MSDS Number: 111 27X38, CLEAR WOOD FINISH INT. SEMI-GLOSS Printing Date: 04/21/2006 Page 1 of 5
Material Safety Data Sheet
For Coatings, Resins and Related Materials
NOTE: 聽 CHEMTREC, CANUTEC and National Response Center emergency numbers to be used only in the event of
chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals
24 Hour Emergency:聽 1-800-123-4567 CHEMTREC:聽 1-800-424-9300
National Response in Canada聽 CANUTEC:聽 613-996-6666
Outside U.S. and Canada聽 Chemtrec: 聽 202-483-7616
Section 1 - Chemical Product / Company Information
27X38, CLEAR WOOD FINISH INT. SEMI-
Product Name: Revision Date: 12/02/2005
GLOSS
Identification Number: 111 Print Date: 04/21/2006
聽 聽
Product Use/Class: LACQUER
Manufacturer: Deft, Inc.聽 (CAGE CODE 33461) Information Phone: (949) 474-0400
17451 Von Karman Ave Emergency Phone: (800) 424-9300
Irvine, Ca.聽 92614
Section 2 - Hazards Identification
*** Emergency Overview ***:聽 Harmful by inhalation, in contact with skin, and if swallowed. Opaque liquid with solvent
odor. May cause eye burns. Flammable liquid. Contact with eyes or skin causes irritation.
Effects Of Overexposure - Eye Contact: 聽 May cause swelling of the conjunctiva, corneal injury, or burns to the eye. Direct
eye contact may cause irritation. Contact may cause excessive blinking and tear production or damage to the conjunctiva.
Exposure to liquid, aerosol, or vapors may cause irritation, tearing, redness, and swelling accompanied by a stinging
sensation.
Effects Of Overexposure - Skin Contact: 聽 Prolonged and repeated skin contact may cause dermatitis, drying, and defatting
due to the solvent properties. Symptoms may include swelling, redness, and rash. Direct skin contact may cause irritation.
Product may be absorbed through the skin. Repeated skin contact may cause absorption through the skin, which may cause
a coma. The severity of the coma depends on the amount of product absorbed through the skin or ingested.
Effects Of Overexposure - Inhalation: 聽 Exposure may cause nausea and vomiting. Inhalation may cause irritation to the
respiratory tract (nose, mouth, mucous membranes) & acute nervous system depression characterized by the following
progressive steps: headache, dizziness, staggering gait, confusion, unconsciousness, or coma. Exposure may cause
coughing, chest pain, nasal discomfort, and discharge. Exposure may cause drowsiness. Inhalation may cause headaches,
difficult breathing, and loss of consciousness.
Effects Of Overexposure - Ingestion:聽聽 Ingestion may cause gastrointestinal irritation, abdominal pain, nausea, vomiting
and diarrhea. Ingestion may cause decreased body temperature and blood pressure, drowsiness, headache, kidney failure,
hemolytic anemia, shock, coma, or death. Ingestion may cause a sore throat. Vomiting may cause aspiration of the solvent,
resulting in chemical pneumonitis. May result in possible corrosive action in the mouth, stomach tissue and digestive tract.
Exposure to large doses may cause abdominal spasms.
Effects Of Overexposure - Chronic Hazards:聽 Overexposure has been shown to cause mild and reversible liver effect in lab
animals. May cause chemical pneumonitis, cyanosis, or pulmonary edema. Exposure to a component's vapors caused
damage to the lining of the middle ear in animal studies. The relevance of these findings is uncertain in humans. Exposure
may cause loss of coordination, confusion, slowed heart rate, effects on the liver and spleen, respiratory depression, lung
edema, kidney damage, mild temporary changes to the liver, low blood pressure, or coma. WARNING: This product
contains a chemical known to the state of California to cause cancer. Prolonged contact will cause drying and cracking of
the skin, due to defatting action. Skin sensitization, asthma or other allergic responses may develop. Contains components
listed as a Carcinogen: NTP? : No, IARC Monographs? : Yes, OSHA Regulated? : No. Preexisting liver or kidney disease
may be aggravated by repeated or prolonged exposure.
