MATERIAL SAFETY DATA SHEET
Complies with OSHA Hazard Communications Standard 29 CFR 1910.1200
Product Desc: N.C.C.E. Windshield Washer Fluid
Product Code 55-2110-00, 55-2120-00 HMIS codes H F R P
2 1 0 X (See Section VIII)
Section I: Manufacturer Information
Name: N.C. Dept. of Correction, Janitorial Products Plant
Mailing Address: 1206 E. McNeill St., P.O. Box 1569
City/State/ Zip: Lillington, North Carolina 27546
Telephone: For Information- (910) 893-4552
For Emergency - CHEMTREC - 1-800-424-9300
Date Prepared: February 1998 Date Revised: January 26, 2006
Contact For Technical Information: Plant Manager
Telephone: (910) 893-4552 Fax: (910) 893-6042
Section II: Composition/Information on ingredients and exposure guidelines
COMPONENTS CAS NO. TYPICAL % NCOS AGGIH
(Chemical Name BY WEIGHT PEL TLV
and Synonyms)
*2-Butoxyethanol 111-76-2 1-4 25 ppm TWA 20 ppm TWA
(Skin)
*Isopropyl Alcohol 67-63-0 10 - 13 400 ppm TWA 200 ppm TWA
500 ppm STEL 400 ppm STEL
Dioctyl Sodium
Sulfosuccinate 577-11-7 < 0.1 NE NE
Propylene Glycol 57-55-6 < 0.1 NE NE
Blue EI 408 Undetermined < 0.1 NE NE
Water 77-32-18-5 85 - 88 NE NE
*These substances are hazardous chemicals as defined by the hazard communication
standard (29 CFR 1910.1200) NE: Not Established
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Section III: Hazards Identifications
EMERGENCY OVERVIEW
A blue liquid with an alcohol odor. Product forms combustible vapors if heated above
flashpoint. May cause eye irritation. Prolonged or repeated skin contact may dry skin and
cause irritation. High concentrations of vapor in confined or poorly ventilated areas may
cause respiratory irritation, dizziness, drowsiness, and unconsciousness. Can react with
strong acids and other substances. For large spills, emergency responders should wear
impervious coveralls, boots, gloves, and respiratory protection in poorly ventilated areas.
Absorb spill with inert material or transfer to a suitable container for reuse or disposal.
See section III, V, VI, and X.
Potential Health Effects and Primary Routes of Entry:
Inhalation: Inhalation of high concentrations of vapors at or above the exposure
limits, may cause respiratory irritation, weakness, drowsiness, dizziness, and lose of
consciousness. Other symptoms from breathing high concentrations of the isopropyl
alcohol in this product may include flushing, lowering of pulse rate and blood pressure,
anesthesia, narcosis, headache, mental depression, hallucinations, distorted perceptions,
dyspnea (breathing difficulty), respiratory depression, nausea or vomiting, and coma.
Skin: Skin contact may cause minor irritation with itching and possible redness.
Prolonged or repeated contact may cause defatting, drying, and cracking of the skin and
may aggravate an existing dermatitis. Exposure to small quantities by skin absorption is
not expected to cause adverse health effects. Widespread or prolonged exposure may
result in absorption of harmful amounts of isopropyl alcohol.
Eyes: Eye contact may cause irritation, stinging, pain, or discomfort. Eye burns and
corneal injury may occur if not treated promptly.
Ingestion: If ingested, this product may cause dizziness, drowsiness, decreased
awareness and responsiveness, lack of coordination, flushing, lowering of blood pressure
and pulse rate, headache, mental depression, hallucinations, distorted perceptions,
difficulty breathing, respiratory depression, abdominal discomfort, nausea, vomiting,
diarrhea, and coma.
Chronic Effects/ Carcinogenicity: None of the components in this product at
concentrations of 0.1% or greater are listed by the NTP, IARC or OSHA as carcinogens.
