Product Name: Duro(R) Contact Cement Page 1 of 6
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 07
Duro(R) Contact Cement
81523
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: 81523
Part No.: CC-8
Product Type: Adhesive
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Light aliphatic
solvent naphtha 64742-89-8 30-35
TOLUENE* 108-88-3 20-25
ACETONE 67-64-1 15-20
n-HEXANE* 110-54-3 5-10
Neoprene 9010-98-4 Unknown
Synthetic resin Proprietary Unknown
METHYL ETHYL KETONE* 78-93-3 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Light aliphatic
solvent naphtha 5mg/m3 TWA mist 5mg/m3 TWA mist None
TOLUENE 50 ppm skin 100 ppm None
188 mg/M3 skin 375mg/M3
ACETONE 500 ppm TWA 750 ppm TWA None
1188 mg/m3 1800 mg/m3
n-HEXANE 50 ppm TWA 50 ppm TWA None
180mg/M3
METHYL ETHYL KETONE 200 ppm TWA 200 ppm TWA None
590 mg/m3 590 mg/m3
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
Light aliphatic
solvent naphtha 10 mg/m3 None
TOLUENE None 150 ppm
560mg/M3
ACETONE 750 ppm 1000 ppm
1782 mg/m3 2400 mg/m3
METHYL ETHYL KETONE 300 ppm 300 ppm
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 07
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Product Name: Duro(R) Contact Cement Page 2 of 6
Item No.: 81523
2. COMPOSITION, INFORMATION ON INGREDIENTS (continued)
885 mg/m3 885 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity: Excessive inhalation of vapors can cause nasal and
respiratory irritation, dizziness, weakness,
fatigue, nausea, headache, possible
unconsciousness, and even asphyxiation. Ingestion
can cause gastrointestinal irritation, nausea
vomiting, and diarrhea. Aspiration of material
into the lungs can cause chemical pneumonitis
which can be fatal. Eye contact can cause severe
irritation, redness, tearing, blurred vivion.
Prolonged or repeated skin contact can cause
moderate irritation, defatting, dermatitis. Can be
absorbed through the skin.
Overexposure to components has apparently been
found to cause the following effects in laboratory
animals: Kidney damage, eye damage, liver
abnormalities, lung damage, spleen damage, brain
damage. Overexposure to components has been
suggested as a cause of the following effects in
humans: Liver abnormalities, central nervous
system damage, damage to peripheral nerve tissue
resulting in muscular weakness and loss of
sensation in the extremities, brain cell damage.
Primary Routes of Entry: Skin, eye, ingestion, inhalation
Signs and Symptoms
of Exposure: Vapors can irritate eyes, nose, throat and skin
and can cause headache, nausea, dizziness,
weakness, fatigue. Vomiting and diarrhea from
ingestion. Redness, tearing of eyes, blurred
vision
Existing Conditions
Aggravated by Exposure: None known
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Light aliphatic
solvent naphtha No Data NO NO NO
TOLUENE AC4 CAR CNS DEV IRR NO NO NO
ACETONE AC4 BLO CNS IRR NO NO NO
n-HEXANE DEV IRR NER REP NO NO NO
Neoprene No Data NO N/A NO
Synthetic resin No Data NO NO NO
METHYL ETHYL KETONE CNS IRR NO N/A NO
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LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 07
Item No.: 81523
3. HAZARDS IDENTIFICATION (continued)
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Product Name: Duro(R) Contact Cement Page 3 of 6
Abbreviations
N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc.
BLO Blood CAR Cardiac
CNS Central nervous system DEV Developmental
IRR Irritant NER Nervous System
REP Reproductive
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep warm quiet and get
medical attention. Aspiration of material into the
lungs can cause chemical pneumonitis which can be
fatal.
Inhalation: If affected, remove individual to fresh air. If
breathing is difficult, administer oxygen. If
breathing has stopped, give artifical respiration.
Keep person warm, quiet, and get medical attention
Skin Contact: Thoroughly wash exposed area with soap and water.
Remove contaminated clothing. Launder contaminated
clothing before reuse.
Eye Contact: Flush with large amounts of water for at least 15
minutes, lifting upper and lower lids occasionally
Get medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: Less than 0掳F Method: Setaflash
Recommended
Extinguishing Agents: Use foam, carbon dioxide, water fog, or dry
chemical fire fighting apparatus.
