, ventilation, and personal protective equipment.
Effects of Overexposure
Irritation of eyes, skin, and upper respiratory system. May cause nervous system depression. Extreme
overexposure may result in unconsciousness and possibly death.
Signs and Symptoms of Overexposure
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or
spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure.
Cancer Information
For complete discussion of toxicology data refer to Section 11.
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Duncan Enterprises Material Safety Data Sheet 鈥? OG 805 Premium Gold
4. FIRST AID MEASURES
Eye contact: Rinse with clean water or saline solution for at least 15 minutes. Seek medical advice if
irritation persists.
Skin contact: Remove contaminated clothing and wash skin with soap and water. Wash or clean
before reuse.
Inhalation: Remove from exposure to fresh air. Give artificial respiration if not breathing.
If breathing is difficult, give oxygen. Contact a physician immediately.
Ingestion: Rinse mouth with water and give water or milk to drink. Do not induce vomiting. Do not
give anything by mouth to an unconscious person. Contact a physician immediately.
5. FIRE FIGHTING MEASURES
Flash Point: 118掳 F (48掳 C) Setaflash Closed Cup
Flammable Limits LEL : N/A UEL : N/A
Extinguishing Media
CO2, dry chemical or Chemical Foam. Water may be ineffective, but may be used to control exposed
containers.
Special Fire Fighting Procedures
Fire Fighters should wear NIOSH/MSHA approved pressure demand self-contained breathing apparatus.
Unusual Fire And Explosion Hazards
Toxic fumes of metals and vapors may be evolved in a fire.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Released Or Spilled
Use appropriate personal protective equipment during clean up operations. Promptly absorb spill using
inert materials such as sand, vermiculite or sawdust. Remove all sources of ignition. Cover drains to
prevent entry into waterways. If a Reportable Quantity is exceeded for any ingredients, contact the
National Response Center.
7. HANDLING AND STORAGE
Precautions To Be Taken In Handling And Storing
Store in sealed containers in a cool, dry place. Keep away from heat, open flame, and sources of
ignition. Store as flammable liquid.
Other Precautions
Follow good industrial hygiene and housekeeping practices. Do not eat, drink or smoke while using this
material. After using product, wash hands before eating, drinking, smoking, or applying cosmetics, and at
the end of the work shift. Avoid contact with eyes, skin, or clothing.
8. EXPOSURE CONTROL AND PERSONAL PROTECTION
Respiratory Protection (Specify Type)
If there is a possibility that the TLVs or PELs may be exceeded, a NIOSH/MSHA approved respirator with
organic vapor cartridge represents the minimum level or respiratory protection. To insure proper
respirator selection and use, refer to the requirements of 29 CFR 1910.134 and the latest edition of ANSI
Z 88.2.
Ventilation
Local Exhaust: Fume hood at point of generation with sufficient exhaust
Mechanical (General): Must be sufficient to remove vapors from breathing zone
Protective Gloves: Solvent impermeable gloves
Eye Protection: Safety glasses or goggles
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8. EXPOSURE CONTROL AND PERSONAL PROTECTION (Continued)
Other Protective Clothing
Or Equipment: Eye bath and safety shower.
Work/Hygienic Practices: Wear disposable protective clothing to facilitate recovery of any materials
spilled. Use adequate ventilation.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor: Brown liquid with characteristic odor
Specific Gravity (Water = 1): >1
Boiling Point: N/A
Evaporation Rate (butyl acetate = 1): > 1 (Slower than Butyl Acetate)
Melting Point: N/A
Vapor Density (Air = 1): > 1 (Heavier than air)
Vapor Pressure: N/A
Water Solubility, %: Insoluble
Percent Volatiles by Volume: Not less than 25%
PH: N/A
Flash Point: 118掳 F (48掳 C) (Setaflash Closed Cup)
10. STABILITY AND REACTIVITY
Stability Unstable: Stable: X
Conditions To Avoid
Avoid heating substance where it may be inhaled, open flames, oxidizers and sources of ignition. Solvent
vapors are heavier than air and can accumulate, travel to sources of ignition and flash back.
Incompatibility (Materials To Avoid)
Oxidizers such as chlorates, perchlorates, permanganates, and nitrates. If the preparation comes into
contact with ammonia, explosive gold compounds may be formed. Ammoniacal gold solutions should
never be stored.
Hazardous Decomposition or Byproducts
Carbon dioxide, carbon monoxide, hydrochloric acid, oxides of sulfur and carbonaceous fumes.
Hazardous Polymerization May Occur: Will Not Occur: X
11. TOXICOLOGICAL INFORMATION
Routes of entry under normal conditions of use
Eyes: No Inhalation: Yes Skin: Yes Ingestion: No
Toxicological Information:
There is no specific toxicological data available for this preparation. Any toxicological information is
based on individual components that make up this material.
