3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
Material Safety Data Sheet
Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-
9800-2403-2; Europe 60-9800-3175-5/XS-0034-0429-9)
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/26/2003
Supercedes Date: 12/13/2001
Document Group: 07-2551-5
Product Use:
Specific Use: Urethane Windshield Primer
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
METHYL ETHYL KETONE 78-93-3 30 - 60
N-BUTYL ACETATE 123-86-4 10 - 30
HEXAMETHYLENE DIISOCYANATE POLYMER 28182-81-2 10 - 20
CARBON BLACK 1333-86-4 3- 7
POLYURETHANE PREPOLYMER 63368-95-6 3- 7
POLYURETHANE RESINS Unknown 3- 7
1-METHOXY-2-PROPYL ACETATE 108-65-6 1- 5
HEXAMETHYLENE DIISOCYANATE 822-06-0 < 0.2
TDI ISOMERS 584-84-9 < 0.1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Page 1 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
Odor, Color, Grade: Black liquid with solvent odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Reacts violently with water. Flammable liquid and vapor. Closed
containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an
ignition source and flash back. May cause severe eye irritation. May cause allergic skin reaction. May cause allergic respiratory
reaction. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. HEXAMETHYLENE
DIISOCYANATE (822-06-0): Persons previously sensitized to an isocyanate, or persons with a preexisting non-specific bronchial
hyperreactivity, can respond to concentrations well below the TLV. These symptoms, which can include chest tightness, wheezing,
cough, shortness of breath, or asthma attack, could be immediate or delayed (up to several hours after exposure). Toluene Diisocyante
exposure in combination with Hexamethylene Diisocyante may have a synergistic effect and result in increased inhalation toxicity.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
May be absorbed through skin and cause target organ effects.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
Prolonged or repeated exposure, above recommended guidelines, may cause:
Lung Effects: Signs/symptoms may include difficulty breathing, cough, wheezing, weakness, increased heart rate, bluish
colored skin (cyanosis), sputum production and changes in lung function tests.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Ingestion may cause:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
Page 2 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
Prolonged or repeated exposure may cause:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure, above recommended guidelines, may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description Regulation
CARBON BLACK 1333-86-4 Group 2B International Agency for Research on
Cancer
TDI ISOMERS 584-84-9 Group 2B International Agency for Research on
Cancer
TDI ISOMERS 584-84-9 Anticipated human carcinogen National Toxicology Program
Carcinogens
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. If signs/symptoms
develop, get medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Page 3 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
-7 潞C [Test Method: Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Class IB Flammable Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). DO NOT USE WATER
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for
exposed areas of the head. Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and
surfaces cool and prevent explosive rupture.
Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build
pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build
dikes to prevent entry into sewer systems or bodies of water. Avoid contact with incompatible materials listed in the Reactivity Data
Section. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for
10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Working from around the edges of the spill inward,
cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears
dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the
spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and
authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the
resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the
container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
Page 4 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not breathe vapors. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
Avoid contact with water to prevent potentially violent reaction or fire. Ground containers securely when transferring contents. Wear
low static or properly grounded shoes. Avoid static discharge. For industrial or professional use only. Keep away from heat, sparks,
open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid contact with oxidizing agents.
Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray.
7.2 STORAGE
Keep container tightly closed. Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing
agents. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits
and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Do not use in a confined area
or areas with little or no air movement. Provide appropriate local exhaust ventilation on open containers.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact. Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA), Polyethylene/Ethylene Vinyl Alcohol.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Fullface air-purifying respirator with organic vapor cartridges and N95 particulate prefilters. Consult the current
3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1-METHOXY-2-PROPYL ACETATE AIHA TWA 541 mg/m3
1-METHOXY-2-PROPYL ACETATE CMRG TWA 100 ppm
CARBON BLACK ACGIH TWA 3.5 mg/m3 Table A4
CARBON BLACK CMRG TWA 0.5 mg/m3
CARBON BLACK OSHA TWA 3.5 mg/m3 Table Z-1
HEXAMETHYLENE DIISOCYANATE ACGIH TWA 0.005 ppm
Page 5 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
HEXAMETHYLENE DIISOCYANATE CMRG TWA 0.5 mg/m3
POLYMER
HEXAMETHYLENE DIISOCYANATE CMRG STEL 1 mg/m3
POLYMER
METHYL ETHYL KETONE ACGIH TWA 200 ppm
METHYL ETHYL KETONE ACGIH STEL 300 ppm
METHYL ETHYL KETONE OSHA TWA 200 ppm Table Z-1A
METHYL ETHYL KETONE OSHA STEL 300 ppm Table Z-1A
N-BUTYL ACETATE ACGIH TWA 150 ppm
N-BUTYL ACETATE ACGIH STEL 200 ppm
N-BUTYL ACETATE OSHA TWA 150 ppm Table Z-1A
N-BUTYL ACETATE OSHA STEL 200 ppm Table Z-1A
TDI ISOMERS ACGIH TWA 0.005 ppm Table A4
TDI ISOMERS ACGIH STEL 0.02 ppm Table A4
TDI ISOMERS OSHA TWA, 0.005 ppm
Vacated
TDI ISOMERS OSHA CEIL 0.02 ppm Table Z-1
TDI ISOMERS OSHA STEL, 0.02 ppm
Vacated
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Black liquid with solvent odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
-7 潞C [Test Method: Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
80 潞C
Boiling point
No Data Available
Vapor Density
71 mmHg [@ 20 潞C]
Vapor Pressure
1.0 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
Not Applicable
Melting point
Nil
Solubility in Water
No Data Available
Evaporation rate
699 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
Approximately 70 %
Percent volatile
699 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
Page 6 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
No Data Available
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat; Sparks and/or flames
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Oxides of Nitrogen During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in
a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D035 (Methyl ethyl ketone)
Since regulations vary, consult applicable regulations or authorities before disposal.
Page 7 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9800-2537-7, 60-9800-2539-3
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
METHYL ETHYL KETONE 78-93-3 30 - 60
TDI ISOMERS 584-84-9 < 0.1
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
N-BUTYL ACETATE 123-86-4 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
The components of this product are in compliance with the chemical notification requirements of TSCA.
The components of this product are listed on the Canadian Domestic Substances List.
The components of this product are listed on the Australian Inventory of Chemical Substances.
Page 8 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
The components of this material are in compliance with the new chemical notification requirements for the Korean Existing
Chemicals Inventory.
The components of this product are in compliance with notification requirements in the Philippines.
All the components of this product are listed on China's Inventory of Chemical Substances.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of
the product have not changed. We encourage you to reread the MSDS and review the information.
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
Page 9 of 10
3M MATERIAL SAFETY DATA SHEET 3M(TM) Black Primer (Step 2), PN 08684/30 mL; 08686/125 mL; 08692/5.91m L (US 60-9800-
2403-2; Europe 60-9800-3175-5/XS-0034-0429-9) 05/26/2003
3M MSDSs are available at www.3M.com
Page 10 of 10
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