Product Name: Duro(R) White Appliance Touch-up Page 1 of 7
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 07
Duro(R) White Appliance Touch-up
80229
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: 80229
Part No.: PG-10
Product Type: Paint & Varnish
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
XYLENES* 1330-20-7 20-25
n-BUTYL ACETATE 123-86-4 15-20
ISOPROPYL ALCOHOL 67-63-0 5-10
ETHYL ALCOHOL 64-17-5 1-5
ETHYL BENZENE* 100-41-4 1-5
n-BUTANOL* 71-36-3 1-5
Light aromatic solvent naphtha 64742-95-6 1-5
2-BUTOXYETHANOL* 111-76-2 1-5
Butoxyethyl acetate* 112-07-2 1-5
PSEUDOCUMENE* 95-63-6 1-5
TITANIUM DIOXIDE 13463-67-7
Phthalate ester 26761-40-0
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
XYLENES 100 ppm TWA 100 ppm TWA None
434 mg/m3 435 mg/m3
n-BUTYL ACETATE 150 ppm TWA 150 ppm TWA None
713 mg/m3 710 mg/m3
ISOPROPYL ALCOHOL 400 ppm TWA 400 ppm TWA 400 ppm TWA
983 mg/m3 980 mg/m3 DuPont AEL
ETHYL ALCOHOL 1000 ppm TWA 1000 ppm TWA None
1880 mg/m3 1900 mg/m3
ETHYL BENZENE 100 ppm 100 ppm None
434 mg/m3 435 mg/m3
n-BUTANOL 50 ppm ceiling 50 ppm ceil-skn None
152 mg/m3 ceil 150 mg/m3 ce-sk
Light aromatic solvent naphtha 5mg/m3 TWA mist 5mg/m3 TWA mist None
2-BUTOXYETHANOL 25 ppm TWA skin 50 ppm TWA skin None
121mg/m3 skin 120mg/m3 skin
PSEUDOCUMENE 25ppm 25ppm None
TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 07
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Item No.: 80229
2. COMPOSITION, INFORMATION ON INGREDIENTS (continued)
5 mg/m3 resp
Phthalate ester
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
XYLENES 150 ppm 150 ppm
651 mg/m3 655 mg/m3
n-BUTYL ACETATE 200 ppm 200 ppm
950 mg/m3 950 mg/m3
ISOPROPYL ALCOHOL 500 ppm 500 ppm
1230 mg/m3 1225 mg/m3
ETHYL BENZENE 125 ppm 125 ppm
543 mg/m3 545 mg/m3
Light aromatic solvent naphtha 10 mg/m3 mist None
TITANIUM DIOXIDE
Phthalate ester
3. HAZARDS IDENTIFICATION
Toxicity: EYE: This material can cause severe eye irritation
redness, tearing or blurred vision.
SKIN: This product may cause skin irritation. This
material may cause skin irritation. Prolonged or
repeated contact may cause redness, burning,
defatting or dermatitis. This product is not known
to be a skin sensitizer. Components of this
product can be absorbed through the skin in toxic
amounts.
INHALATION: This material may cause nasal or
respiratory irritation. Symptoms include central
nervous system depression characterized by
headache, dizziness, fatigue, loss of coordination
nausea, unconciousness or even asphyxiation.
INGESTION: Can cause gastrointestinal irritation,
nausea, vomiting or diarrhea. Aspiration of
material into lungs (during swallowing or
vomiting) can cause chemical pneumonitis which can
be fatal.
CHRONIC HAZARDS: Components of this product have
been found to cause the following in laboratory
animals: CNS damage, Liver abnormalities, Kidney
damage, Eye damage, Lung damage, Spleen damage,
Brain damage, Anemia, Blood changes. Components
of this product have been suggested as a cause of
liver abnormalities, eye and CNS damage in humans.
Components of this product have been suggested as
a cause of cardiac abnormalities and CNS damage in
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 07
Item No.: 80229
3. HAZARDS IDENTIFICATION (continued)
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humans.
Primary Routes of Entry: Skin contact, skin absorption, inhalation,
ingestion and eye contact.
Signs and Symptoms
of Exposure: See TOXICITY
Existing Conditions
Aggravated by Exposure: Preexisting eye, skin and respiratory disorders
may be aggravated by exposure to this product.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
XYLENES AC4 CAR CNS IRR KID LIV NO NO NO
n-BUTYL ACETATE AC4 CNS IRR NO NO NO
ISOPROPYL ALCOHOL ALG CNS IRR NO N/A NO
ETHYL ALCOHOL AC4 CNS IRR NO N/A NO
ETHYL BENZENE CNS IRR NO NO NO
n-BUTANOL CNS EAR IRR NO NO NO
Light aromatic solvent naphtha No Data NO NO NO
2-BUTOXYETHANOL BLO CNS IRR NO NO NO
Butoxyethyl acetate No Data NO NO NO
PSEUDOCUMENE IRR LUN NER NO NO NO
TITANIUM DIOXIDE AC4 IRR NUI
Phthalate ester
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc.