Target Organ Effects:
Camphor 鈥? Central nervous system, eye, skin, respiratory system
Chromium compounds 鈥? Skin
Cyclohexanol 鈥? Eyes, skin, respiratory system
Cyclohexanone 鈥? Eyes, skin, respiratory system, central nervous system
0-dichlorobenzene 鈥? Respiratory system, gastrointestinal tract
Turpentine 鈥? Skin, eyes, kidneys, respiratory system
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Duncan Enterprises Material Safety Data Sheet 鈥? OG 805 Premium Gold
11. TOXICOLOGICAL INFORMATION (Continued)
Carcinogenicity:
The following chemicals are listed as carcinogens by NTP, IARC, and / or OSHA:
Chromium Compounds (NTP)
Effects of Overexposure:
Eyes: Short-term liquid or vapor contact may result in slight eye irritation. Prolonged and repeated
contact may be more irritating.
Skin: Prolonged and repeated liquid contact can cause defatting and drying of the skin, which may result
in skin irritation and dermatitis.
Inhalation: Solvents can act as central nervous system depressants, exhibiting narcotic and anesthetic
effects. Overexposure to some of these components may cause headaches, nausea, vomiting,
drowsiness, diarrhea, liver and kidney damage.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method
Return accumulated residues to refinery for metals recovery. Follow local, state and federal regulations
for packaging, labeling, manifesting, transportation and disposal.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Information
DOT Shipping Name: Consumer Commodity ORM-D
DOT Hazard Class: Glazes or Stains OA/OG 88690 Sub. 1
U.N. Number: 1950
15. REGULATORY INFORMATION
TSCA Certification
All chemicals in this product are listed, or are exempt from listing, on the TSCA inventory.
SARA Title III Section 313 Reportable Chemicals:
Chromium Compounds
o-Dichlorobenzene
This product contains one or more components which are subject to government restrictions concerning
use. Therefore, this product is to be used only for the applications specified below:
1. Ceramic decorative paint for use in the pottery, glass or ceramic industry
2. Electronic Circuitry
Should you re-sell this product to a processor or industrial user, advise them of this restriction.
Right to Know Information
Component CAS #
Camphor 76-22-2
Chromium Octanoate 20195-23-7
Cyclohexanol 108-93-0
Cyclohexanone 108-94-1
Monochlorobenzene 108-90-7
o-Dichlorobenzene 95-50-1
Turpentine 8006-64-2
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Duncan Enterprises Material Safety Data Sheet 鈥? OG 805 Premium Gold
15. REGULATORY INFORMATION (Continued)
Right to Know Information (Continued)
Component
Resin TSRN 80100353-5039p
Resin TSRN 80100353-5010p
Reodorant TSRN 80100419-5016p
Organo Gold Compound TSRN 80100353-5030p
Terpene Hydrocarbon TSRN 80100419-5028p
California Proposition 65
WARNING: Cyclohexanol is known to the State of California to cause male reproductive harm.
Products bearing the Caution Label are certified to be properly labeled in a program of
toxicological evaluation by a nationally recognized toxicologist. The products are certified
by the toxicologist to be labeled in accordance with the chronic hazard labeling standard
ASTM D-4236.
16. OTHER INFORMATION
References:
Barclays California Code of Regulations
NIOSH Pocket Guide to Chemical Hazards
The Sigma Aldrich Library of Regulatory and Safety Data
29 CFR 1910.1000, Z-tables
ACGIH TLV for Chemical Substances and Physical Agents
Table of Abbreviations
ACGIH American Conference of Governmental Industrial Hygienists
AICS Aboriginal Independent Community Schools
ANSI American National Standards Institute
ASTM American Society for Testing Materials
掳C Degrees Centigrade
CAS Chemical Abstract Service
CERCLA Comprehensive Environmental Response, Compensation and Liability Act
CFR Code of Federal Regulations
CPR Controlled Products Regulations
DOT Department of Transportation
DSL Domestic Substances List
ECL Education Counseling Service
EINECS European Inventory of Existing Commercial Chemical Substances
ENCS Existing and New Chemical Substances
EPA Environmental Protection Agency
掳F Degrees Fahrenheit
FDA Food & Drug Administration
Hg Mercury
HMIS Hazardous Materials Identification System
IARC International Agency for Research on Cancer
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMO International Maritime Organization
LD Lethal Dose
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Duncan Enterprises Material Safety Data Sheet 鈥? OG 805 Premium Gold
16. OTHER INFORMATION (Continued)
Table of Abbreviations (Continued)
mg / kg Milligram per kilogram
MITI Ministry of International Trade and Industry
mm Millimeter
MSDS Material Safety Data Sheet
MSHA Mine Safety and Health Administration
N/A Not Applicable
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
ppm Parts per million
SARA Superfund Amendment and Reauthorization Act
STEL Short-Term Exposure Limit
TDG Transport Dangerous Goods
TSCA Toxic Substances Control Act
TWA Time - Weighted Average
U.N. United Nations
WHMIS Workplace Hazardous Materials Information System
> Greater Than
< Less Than
Creation Date: 05/98
Revision Date: 06/23/05
Technical Contact: Candi Prado
Senior R&D Specialist
Duncan Enterprises
5673 East Shields Avenue
Fresno, CA 93727
559-291-4444
559-291-9444 (Fax)
Disclaimer
The information given and the recommendations made herein apply to our product(s) alone and
not combined with any other product(s). Such are based on our research and on data from other
reliable sources and are believed to be accurate. No guarantee of accuracy is made. It is the
purchaser鈥檚 responsibility before using any product to verify this data under their own operating
conditions and to determine whether the product is suitable for their purposes.
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