Ingredients in this product have been tested in laboratory animals. Animal studies
indicate that long-term inhalation of high concentrations of isopropyl alcohol, well above
the exposure limits, may temporarily affect the central nervous system and could cause
kidney deterioration. Animal studies indicate that long term exposure, which exceeds
exposure limits, may effect the liver, kidneys, lymphoid system, skin, blood, eyes, central
nervous system and respiratory system. In dietary studies, laboratory animals fed large
doses of isopropyl alcohol give birth to offspring with lower birth weights, and there
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were higher mortality (death) rates in offspring. There was a reduced mating performance
in second generation males. The types of exposures tested in laboratory animals should
not occur in normal industrial use when worker exposures are maintained below exposure
limits. For a complete discussion of the toxicology data from which this evaluation was
made, please refer to Section XI.
Section IV: First Aid
Eyes: Immediately flush eyes with water for at least 20 minutes and seek immediate
medical attention. Eyelids should be held away from the eyeballs to ensure thorough
rinsing.
Skin: Immediately flush skin with plenty of water. Remove contaminated clothing and
shoes. Seek medical attention if irritation develops and persists. Launder clothing before
reuse.
Inhalation: Move victim to fresh air, administer artificial respiration if not breathing.
Give oxygen if breathing is difficult. Trained person should give oxygen if breathing is
difficult. Get medical attention.
Ingestion: If swallowed, drink large quantities of water, do not induce vomiting and seek
immediate medical attention. Never give anything by mouth to an unconscious person.
Get medical attention immediately. If vomiting occurs spontaneously, keep airway clear
and give more water.
Medical Conditions Generally Aggravated By Exposure: Individuals with pre-existing
skin diseases, lung diseases, and asthma may be more susceptible to the effects of
excessive exposure to this product.
Section V: Fire and Explosion Data
Flash Point: 95 deg F. Forms combustible vapors when heated above
flashpoint, but product does not sustain burning.
Flammable Limits: Lower: 2% (Isopropyl alcohol) Upper: 12.7% at 200 deg F
(Isopropyl alcohol)
Extinguishing Media: If this product is involved in a fire, use dry chemical,
alcohol foam, or carbon dioxide type extinguishers. Keep containers cool with water
spray to prevent container rupture due to steam pressure and to prevent thermal
decomposition.
Fire and Explosion Hazards: During a fire, carbon monoxide, carbon dioxide,
and oxides of nitrogen may be evolved. Components in product can thermally
decompose at temperatures above 250 deg C (485 deg F). Combustible vapors formed
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when product is heated may settle in low or confined areas or travel a long distance to an
ignition source and flash back.
Fire-Fighting Equipment: Exposed firefighters should wear NIOSH approved self-
contained breathing apparatuses under positive pressure and chemical-resistant protective
equipment. Refer to Section VIII for further information.
Section VI: Accidental Release Measures
Cleanup personnel should wear appropriate equipment (See Section VIII). Eliminate all
ignition sources. Floor may be slippery; use care to avoid falling. Stop and control leak.
Small spills can be diluted with plenty of water and mopped up or absorbed with an inert
absorbent material. Mop spill area several times with water. Dispose of waste properly
(See Section XIII).
Contact CHEMTREC (800-424-9300) for technical advice and assistance relating to
chemical emergencies involving this product.
Section VII: Handling and Storage
Handling: Keep away from heat and flame. Do not get in eyes, on skin, or on clothing.
Avoid breathing mist or vapor. Use with adequate ventilation. Do not taste or swallow.
Wash thoroughly after handling. Remove contaminated clothing and launder before
reuse. Do not mix with acids or with any other cleaning agents. Empty containers may
contain residue which is hazardous.
Storage: Keep containers in well ventilated area and closed when not in use. Keep away
from heat and flame. Keep from contact with oxidizing materials and strong acids. Keep
product in original container. For institutional use only. Keep this and all chemicals out
of reach of children.
Section VIII: Exposure Control/Personal Protection
Respiratory Protection: Not normally required in well-ventilated area. Use NIOSH
approved air-purifying respirator with an organic vapor cartridge if there is a reasonable
possibility for harmful exposure to vapors or mists. Protection by air purifying
respirators is limited. Use NIOSH approved self-contained apparatus made for
emergencies or entry into unknown concentrations or immediately dangerous to life or
health conditions. All personal respiratory protection equipment should be used in
accordance with OSHA 29 CFR 1910.134.
