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Material 24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Safety Transportation:
1-800-535-5053
1-352-323-3500
Data
Sheet
NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales est谩 disponible en franc茅s canadiense y en espa帽ol a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Floor Tile Adhesive Revision Date: 03/24/2004
Product UPC 7079800136, 7079800137, 7079800139, Supercedes: 03/04/1999
Number: 7079872044, 7079872042, 7079872040
Product Use/Class: Latex Floor Covering Adhesive MSDS Number: 00077272001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 (non-emergency matters)
Section 2 - Composition / Information On Ingredients
Chemical Name CASRN WT% ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
Petroleum hydrocarbon oil 64742-52-5 10 -30 N.E. N.E. N.E. N.E. N.E. N.E. No
Kaolin 1332-58-7 3-7 2 MGM3 N.E. N.E. N.E. N.E. N.E. No
Urea 57-13 -6 1-5 N.E. N.E. N.E. N.E. N.E. N.E. No
Ethylene glycol 107-21-1 1-5 N.E. N.E. 100 MGM3 N.E. N.E. N.E. No
Silica, crystalline 14808-60-7 <0.06 0.05 MGM3 N.E. N.E. N.E. N.E. N.E. No
Exposure Notes:
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices
Section 3 - Hazards Identification
Emergency Overview: A Tan Liquid product. WARNING! Causes eye, skin, nose, throat, lung and respiratory
tract irritation. Harmful or fatal if swallowed. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
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Effects Of Overexposure - Eye Contact: May cuses eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Prolonged or repeated contact with skin
may cause irritation.
Effects Of Overexposure - Inhalation: Vapors may be irritating to eyes, nose, throat, and lungs.
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause
gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. If ingested, may
cause vomiting, diarrhea, and depressed respiration. Aspiration of material into the lungs due to vomiting can
cause chemical pneumonitis, which can be fatal.
Effects Of Overexposure - Chronic Hazards: Overexposure may cause kidney, cardiovascular, skin and liver
damage. Prolonged or repeated contact with skin results in irritation and dermatitis. Studies have shown that
repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: None known.
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention immediately.
First Aid - Skin Contact: Wash off with soap and water.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: No Information.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the
above routes of entry.
Section 5 - Fire Fighting Measures
Flash Point, F: >212 Lower Explosive Limit, %: Not Established
Method: ( Seta Closed Cup) Upper Explosive Limit, %: Not Established
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
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Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Wet dried material before scraping up and place into containers.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! Provide fresh air such that chemical odors cannot be
detected during use and while drying. Avoid breathing vapors. Use in well ventilated area. Do not sand, dry
sweep, dry scrape, drill, saw, beadblast, mechanically chip, pulverize or otherwise machine existing resilient
flooring, backing, lining felt, or asphaltic "cut-back" adhesives. These products may contain either asbestos fibers
or crystalline silica. Avoid creating dust. Inhalation of such dust is a cancer and respiratory tract hazard. See
current edition of the Resilient Floor Covering Institute's publication. "Recommended Work Practices for Removal
of Resilient Floor Coverings", for detailed information and instructions addressed to the task of removing all
resilient floor covering materials. Avoid contact with eyes, skin and clothing. Construction and repair activities can
adversely affect indoor air quality. Consult with occupants or a representative (i.e. maintenance, building
manager, industrial hygienist, or safety officer) to determine ways to minimize impact. Wash thoroughly after
handling.
Storage: Store containers away from excessive heat and freezing. Keep containers tightly closed. Store away
from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Use only in well-ventilated areas. Provide sufficient general and/or local exhaust
ventilation to maintain exposure below recommended exposure limit.
Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator's use. Respirator use is not
expected to be necessary under normal conditions of handling. In emergency situations, use of a NIOSH-
approved respirator may be required.
Skin Protection: Wear rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: None.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Although this product is not
considered and eye irritant, inhalation hazard, or a skin contact hazard under normal conditions, it is advisable
that personnel minimize shin contact, inhalation of vapors, and eye contact.
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Very Slight Ammonia Odor Threshold: Not Established
Appearance: No Data Available Evaporation Rate: Slower Than n-Butyl Acetate
Solubility in H2O: Not Established Specific Gravity: 1.042
Freeze Point: Not Established pH: Between 7.0 and 12.0
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Paste
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
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(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under normal conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
57-13-6 Urea Rat:8471 mg/kg -------------
107-21-1 Ethylene glycol Rat:4700 mg/kg Rat:10876 mg/kg
106-99-0 1,3-Butadiene ------------- Rat:285 gm/m3/4H
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
14808-60 -7 Silica, crystalline Suspected human carcinogen. ----- ----- Known carcinogen.
106-99-0 1,3-Butadiene Suspected human carcinogen. Cancer hazard. Probable carcinogen. Known carcinogen.
140-88-5 Ethyl acrylate ----- ----- Possible carcinogen. -----
50-00-0 Formaldehyde Suspected human carcinogen. Potential cancer hazard. Probable carcinogen. Anticipated carcinogen.
Significant Data with Possible Relevance to Humans: None
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None
Section 14 - Transportation Information
DOT Proper Shipping None Packing Group: N.A.
Name:
DOT Technical Name: None Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: None
Section 15 - Regulatory Information
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CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Ethylene glycol 107-21-1
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
None
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
None
California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name CAS Number Definition Date Listed
Silica, crystalline 14808-60-7 Carcinogenic. Listed: October 1, 1988
1,3-Butadiene 106-99-0 Carcinogenic. Listed: April 1, 1988
Ethyl acrylate 140-88-5 Carcinogenic. Listed: July 1, 1989
Formaldehyde 50-00-0 Carcinogenic. Listed: January 1, 1988
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm.
None
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Section 16 - Other Information
HMIS Ratings:
Health: Flammability: 1 Reactivity: 0 Personal Protection: 0
VOLATILE ORGANIC COMPOUNDS, GR/LTR: 26.8 LB/GAL: 0.2 WT%: 1.643
REASON FOR REVISION:
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
STEL 鈥? Short Term Exposure Limit CEIL 鈥? Ceiling Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit C 鈥? Degree Celcius
MSDS 鈥? Material Safety Data Sheet CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.
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