Primary Route(s) Of Entry:聽 Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
Section 3 - Composition / Information On Ingredients
Component CAS Number Weight % Reporting Ranges
ALIPHATIC HYDROCARBON 8052-41-3 10-30
ISOBUTYL ISOBUTYRATE 97-85-8 10-30
METHYL n-AMYL KETONE 110-43-0 7-13
2-BUTOXYETHANOL 111-76-2 7-13
VM & P NAPHTHA 64742-89-8 5-10
NITROCELLULOSE 9004-70-0 3-7
n-BUTYL ALCOHOL 71-36-3 3-7
XYLENE 1330-20-7 1-5
ISOPROPANOL ANHYDROUS 67-63-0 1-5
ZINC STEARATE 557-05-1 1-5
NITROCELLULOSE 9004-70-0 1-5
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ETHYL BENZENE 100-41-4 0.1-1.0
ISOBUTYL ALCOHOL 78-83-1 0.1-1.0
ETHYL BENZENE 100-41-4 0.1-1.0
聽
THE ABOVE LISTED PRODUCTS ARE ON THE TSCA INVENTORY LIST.聽 ALSO ANY UNLISTED INGREDIENTS.
聽
Section 4 - First Aid Measures
First Aid - Eye Contact:聽 If material gets into eyes, flush with water immediately for 15 minutes. Consult a physician. Hold
eyelids open to rinse out the entire eye. If eyes are irritated from airborne exposure, move to fresh air.
First Aid - Skin Contact:聽 In case of contact, immediately flush skin with plenty of water and wash affected areas
thoroughly with soap and water. Remove contaminated clothing and shoes.
First Aid - Inhalation:聽 Asthmatic type symptoms may develop and maybe immediate or delayed by several hours. In the
case of inhalation of aerosol/mist consult a physician, if necessary. Move to fresh air in case of accidental inhalation of
vapors. Give oxygen, if needed.
First Aid - Ingestion:聽 Do not induce vomiting. Do not give anything to an unconscious person. Obtain medical help.
Section 5 - Fire Fighting Measures
Flash Point (掳F): 53 TCC LOWER EXPLOSIVE LIMIT (%): UPPER EXPLOSIVE LIMIT (%): N.D.
N.D.
Extinguishing Media: Alcohol Foam, Carbon Dioxide, Dry Chemical, Foam, Water Fog, Water Spray, Dry Sand
Unusual Fire And Explosion Hazards: To avoid ignition of vapors by static electricity discharge, all metal parts of the
equipment must be grounded. Toxic gases may form when product burns. Application to hot surfaces requires special
precautions. Isolate from heat, sparks, electrical equipment and open flame. Keep containers tightly closed. Flammable
liquid. Vapors can form an ignitable mixture with air. Vapors can flow along surfaces to a distant ignition source and
flashback. Fire or intense heat may cause violent rupture of packages. Do not use a cutting or welding torch near or on a
drum of product, because vapors can ignite explosively, even if the drum is empty and contains only product residue.
Remove all sources of ignition.
Special Firefighting Procedures: In the event of fire, wear self-contained breathing apparatus. Flammable. Cool fire-exposed
containers using water spray. Firefighters should wear full protective clothing.
Section 6 鈥? Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Dike to prevent entering any sewer or waterway. Evacuate all non-
essential personnel. Remove all sources of ignition. Ventilate area. Contain and remove spilled material with inert
absorbent and non-sparking tools. Use personal protective equipment as necessary.
Section 7 - Handling and Storage
Handling: Protect container against physical damage. Use only in ventilated areas. Open doors and windows. Handle in
accordance with good industrial hygiene and safety practice. Keep product and empty containers away from heat, hot
surfaces, open flame, and other sources of ignition. Preparation may charge electrostatically: always use grounding leads
when transferring from one container to another.
Storage: Avoid storing near high temperatures, fire, open flames, and spark sources. Keep containers upright to prevent
leakage and tightly closed in a dry, cool and well-ventilated place. Under oxidizing conditions peroxides of unknown
stability may form. Concentrated peroxides are an explosion hazard. Store in buildings designed to comply with OSHA
1910.106.
Section 8 - Exposure Controls / Personal Protection
Component ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL
ALIPHATIC HYDROCARBON N.E. N.E. N.E. N.E.
ISOBUTYL ISOBUTYRATE N.E. N.E. N.E. N.E.
METHYL n-AMYL KETONE 50 ppm N.E. 100 ppm N.E.
2-BUTOXYETHANOL 25 ppm N.E. 25 ppm N.E.
VM & P NAPHTHA 300 ppm N.E. 300 ppm 400 ppm
NITROCELLULOSE HAZARD - N.E. HAZARD - N.E. HAZARD - N.E. HAZARD - N.E.
n-BUTYL ALCOHOL 20 ppm N.E. 50 ppm N.E.
XYLENE 100 ppm 150 ppm 100 ppm N.E.
