SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
HYDRANAL-Aqualyte RO-A
SEC34785
Version 1. Revision Date 22.08.2007 Print Date 27.08.2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
Trade name : HYDRANAL-Aqualyte RO-A
Product code : SEC34785
Use of the : Laboratory Use
Substance/Preparation
Company/Undertaking Identification
Company : Sigma-Aldrich Laborchemikalien GmbH
Wunstorfer Stra脽e 40
30926 Seelze
Telephone : (49) 5137-8238 0
Telefax : (49) 5137-8238 120
Emergency telephone : (49) 5137-999 0
For further information, : EurTechServ@sial.com
please contact:
2. HAZARDS IDENTIFICATION
Risk advice to man and the environment
F, Highly flammable
T, Toxic
N, Dangerous for the environment
R11 Highly flammable.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin
and if swallowed.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Highly flammable
Toxic
Irritant
dangerous for the environment
See Section 11 for more detailed information on health effects and symptoms.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization
Chemical Name Preparation contains organic an inorganic compounds
:
Hazardous components
Chemical Name CAS-No. EC-No. Index-No. Classification Concentration
[%]
Methanol 67-56-1 200-659-6 603-001-00-X F; R11 >= 30 - < 60
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SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
HYDRANAL-Aqualyte RO-A
SEC34785
Version 1. Revision Date 22.08.2007 Print Date 27.08.2007
T; R23/24/25-
R39/23/24/25
Pentan-1-ol 71-41-0 200-752-1 603-006-00-7 R10 >= 10 - < 20
Xn; R20
Xi; R37
R66
Dodecyldimethyl 112-18-5 203-943-8 C; R35 >= 10 - < 25
amine Xn; R22
N; R50/53
Imidazole 288-32-4 206-019-2 C; R34 >= 5 - < 15
Xn; R22
Occupational Exposure Limit(s), if available, are listed in Section 8.
For the full text of the R phrases mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
Inhalation : Remove to fresh air.
Keep patient warm and at rest.
Skin contact : Wash off immediately with plenty of water.
Eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Ingestion : When swallowed, allow water to be drunk.
Do NOT induce vomiting.
Call a physician immediately.
See Section 11 for more detailed information on health effects and symptoms.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Water spray
media Foam
Carbon dioxide (CO2)
Dry powder
Specific hazards during fire : Fire may cause evolution of:
fighting nitrogen oxides (NOx)
Sulphur oxides
Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Ensure adequate ventilation.
Environmental precautions : Do not flush into surface water or sanitary sewer system.
Methods for cleaning up : Soak up with inert absorbent material.
Pick for disposal in tightly closed containers
For personal protection see section 8.
7. HANDLING AND STORAGE
Handling
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SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
HYDRANAL-Aqualyte RO-A
SEC34785
Version 1. Revision Date 22.08.2007 Print Date 27.08.2007
Advice on safe handling : Exhaust ventilation at the object is necessary.
Advice on protection : Keep away from sources of ignition - No smoking.
against fire and explosion The heavy vapours can overcome a considerable distance up
to the source of ignition.
Storage
Further information on : Keep containers tightly closed in a dry, cool and well-ventilated
storage conditions place.
Advice on common storage : Do not store together with:
Oxidizing agents
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational exposure controls
Components Basis Value Control Exceeding Form of Remarks
type parameters Factor exposure
Methanol EH40 WEL time 266
weighted mg/m3
average 200 ppm
Methanol EH40 WEL Short term 333
exposure mg/m3
limit 250 ppm
Methanol Skin Can be absorbed
designatio through the skin.
n:
Methanol EU ELV time 260
weighted mg/m3
average 200 ppm
Methanol Skin Can be absorbed
designatio through the skin.
n:
Personal protective equipment
Respiratory protection : Remarks: In case of insufficient ventilation wear suitable
respiratory equipment.
Hand protection : Glove material: Solvent-resistant gloves
Eye protection : Goggles
Skin and body protection : Protective suit
Protective measures : Do not breathe vapours/dust.
Take off all contaminated clothing immediately.
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SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
HYDRANAL-Aqualyte RO-A
SEC34785
Version 1. Revision Date 22.08.2007 Print Date 27.08.2007
Wash hands before breaks and at the end of workday.