Ventilation: Provide sufficient mechanical (general and/or local exhaust ventilation) to
maintain vapor mist concentrations below exposure limits.
Protective Gloves: Use chemical-resistant rubber gloves to prevent skin contact.
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Eye Protection: Avoid eye contact. Chemical splash goggles and a face shield (8
in. minimum) are recommended whenever eye or face contact may occur. Provide an
ANSI-approved eye wash station in the work area.
Other Protective Clothing or Equipment: Not generally required.
Section IX: Physical/Chemical Properties
APPEARANCE ODOR
Blue clear liquid Alcohol odor
BOILING RANGE VAPOR PRESSURE
180 - 212 deg F (100 deg C) 33 mm Hg at 20 deg C (Isopropyl alcohol)
At normal pressure
SPECIFIC GRAVITY VAPOR DENSITY (Air = 1)
0.950 - 1.000 >1
pH PERCENT VOLATILE BY VOLUME
9.5 - 11 > 99% (Primarily water)
MELTING POINT EVAPORATION RATE
Not applicable Unknown
VISCOSITY SOLUBILITY IN WATER
1 - 20 Centipoise completely soluble
MAXIMUM THEORETICAL VOC CONTENT
12.7% (weight percent VOC)
Section X: Reactivity Information
Stability: Product is stable. Avoid exposing product to heat or flame.
Incompatibility: The product is incompatible with strong acids, halogens, aldehydes,
strong oxidizing agents, and isocyanates.
Hazardous Reaction/Decomposition or by Product: Burning can produce acrid smoke
and toxic fumes of carbon monoxide, carbon dioxide, and nitrogen oxides.
Hazardous Polymerization: Will not occur.
Section XI: Toxicological Information
Ingredients used in this product have the following toxicological data:
ANIMAL DATA: Isopropyl Alcohol
Contact: A moderate eye irritant and a mild skin irritant.
Skin-Rabbit, adult 500 mg 鈥? Mild irritation effects
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Eye effects-Rabbit, adult 10 mg 鈥? Moderate irritation effects
Skin-Rabbit, adult LD50: 12,800 mg/kg
Inhalation: Inhalation-Rat LCLo: 16,000 ppm/4H
Inhalation of high concentrations of isopropyl alcohol (1,500 ppm and greater) in
rats caused increased motor activity and narcosis.
Ingestion: Oral-Rat LD50: 5,045 mg/kg
Other: Mutation, teratogenic, and reproductive effects data has been reported.
Cytogenic Analysis-Saccharomyces cerevisiae 200 mmol/tube
Cytogenic Analysis-Rat-Inhalation 1,030 mg/m3/16W-I
Inhalation-Rat TCLo: 10,000 ppm/7H (female 1-19D post): Teratogenic effects
Oral-Rat TDLo: 6,480 mg/kg (male 26W pre): Reproductive effects
2-Butoxyethanol
Contact: toxic by skin contact and a skin irritant. Absorbed through the skin. An
eye irritant.
Skin-Rabbit, adult: 500 mg open - Mild irritation effects
Skin-Guinea Pig, adult LD50: 230 mg/kg
Inhalation: Moderately toxic by inhalation. Animal studies indicate
inhalation of material damages red blood cells and may be a reproductive toxin.
Inhalation-Rat TCLo: 200 ppm/6H (female 6-15D post) - Reproductive effects
Inhalation-Rabbit, adult TCLo: 100 ppm/6H (female 6-18D post) - Teratogenic
effects
Inhalation-Rat LC50: 2,900 mg/m3 (590 ppm)
Inhalation-Mouse LC50: 700 ppm/7H
Ingestion: Toxic by ingestion.
Oral-Rat LD50: 470 mg/kg
Oral-Rat LD50: 1.48 g/kg
Oral-Mouse LD50: 1.2 g/kg
Oral-Rabbit, adult LD50: 300 mg/kg
Developmental Toxicity Data: Experimental reproductive and teratogenic
effects in laboratory animals.