ISOPROPANOL ANHYDROUS 400 ppm 500 ppm 400 ppm 500 ppm
ZINC STEARATE N.E. N.E. 15 mg/m3 N.E.
NITROCELLULOSE HAZARD - N.E. HAZARD - N.E. HAZARD - N.E. HAZARD - N.E.
ETHYL BENZENE 100 ppm 125 ppm 100 ppm 125 ppm
ISOBUTYL ALCOHOL 50 ppm N.E. 50 ppm N.E.
ETHYL BENZENE 100 ppm 125 ppm 100 ppm 125 ppm
聽
Notes
ALIPHATIC HYDROCARBON - NISOH recommends a limit of 350 mg/m3 - 8 hour TWA, 1800 mg/m3 as determined by a 15-minute sample.
ISOBUTYL ISOBUTYRATE - Eastman Kodak recommends an exposure limit of: 100 ppm 8 hour TWA.
2-BUTYOXYETHANOL CAS# 111-76-2 - This component has been shown to cause harm to the fetus in laboratory animals. It only caused harm at levels of
overexposure that would also harm the pregnant animal. It has been shown to cause cancer in laboratory animals. The relevance to humans is unknown. It also has
been shown to cause reversible kidney effects and reversible liver effects in laboratory animals. Congestion in the liver, kidneys, and lungs resulted from acute
MSDS Number: 111 27X38, CLEAR WOOD FINISH INT. SEMI-GLOSS Printing Date: 04/21/2006 Page 3 of 5
lethal exposure in animal studies.
NITROCELLULOSE CAS# 9004-70-0 - It is on the OSHA Process Safety Management (PSM) list.
BUTYL ALCOHOL CAS# 71-36-3, there is evidence that some hearing loss may occur from long-term repeated exposure to vapor concentrations that are greater
than 50 ppm. Animal studies have shown exposure causes effects on the liver, kidney, lungs, eyes, ears (vertigo), and central nervous system. Exposure caused birth
defects and is toxic to the fetus of animals at levels that are nontoxic to the pregnant animal. The animals were exposed to doses many times higher than are
expected to occur during use of the component.
XYLENE CAS# 1330-20-7 - In animal studies, exposure has caused birth defects. The relevance to humans is unknown. It also has been shown to cause reversible
liver effects, kidney damage, hearing effects, and cardiac sensitization in laboratory animals.
ISOPROPANOL ANHYDROUS CAS# 67-63-0 in animal studies, exposure has caused fetal developmental effects and low fetal weights in non-toxic exposure levels
to the mothers. It has been shown to cause fetotoxic effects at the level of exposure that was harmful to the mother. The relevance of these findings to humans is
unknown. Exposure has been shown to cause kidney damage in male rats. The mechanism of toxicity that caused the kidney damage is not found in humans;
therefore kidney damage from exposure is not expected to occur in humans.
ZINC STEARATE - OSHA - 8 hour TWA 15 mg/m3 total dust. 8 hour TWA 5 mg/m3 respirable fraction.
NITROCELLULOSE CAS# 9004-70-0 - It is on the OSHA Process Safety Management (PSM) list.
ETHYL BENZENE CAS# 100-41-4 - IARC Group 2B possibly carcinogenic to humans.
ETHYL BENZENE CAS# 100-41-4 - IARC Group 2B possibly carcinogenic to humans.
聽
Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations below
permissible OSHA exposure limits. Remove all ignition sources (heat, sparks, flame, and hot surfaces).
Respiratory Protection: A respirator that is recommended or approved for use in an organic vapor environment (air
purifying or fresh air supplied) is necessary. Observe OSHA regulations for respirator use. Ventilation should be provided
to keep exposure levels below the OSHA permissible limits.
Skin Protection: Chemical-resistant gloves (cotton, neoprene, rubber, polyethylene) should be used to prevent skin contact.
Eye Protection: Wear safety eyewear (safety glasses, safety glasses with side-shields, chemical goggles, or face shields) to
prevent eye contact.
Other protective equipment: Long sleeve and long leg clothing is recommended. Remove and wash contaminated clothing
before reuse or discard. Safety shower and eyewash station should be located in immediate work area.
Hygienic Practices: Wash hands before breaks, eating, smoking, and at the end of the workday.
聽Section 9 - Physical and Chemical Properties
Boiling Range (掳F): N.D. - 343 Vapor Density: Heavier than air
Odor: Solvent odor Odor Threshold: N.D.
Appearance: Opaque liquid Evaporation Rate: 0.5 x n-Butyl Acetate
Solubility in H2O: Insoluble 聽 聽
Freeze Point: N.D. Specific Gravity: 0.901
Vapor Pressure: N.D. PH: N.A.