When using do not eat, drink or smoke.
The Personal Protective Equipment must be in accordance
with EN standards:respirator EN 136, 140, 149; safety glasses
EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2;
gloves EN 374, safety shoes EN-ISO 20345.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form : liquid
Colour : light yellow
Odour : aromatic
Safety data
Boiling point/boiling range : 63 掳C
at 1.013 hPa
Flash point : 14 掳C
Density : 0,930 g/cm3
at 20 掳C
pH : 5,0 - 7,0
at 20 掳C
Water solubility : Remarks: completely miscible
10. STABILITY AND REACTIVITY
Materials to avoid : Oxidizing agents
Evolution of inflammable gases/vapours easily.
Hazardous decomposition : Sulphur dioxide
products Nitrous gases
Thermal decomposition : Note: No decomposition if used as directed.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50
Species: rat
Dose: 5.628 mg/kg
Acute inhalation toxicity : LC50
Species: rat
Dose: 64000 ppm
Exposure time: 4 h
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SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
HYDRANAL-Aqualyte RO-A
SEC34785
Version 1. Revision Date 22.08.2007 Print Date 27.08.2007
Further information : Remarks: Toxicity data refers to the solvent
12. ECOLOGICAL INFORMATION
Additional ecological : There is no data available for this product.
information
13. DISPOSAL CONSIDERATIONS
Product : Dispose according to legal requirements.
Packaging : Legal requirements are to be considered in regard of reuse or
disposal of used packaging materials
14. TRANSPORT INFORMATION
ADR
UN Number : 1230
Description of the goods : METHANOL SOLUTION
Class : 3
Packaging group : II
Classification Code : FT1
Hazard identification No : 336
Hazard Label : 3 (6.1)
IATA
UN Number : 1230
Description of the goods : Methanol solution
Class : 3
Packaging group : II
Hazard Label : 3 (6.1)
Packing instruction (cargo : 307
aircraft)
Packing instruction : 305
(passenger aircraft)
Packing instruction : Y305
(passenger aircraft)
IMDG
UN Number : 1230
Description of the goods : METHANOL SOLUTION
Class : 3
Packaging group : II
Hazard Label : 3 (6.1)
EmS Number : F-E
Marine pollutant : no
RID
UN Number : 1230
Description of the goods : METHANOL SOLUTION
Class : 3
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SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
HYDRANAL-Aqualyte RO-A
SEC34785
Version 1. Revision Date 22.08.2007 Print Date 27.08.2007
Packaging group : II
Classification Code : FT1
Hazard identification No : 336
Hazard Label : 3 (6.1)
Other information : Risk of serious damage to eyes.
15. REGULATORY INFORMATION
Labelling according to EC Directives 1999/45/EC
Symbol(s) : F Highly flammable
T Toxic
N Dangerous for the environment
R-phrase(s) : R11 Highly flammable.
R23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R39/23/24/25 Toxic: danger of very serious irreversible
effects through inhalation, in contact with
skin and if swallowed.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
S-phrase(s) : S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S45 In case of accident or if you feel unwell,
seek medical advice immediately (show the
label where possible).
S61 Avoid release to the environment. Refer to
special instructions/ Safety data sheets.
Hazardous components which must be listed on the label:
鈥? Methanol 67-56-1
鈥? Dodecyldimethylamine 112-18-5
鈥? Imidazole 288-32-4
16. OTHER INFORMATION
Text of R-phrases referred to under heading 3
Methanol : R11 Highly flammable.
R23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R39/23/24/25 Toxic: danger of very serious irreversible
effects through inhalation, in contact with
skin and if swallowed.
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SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
HYDRANAL-Aqualyte RO-A
SEC34785
Version 1. Revision Date 22.08.2007 Print Date 27.08.2007
Pentan-1-ol : R10 Flammable.
R20 Harmful by inhalation.
R37 Irritating to respiratory system.
R66 Repeated exposure may cause skin
dryness or cracking.
Dodecyldimethylamine : R35 Causes severe burns.
R22 Harmful if swallowed.
R50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
Imidazole : R34 Causes burns.
R22 Harmful if swallowed.
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Final determination of suitability of any
material is the sole responsibility of the user.
This information should not constitute a guarantee for any specific product properties.
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