MSDS
Product : Polyflo 128
Rev # : 00 Date : 10/11/2001
Page 1 of 4
MATERIAL SAFETY DATA SHEET
Section 1. PRODUCT IDENTIFICATION
: UOPTM PolyfloTM 128 Fuel Additive
Product Name
Section 2. COMPOSITION
Ingredient CAS No. Wt% EU Symbol EU Risk Phrase
N-2octylethanolamine 26535-68-2 45-55 C,Xn R-20/21/22,35,41
N,N-dimethylcyclohexylamine 98-94-2 30-40 T, C R-10, 20/22, 24, 35, 41
Aromatic Hydrocarbons 64742-94-5 5-15 Xn R-22
N,N1disalicylidene
鈥?1,2-propanedioamine 94-91-7 <10 Xn R-22
Xylene 13320-20-7 <3 Xn R-10,38,30/21
1,2,4-trymethylbenzene 95-63-6 <2 Xn R-10,20,36/37/38
Naphthalene 91-20-3 <1 Xn R-22,36/37,40
Section 3. HAZARD IDENTIFICATION
Emergency Overview : This amber liquid may be corrosive to the skin and eyes. The product is considered toxic if absorbed through the
skin. The product is considered harmful via ingestion and inhalation. Inhalation of vapors may cause nausea, headache, dizziness, and
temporary central nervous system depression. Ingestion may cause gastrointestinal pain and discomfort. Product is flammable. Fire may
produce toxic gases.
Potential Health Effects :
Primary Routes of Exposure : Contact with skin, eyes and product vapor inhalation. Product ingestion is unlikely to occur if proper
safety/hygiene procedures are followed.
Skin Contact : Product is corrosive to the skin, eyes, and will cause burns. The product may be absorbed through the skin in toxic amounts.
This product may cause an allergic skin reaction and/or dermatitis.
Eye Contact : Product is corrosive to eye.
Ingestion : The product is harmful if ingested. Ingestion may cause nausea, vomiting, diarrhea, and abdominal discomfort. Ingestion may
cause irritation of the gastrointestinal tract.
Inhalation : The product is harmful via inhalation. Inhalation of high vapor concentrations may cause headaches, nausea, dizziness, and
central nervous system depression.
Target Organ : The product is corrosive to any tissue; this includes the skin, eyes and mucous membranes. Prolonged or repeated
overexposure may cause lung, damage, liver damage and kidney damage. May cause central nervous system disorder (e.g. narcosis
involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage.
Carcinogenicity Classifications: International Agency for Research on Cancer (IARC) :
Xylene 鈥? Not classifiable as human carcinogen (Group 3)
Section 4. FIRST AID INFORMATION
Skin Contact : REMOVE FROM SKIN EMERGENCY. Apply a generous amount of waterless and hand cleaner (such as GOOP庐, GoJo庐,
or similar product) to the affected area. Rub briskly on the skin, on and around the affected area. Remove the mixture of cleaner-product
with paper towels or clean dry rags. Repeat the entire procedure, then wash the skin with a mild soap, rinsing with warm water. If irritation
develops, obtain medical attention.
Eye contact : Flush with water for at least 15 minutes. If irritation occurs, obtain medical attention.
Ingestion : Do not induce vomiting. Obtain immediate medical attention.
Inhalation : Remove affected area to fresh air. If respiratory problems develop, obtain medical attention.
Notes to physician : An activated charcoal slurry taken within 30 minutes of product ingestion may reduce the toxicity of the chemical. A
5:1 weight ratio of charcoal to material ingested is the recommended dosage. Activated charcoal should not be considered as an antidote;
normal symptomatic treatment is recommended with or without the administration of activated charcoal.
MSDS
Product : Polyflo 128
Rev # : 00 Date : 10/11/2001
Page 2 of 4
Section 5. FIRE FIGHTING MEASURES
Flash Point : 126!20F (53!20C) PMCC
Extinguishing Media : Use water fog, foam dry chemical or CO2
Fire and Explosion Hazards: Toxic vapors may be given off in a fire (See section 10). Wear protective clothing and self-contained
breathing apparatus.