Human Effects Data: Isopropyl Alcohol
Ingestion: Slightly toxic. A single dose for a human adult is about 250 ml,
although as little as 100 ml can be fatal. There are reports of serious illness fram
as little as 10 ml taken internally.
Oral-Man TDLo: 14,432 mg/kg 鈥? Central nervous system effects, Cardiovascular
effects, Pulmonary system effects
Oral-Man TDLo: 223 mg/kg 鈥? Central nervous system effects, Cardivascular
effects
Oral-Man LDLo: 5,272 mg/kg
Oral-Human LDLo: 3,570 mg/kg 鈥? Central nervous system effects, Pulmonary
system effects, Gastrointestinal tract effects
Contact: Mildly toxic by skin contact.
Can cause eye burns and corneal damage.
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Prolonged or repeated contact may cause defatting of the skin which can lead to
dermatitis.
Inhalation: High concentrations may cause central nervous system depression
resulting in headaches, dizziness and nausea; continued inhalation may result in
unconsciousness and/or death. Inhalation of vapours or mists may cause irritation
to the respiratory system.
Acts as a local respiratory irritant and in high concentration as a narcotic.
2-Butoxyethanol
Inhalation: Inhalation-Human TCLo: 195 ppm/8H - Gastrointestinal tract effects
Inhalation-Human TCLo: 100 ppm - Nose, Eye effects, Central nervous system
effects
Ingestion: Poison by ingestion.
Oral-Woman TDLo: 600 mg/kg
Lethal oral dose of ethylene glycols in humans is approximately 1.4 ml/kg, which
would be equivalent to approximately 100 ml for a 70 kg person.
Other: Target organs include liver, kidneys, lymphoid system, skin, blood, eyes,
and respiratory system.
Section XII: Ecological Information
Ecotoxicological information: Not available for product. The major component in
this product is practically non-toxic to aquatic organisms. 2-Butoxyethanol has a high
biochemical oxygen demand and a potential to cause oxygen depletion in surface water.
Product may be dangerous if it enters water intakes.
Isopropyl Alcohol 24H LC50, Fathead minnows: 11,160 mg/L.
2-Butoxyethanol 24H LC50, Bluegill sunfish: 1,490 mg/L.
Chemical Fate Information: At low concentrations in water, this product is
biodegradable in a biological wastewater treatment plant. Degradation of 3 - 10 mg/L of
isopropyl alcohol with filtered sewage seed in fresh water resulted in a 28% theoretical
BOD in 5 days and 78% in 20 days. Isopropyl alcohol was 99% degraded in acclimated
sewage sludge at 20 deg C. 2-Butoxyethanol will rapidly biodegrade and should have low
persistence in the environment.
Section XIII: Disposal Consideration
Waste Disposal: Unused product is not expected to be a hazardous waste under RCRA.
Any disposal must be in accordance with federal, state, and local regulations. Do not
discharge product to storm sewers or waterways. Concentrated product should be
recovered for reuse.
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Section XIV: Transport Information
DOT Proper Shipping Description: None
Dot Hazard Class / Division Label: None
Shipping Containers: 1 Gallon, 4 Bottles per Case and 55 gallon Drums
Section XV: Regulatory Information
OSHA Hazard Communication Standard: OSHA hazardous chemicals as
defined under 29 CFR 1910.1200 are listed in Section II.
Toxic Substances Control Act (TSCA): The intentional ingredients of this product are
listed.
SARA Title III:
Section 302 Extremely Hazardous Substances: None
Section 311 /312 Hazard Categories: Immediate health hazard. Delayed health hazard.
Fire hazard.
Section 313 Toxic Chemicals*: None present at or above the minimum reportable
concentrations. Toxic chemicals used in products for routine janitorial or grounds
maintenance are exempt from reporting requirements (see 40 CFR 372.38(c)).
CERLA Hazardous Substances: 2-Butoxyethanol (2.5 %). No RQ currently assigned to
this class of glycol ethers. If an amount greater than or equal to the RQ is released into
the environment, immediate notification of the National Response Center 1-800-424-
8802, and state and local authorities is required.
Section XVI: Other Information
This product is for institutional use only and is not for resale.
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