Special Firefighting
Procedures: Self-contained breathing apparatus with a full
facepiece operated in pressure-demand or other
positive pressure mode. Water may be unsuitable as
an extinguishing media, but helpful in keeping
adjacent containers cool. Avoid spreading burning
liquid with water used for cooling purposes.
Avoid breathing vapors or fumes.
Hazardous Products formed
by Fire or Thermal Decomp Fumes, smoke, oxides of carbon.
Unusual Fire or
Explosion Hazards: Material is highly volatile and readily gives off
vapors which may travel along the ground or be
moved by ventilation and ignited by pilot lights,
other flames, sparks, heaters, smoking, electric
motors, static discharge or other ignition sources
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 07
Item No.: 81523
5. FIRE FIGHTING MEASURES (continued)
at locations distant from material handling point.
Explosive Limits:
(% by volume in air)Lower 1.1%
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Product Name: Duro(R) Contact Cement Page 4 of 6
(% by volume in air)Upper 12.8%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Remove all ignition sources. Keep people away.
Recover free liquid. Add absorbent (sand, earth,
sawdust, etc.) to spill area. Avoid breathing
vapors. Ventilate confined spaces. Open all
windows and doors. Use non-sparking tools (shovels
scrapers, etc.). Keep petroleum products out of
sewers and water courses by diking or impounding.
Advise authorities if product has or may enter
sewers.
7. HANDLING AND STORAGE
Safe Storage: Keep container closed when not in use. Do not
store near heat, sparks, flame, or oxidizing
agents.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Avoid breathing vapors. Keep away from eyes.
Avoid prolonged skin contact. Do not handle near
heat, sparks, flame, or strong oxidizers.
Containers of this material may be hazardous when
empty since emptied containers retain product
residue (vapor, liauid, and solid). Never use
welding or cutting torch on or near container
(even when empty) because product (even just
residue) can ignite expolsively. All hazard
precautions given in data sheet must be observed.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Use splash goggles or face shield.
Skin: Use chemical resistant gloves. Use chemical resist
resistant apron or other clothing, if needed, to
avoid repeated or prolonged skin contact.
Ventilation: Sufficient local exhaust to maintain vapor
exposure below TLV, PEL, or STEL. Use explosion
proof mechanical equipment. No smoking or open
lights should be permitted.
Respiratory Use NIOSH approved hydrocarbon vapor cannister or
supplied air respiratory protection in confined or
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 07
Item No.: 81523
8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued)
enclosed spaces or where vapor concentration
exceeds TLV, PEL, or STEL.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Amber medium syrup
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Product Name: Duro(R) Contact Cement Page 5 of 6
Odor: Petroleum
Boiling Point: 134掳F
pH: Does not apply
Solubility in Water: Negligible
Specific Gravity 0.81
Volatile Organic Compound
(EPA Method 24) 60.6%; 492 grams per liter
Vapor Pressure: 120mm Hg
Vapor Density: 2.7
Evaporation Rate
(Ether = 1) More than 1
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizing agents, strong alkalies, strong
acids, or bases.
Conditions to Avoid: None
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Small spill- Allow volatile portion to evaporate
in well ventilated area. Dispose of remaining
material in accordance with applicable regulations
Large spill- Dispose of material or contaminated
absorbent in accordance with local, state, or
federal regulations.
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 07
Item No.: 81523
13. DISPOSAL CONSIDERATIONS (continued)
EPA Hazardous Waste
Number D001/D035 - Hazardous waste per 40CFR 261.21 and
a TCLP waste per 261.24/Methyl Ethyl Ketone.
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity (Not more than one liter);
Adhesives (More than one liter)
Hazard Class or
Division: ORM-D (Not more than one liter);
Class 3, Packing Group II (More than one liter)
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Product Name: Duro(R) Contact Cement Page 6 of 6
Identification Number: None (Not more than one liter);
UN 1133 (More than one liter)
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than 500 ml);
Adhesives (More than 500 ml)
Class or Division: Class 9 (Not more than 500 ml);
Class 3, Packing Group II (More than 500 ml)
UN or ID Number: UN 1133 (More than 500 ml)
ID 8000 (Not more than 500 ml);
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains a chemical known to
the State of California to cause birth
defects or other reproductive harm.
Toluene
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 3
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 3
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 07 of 07
Item No.: 81523
16. OTHER INFORMATION (continued)
Prepared By: Stephen Repetto
Title: Research Chemist- Safety,Health&Regulatory Affairs
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: August 20, 1998 Revision: 0004
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