Section 6. ACCIDENTAL RELEASE MEASURES
Large Spill : Remove all sources of ignition. Isolate the affected areas. Confine entry into the affected area to those persons properly
protected. Stop leak at the source. Cut off and redirect surface runoff by trenching or diking. Spills should be contained through the use of
commercial oil adsorbent, but other materials such earth, sand or sawdust may be more expedient to limit the extent of the spill. Prevent the
release of this product into the waterway or sewer. To prevent further losses, reposition, plug or place the leaking container into an oversized
recovery drum/container.
Small Spill : Wear protective equipment. Absorb spilled product using a commercial oil absorbent soaking up as much product as possible.
Product should be disposed of in accordance with all applicable government regulations.
Section 7. HANDLING AND STORAGE
Store in tightly closed, properly labeled containers in a cool, well ventilated area away from all ignition sources. Store out of direct sunlight.
Wear appropriate personal protective equipment. Avoid inhalation of product vapors or mist. Never use a welding or cutting torch on or near
a drum (even empty) because vapors from the material (even residue) can ignite explosively. Follow all MSDS/label precautions even after
container is emptied because it may retain product residue.
Section 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Respiratory Protection: Where natural ventilation is inadequate, use mechanical ventilation, other engineering controls, or an organic
adsorption respirator (in USA 鈥? NIOSH/MSHA approved) to prevent inhalation of product vapor.
Skin protection : Gloves, footwear, coveralls and/or apron as necessary to prevent repeated or prolonged skin contact. Any clothing which
becomes wet with product should be removed immediately and laundered before reuse.
Eye Protection : Chemical goggles or face shield as necessary to prevent eye contact.
Exposure Limits
Ingredient MAK VME ACGIH TLV-TWA(1997)
N-2-octylethanolamine N/E N/E N/E
N,N-dimethylcyclohexylamine N/E N/E N/E
150 mg/m3
Aromatic hydrocarbons N/E N/E
N,N`-disalicylidene-1,2 N/E N/E N/E
-propanediamine
125 mg/m3 123 mg/m3, 25 ppm
1,2,4-trimethylbenzene N/E
3 3 3
Naphthalene 10 ppm, 50mg/m 10 ppm, 50mg/m 10 ppm, 52mg/m
STEL15 ppm, 79 mg/m3
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
These data do not represent technical or sales specifications.
0.88 ! 0.02 @ 600F
Appearance : Amber Liquid Sp. Gr. :
Odor : Hydrocarbon Apparent Bulk Density : NA
pH : NA Solubility in water : Negligible
300 0F (148 0C)
% Volatile : NA Boiling Point :
< - 70 0F (<-57 0C)
Pour Point : Freezing Point : NA
38 SUS @ 100 0F
Viscosity : Melting Point : NA
< 10 mmHg @ 20 0F
Vapor Density : NA Vapor Pressure :
MSDS
Product : Polyflo 128
Rev # : 00 Date : 10/11/2001
Page 3 of 4
Section 10. STABILITY
Stability : Stable.
Condition to avoid : Thermal decomposition. Exposure to heat, light sparks and open flame.
Hazardous Decomposition Products : The product itself does not readily decompose unless subject to extreme temperature or chemical
conditions. CO, CO2, NOX may be generated in the event of incomplete burning.
Hazardous Polymerization : Will not occur.
Incompatible Materials : Oxidizing agents. The product, in its concentrated form, may corrode aluminum, copper, tin, zinc, and alloys
containing these metals.
Section 11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity :
No data for this product.
N-2-octylethanolamine : Oral LD50 : 0.98 g/kg (rat)
N,N-dimethylcyclohexylamine : Oral LD50 = 280 g/kg (rat)
N,N`-disalicylidene-1,2 propanediamine: Oral LD50 : 0.98 g/kg (rat)
Aromatic Solvent: Oral LD50 of 11.97 g/kg (rat) (includes 1,2,4-trimethylbenzene and naphthalene)
Xylene : Oral LD50 : 4.3 g/kg (rat)
Acute Dermal Toxicity :
No data for this product.
N-2-octylethanolamine : Dermal LD50 : 1.06 g/kg (rabbit)
N,N-dimethylcyclohexylamine : Dermal LD50 = 210 g/kg (rabbit)
Aromatic Solvent: Dermal LD50 >4.5 g/kg (rabbit) (includes 1,2,4-trimethylbenzene and naphthalene)
Xylene : Dermal LD50 : 4.32 g/kg (rabbit)
Acute Inhalation Toxicity :
No data for this product.