Physical State: Liquid Viscosity: Thin liquid to heavy
viscous material
(See section 16 for abbreviation legend)
聽Section 10 - Stability and Reactivity
Conditions To Avoid: Avoid high temperatures, sparks, or open flames. Do not breathe vapors or spray mist.
Incompatibility: A component is incompatible with chlorinated hydrocarbons, isocyanates, ethylene oxide, amines,
aldehydes, and aluminum equipment above 120 degree (F). Contains a component that is incompatible with peroxides and
oxygen. Material is incompatible with oxidizing agents, strong acids, strong alkalies. Incompatible with halogens.
Hazardous Decomposition: Thermal decomposition can lead to the generation and release of gases and vapors including
carbon monoxide, carbon dioxide, zinc oxides, oxides of nitrogen, and hydrocarbons. Product may form hydrogen cyanide,
methane, aldehydes, and carboxylic acids when burned.
Hazardous Polymerization: Will not occur.
Stability: Stable under recommended storage conditions.
聽Section 11 - Toxicological Information
Product LD50: N.E. Product LC50: N.E.
Section 12 - Ecological Information
Ecological Information: No Information.
Section 13 - Disposal Information
Disposal Information: Hazardous Waste Characteristics: Ignitability and Reactivity. EPA Hazardous Waste Number/Code:
D001, F003, F005. Empty containers will contain product residue and flammable vapors. Handle as hazardous material. Do
not incinerate closed containers. Dispose of waste in accordance with federal, state, and local environmental regulations.
Section 14 - Transportation Information
DOT Proper Shipping Name: Consumer Commodity Packing Group: N.A.
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: ORM-D Resp. Guide Page: N.A.
DOT UN/NA Number: N.A. 聽 聽
Section 15 - Regulatory Information
MSDS Number: 111 27X38, CLEAR WOOD FINISH INT. SEMI-GLOSS Printing Date: 04/21/2006 Page 4 of 5
聽
CERCLA 鈥? SARA Hazard Category
This product has been reviewed according to the EPA 鈥楬azard Categories鈥? promulgated under Sections 311and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:聽 IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
聽
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Component CAS Number Percent By Weight
2-BUTOXYETHANOL 111-76-2 10.95
n-BUTYL ALCOHOL 71-36-3 5.92
XYLENE 1330-20-7 3.78
ISOPROPANOL ANHYDROUS 67-63-0 3.29
ZINC STEARATE 557-05-1 2.45
ETHYL BENZENE 100-41-4 0.64
ETHYL BENZENE 100-41-4 0.17
聽
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
聽
U.S. State Regulations: As follows 鈥?
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Component CAS Number
ALKYD RESIN UNKNOWN
聽
聽Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
Component CAS Number
ALKYD RESIN UNKNOWN
聽
California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
Component CAS Number
ETHYL BENZENE 100-41-4
ETHYL BENZENE 100-41-4
BENZENE 71-43-2
ETHYLENE OXIDE 75-21-8
聽
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or
other reproductive hazards.
Component CAS Number
BENZENE 71-43-2
TOLUENE 108-88-3
ETHYLENE OXIDE 75-21-8
聽
International Regulations: As follows 鈥?
CANADIAN WHMIS:聽 This MSDS has been prepared in compliance with Controlled Product Regulations except for the
use of the 16 headings.
CANADIAN WHMIS CLASS: N.A.
Section 16 - Other Information
聽
HMIS Ratings: 聽 聽 聽
Health: 3 Flammability: 3 Reactivity: 1 Personal Protection: I
聽
VOLATILE ORGANIC COMPOUNDS, GR/LTR: 667.5
VOLATILE ORGANIC COMPOUNDS, LB/GAL: 5.6
VOLATILE ORGANIC COMPOUNDS MIXED, GR/LTR: <= N.D.
VOLATILE ORGANIC COMPOUNDS MIXED, LB/GAL: <= N.D.
REASON FOR REVISION: New Computer System. Information in Sections 2, 3, 4, 5, 6, 8, 10, and 14 have been updated.
REGULATORY CODE: 111
LAYOUT CODE: A2004R
Legend:聽 N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
MSDS Number: 111 27X38, CLEAR WOOD FINISH INT. SEMI-GLOSS Printing Date: 04/21/2006 Page 5 of 5
The information contained on this MSDS has been checked and should be accurate.聽 However, it is the responsibility of the
user to comply with all Federal, State, and Local laws and regulations.
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