ALG Allergen BLO Blood
CAR Cardiac CNS Central nervous system
EAR Ear IRR Irritant
KID Kidney LIV Liver
LUN Lung NER Nervous System
NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: If swallowed, DO NOT INDUCE VOMITING. Keep head
below hips. Get immediate medical attention.
Inhalation: Remove from exposure. Restore breathing. Keep
warm and quiet. Notify a physician.
Skin Contact: Remove from skin using soap and water. Remove and
launder contaminated clothing.
Eye Contact: Flush immediatley with copious quantities of
running water for at least 15 minutes. Take to a
physician for definitive medical treatment.
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 07
Item No.: 80229
5. FIRE FIGHTING MEASURES
Flash Point: 48掳F Method: SetaFlash Closed Cup
Recommended
Extinguishing Agents: Alcohol foam, carbon dioxide, dry chemical, foam,
water, fog.
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Special Firefighting
Procedures: Use full protective equipment, including self-
contained breathing apparatus with full face
shield and positive pressure mode to protect
firefighters from hazardous combustion products.
Hazardous Products formed
by Fire or Thermal Decomp Toxic fumes such as CO, CO2, or various
hydrocarbons.
Unusual Fire or
Explosion Hazards: Product is flammable and may be ignited by heat,
flame, sparks or static discharge. Product vapors
are heavier than air and may travel along floor to
be ignited (by smoking, heaters, electric motors,
pilot lights, etc.) at locations distant from
material handling point. Closed containers may
explode when exposed to extreme heat.
Explosive Limits:
(% by volume in air)Lower 0.5%
(% by volume in air)Upper 19.0%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Remove all sources of ignition (flames, hot
surfaces, and electrical, static or frictional
sparks. Avoid breathing vapors. Dike area to
prevent material from entering drains or sewers.
Remove with inert absorbent.
7. HANDLING AND STORAGE
Safe Storage: Do not store above 120掳F. Keep containers tightly
closed. Store large quantities in buildings
designed to comply with OSHA 1910.106.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Keep away from open flame. Warnings apply to
empty containers.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Use safety eyewear designed to protect against
splash of liquid. DO NOT use this material while
wearing contact lenses.
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 07
Item No.: 80229
8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued)
Skin: Gloves made of impervious material are recommended
for prolonged or repeated contact with this
product.
Ventilation: Provide local exhaust ventilation/general dilution
in volume and pattern to keep TLV and LEL of most
hazardous ingredient below limits. Heavy solvent
vapors should be removed from lower levels of
area.
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Respiratory In open areas use NIOSH approved mechanical
respirator to remove solid airborne particles of
overspray during spray application. In restricted
ventilation areas use NIOSH approved chemical and
mechanical filters designed to remove a
combination of particulate and vapor. In confined
areas use NIOSH approved air line type respirator
or hood.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Paint
Odor: Hydrocarbon
Boiling Point: 167 - 379掳F
pH: Not applicable
Solubility in Water: Negligible
Specific Gravity 1.0340
Volatile Organic Compound
(EPA Method 24) Not available
Vapor Pressure: Not determined
Vapor Density: Is heavier than air
Evaporation Rate
(Ether = 1) Is faster than Butyl Acetate
10. STABILITY AND REACTIVITY
Stability: This product is stable under normal storage
condition.
Hazardous Polymerization: Will not occur under normal conditions.
Incompatibility: Strong oxidizing agents.
Conditions to Avoid: None established.
Hazardous Decomposition
Products (non-thermal): None
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 07
Item No.: 80229
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Dispose of in accordance with local, state and
federal regulations. Do not incinerate closed
containers. Before attempting clean up, refer to
hazard caution information in other sections of
this sheet.
EPA Hazardous Waste
Number D001
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14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity (Not more than one liter);
Paint (More than one liter)
Hazard Class or
Division: ORM-D (Not more than one liter);
Class 3, Packing Group II (More than one liter)
Identification Number: None (Not more than one liter);
UN 1993 (More than one liter)
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than 500 ml);
Paint (More than 500 ml)
Class or Division: Class 9 (Not more than 500 ml);
Class 3, Packing Group II (More than 500 ml)
UN or ID Number: ID 8000 (Not more than 500 ml);
UN 1263 (More than 500 ml)
15. REGULATORY INFORMATION
CA Proposition 65: No Proposition 65 chemicals known to be present
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 3
Reactivity Hazard: 1
Specific Hazard: Does not apply
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 07 of 07
Item No.: 80229
16. OTHER INFORMATION (continued)
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 3
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: C. J. Michaels
Title: Health and Safety
Company: Loctite Corp.,
1001 Trout Brook Crossing, Rocky Hill, CT 06067.
(24hr.) Phone: (860) 571-5100
Revision Date: October 01, 1997 Revision: First Issue
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