N,N-dimethylcyclohexylamine : Inhalation LC50: 9 mg/I/4 (rat)
Aromatic Solvent: Oral LC50 >580 ppm/4H (rat) (includes 1,2,4-trimethylbenzene and naphthalene)
Xylene : Inhalation LCLO : 5000 ppm/4 hrs. (rat) g/kg (rat)
Irritation :
Eye : N-2-octylethanolamine is a severe eye irritant. It produces marked corneal and iris damage (rabbit). Maximum Draize score : 81/110.
Eye : N,N-dimethylcyclohexylamine is severe irritant to the eyes (rabbit). Corrosive.
Skin : N-2-octylethanolamine is a severe dermal irritant. May be corrosive if not properly removed (rabbit)
Skin : N,N-dimethylcyclohexylamine is severe irritant to the skin (rabbit). Corrosive.
Additional Toxicological Information : No other data shown.
Section 12. ECOLOGICAL INFORMATION
Xylene : 96 hoursLC50, fathead minnows : 27-42 mg/l
Section 13. DISPOSAL INFORMATION
Waste material, including liquids, contaminated absorbent and material from spill clean-up procedures, must be handled in accordance with
all applicable government regulations. It is up-to the user of this product to determine the hazards associated with any waste material
generated. Recommended disposal methods include incineration for contaminated liquids and solids.
Section 14. TRANSPORTATION INFORMATION
ADR / RID : Amines Liquid, Corrosive, Flammable, N. O. S. (contains N-2-octylethanolamine and N,N-dimethylcyclohexylamine), Class 8,
Item 54b), Marginal 2801, Danger Code 83.
International Maritime Organization (IMO)
Amines, Liquid, Corrosive, Flammable, N. O. S. (contains N-2-octylethanolamine and N,N`-dimethylcyclohexylamine), Class 8, UN 2734, II
(3)
Page IMDG : 8109-1. EmS No. 8-04. MFAG Table No. 320.
MSDS
Product : Polyflo 128
Rev # : 00 Date : 10/11/2001
Page 4 of 4
Section 15. REGULATORY INFORMATION
Council of European Communities Directive on Classification, Packing and Labeling of Dangerous Substances/Preparation (67/548/EEC &
88/379/EEC):
R10 Flammable
R20/22 Harmful by inhalation and if swallowed.
R24 Toxic in contact with skin.
R35 Causes severe burns.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
R28 After contact with skin, wash immediately with plenty of waterless handcleaner.
S36/37/39 Wear suitable protective clothing, and N,N`Dimethylcyclohexylamine
T : Toxic
Contains :N-2-octylethanolamine and N,N`-Dimethylcyclohexylamine
European Inventory of existing Commercial Chemical Substances :
All components of this preparation are included in EINECS/ELINCS.
Section 16. OTHER INFORMATION
For additional information concerning this product, contact the following:
PRODUCT EMERGENCIES
Dorf Ketal Chemicals (I) Pvt. Ltd. Dorf Ketal LLC
#1 DORF KETAL TOWERS. 3727 Greenbriar
D鈥橫onte Street, Marve Road. Suite 114,
Malad (W). Bombay 64. Stafford, TX 77477
Tel : +91-22-8813654 / +91-22-8828374. Tel : 281 491 3700
Fax : +91-22-8813655 Fax : 281 491 3700
The data and recommendations presented in this data sheet concerning the use of our product and the materials contain there in are believed to be accurate
and are based on information which is considered reliable as of the date hereof. However, the customer should determine the suitability of such material for
his purpose before adopting them on a commercial scale. Since the use our products by others is beyond our control, no guarantee, express or implied, is
made and no responsibility assumed for the use of this material or the results to be obtained there from. Information on this form is furnished for the purpose
of compliance with Government Health and Safety Regulations and shall not be used for any other purposes. Moreover, the recommendations contained in
this data sheet are not to be constructed as a license to operate under, or a recommendation to infringe, any existing patents, nor should they be confused
with state, municipal or insurance requirements, or with national safety codes.
END OF MSDS
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