ChemWatch MSDS MSDS for HOUSE OF KOLOR KOSMIC KOLOR-UK01,02,04,11,12,14-17,19,20
HOUSE OF KOLOR KOSMIC KOLOR-UK01,02,04,11,12,14-
17,19,20
ChemWatch Material Safety Data Sheet
CHEMWATCH 5090-41
Date of Issue: Tue 12-Aug-2003
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
Company:
Meguiar's Australia P/L
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUS
Telephone: (+61 2) 9737 9422
Telephone: 1800 804 182
Fax: (+61 2) 9737 9414
SYNONYMS
SHIPPING NAME
PAINT None
Product Name: House of Kolor Kosmic Kolor-UK01,02,04,11,12,14-17,19,20
Other Names: Product Codes: UK-01, UK-02, UK-904, UK-11
UK-12, UK-14, UK-15, UK-16, UK-17, UK-19
UK-20
CAS RN No(s): None None
UN Number: 1263
Packing Group: III
Dangerous Goods Class: 3
Subsidiary Risk: None, None
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ChemWatch MSDS MSDS for HOUSE OF KOLOR KOSMIC KOLOR-UK01,02,04,11,12,14-17,19,20
Hazchem Code: 3[Y]
Poisons Schedule Number: None
USE
Used according to manufacturers directions.
The use of a quantity of material in an unventilated or confined space may
result in increased exposure and an irritating atmosphere developing
Before starting consider control of exposure by mechanical ventilation
For further information refer to the House of Kolor Technical Manual
PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
Coloured flammable liquid with a solvent odour; does not mix with water.
Boiling Point (掳C): Not Available
Melting Point (掳C): Not Available
Vapour Pressure (kPa): Not Available
Specific Gravity: 0.990-1.014
Flash Point (掳C): 23
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Solubility in Water (g/L): Immiscible
INGREDIENTS
NAME CAS RN %
ethyl-3-ethoxypropionate 763-69-9 5-15
n-butyl acetate 123-86-4 5-15
methyl ethyl ketone 78-93-3 5-15
ethylene glycol monobutyl ether acetate 112-07-2 1-9
pigments at levels not determined to be hazardous 1-20
resin, unregulated NotSpec
HEALTH HAZARD
ACUTE HEALTH EFFECTS
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SWALLOWED
The material has NOT been classified by EC Directives or other classification
systems as "harmful by ingestion". This is because of the lack of corroborating
animal or human evidence. The material may still be damaging to the health of
the individual, following ingestion, especially where pre-existing organ (e.g
liver, kidney) damage is evident. Present definitions of harmful or toxic
substances are generally based on doses producing mortality rather than those
producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may
produce nausea and vomiting. In an occupational setting however, ingestion of
insignificant quantities is not thought to be cause for concern.
EYE
Although the liquid is not thought to be an irritant (as classified by EC
Directives), direct contact with the eye may produce transient discomfort
characterised by tearing or conjunctival redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable control measures be used in an occupational setting.
Inhalation of vapours may cause drowsiness and dizziness. This may be
accompanied by narcosis, drowsiness, reduced alertness, loss of reflexes, lack
of coordination and vertigo.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
Studies with some ethylene glycol ethers and their esters indicate reproductive
changes, testicular atrophy, infertility and kidney function changes. The
metabolic acetic acid derivatives of the glycol ethers, not the ether itself,
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have been found to be the proximal reproductive toxin in animals. The potency of
these metabolites decrease significantly as the chain length of the ether
increases. Consequently glycol ethers with longer substituents (e.g diethylene
glycols, triethylene glycols) have not generally been associated with
reproductive effects. One of the most sensitive indicators of toxic effects
observed from many of the glycol ethers is an increase in the erythrocytic
osmotic fragility in rats. This appears to be related to the development of
haemoglobinuria (blood in the urine) at higher exposure levels or as a result of
chronic exposure. Ethylene glycol ethers and acetates are mainly metabolised to
alkoxyacetic acids but there is also a minor pathway through ethylene glycol to
oxalic acid. The main pathway of ethylene glycol ethers is associated with
significant clinical or experimental health effects, but the minor pathway is
also interesting because formation of urinary stones depends principally upon
urinary concentration of oxalate and calcium. In one study (1) the tendency to
form urinary stones was 2.4 times higher amongst silk-screen printers exposed to
ethylene glycol ethers, than among office workers. (1) Laitinen J., et al:
Occupational Environmental Medicine 1996, 53 595-600
FIRST AID
SWALLOWED
路 Immediately give a glass of water.
路 First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.
EYE
If this product comes in contact with eyes:
路 Wash out immediately with water.
路 If irritation continues, seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Other measures are usually unnecessary.
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ADVICE TO DOCTOR
Treat symptomatically.
For acute or short term repeated exposures to ethylene glycol:
路 Early treatment of ingestion is important. Ensure emesis is satisfactory.
路 Test and correct for metabolic acidosis and hypocalcaemia.
路 Apply sustained diuresis when possible with hypertonic mannitol.
路 Evaluate renal status and begin haemodialysis if indicated. [I.L.O]
路 Rapid absorption is an indication that emesis or lavage is effective only in
the first few hours. Cathartics and charcoal are generally not effective.
路 Correct acidosis, fluid/electrolyte balance and respiratory depression in the
usual manner. Systemic acidosis (below 7.2) can be treated with intravenous
sodium bicarbonate solution.
路 Ethanol therapy prolongs the half-life of ethylene glycol and reduces the
formation of toxic metabolites.
路 Pyridoxine and thiamine are cofactors for ethylene glycol metabolism and
should be given (50 to 100 mg respectively) intramuscularly, four times per day
for 2 days.
路 Magnesium is also a cofactor and should be replenished. The status of
4-methylpyrazole, in the treatment regime, is still uncertain. For clearance of
the material and its metabolites, haemodialysis is much superior to peritoneal
dialysis.
[Ellenhorn and Barceloux: Medical Toxicology]
It has been suggested that there is a need for establishing a new biological
exposure limit before a workshift that is clearly below 100 mmol ethoxy-acetic
acids per mole creatinine in morning urine of people occupationally exposed to
ethylene glycol ethers. This arises from the finding that an increase in urinary
stones may be associated with such exposures.
Laitinen J., et al: Occupational & Environmental Medicine 1996; 53, 595-600
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
No data for House of Kolor Kosmic Kolor-UK01,02,04,11,12,14-17,19,20.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m鲁): 515.5341 mg/m鲁
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
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Component Breathing Zone ppm Breathing Zone mg/m鲁
Mixture Conc: (%)
ethylene glycol monobutyl ether ac 85.9224 9 0
ethyl-3-ethoxypropionate 23.87 143.2039 15
methyl ethyl ketone 48.27 143.2039 15
n-butyl acetate 30.13 143.2039 15
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m鲁): 45 mg/m鲁
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
INGREDIENT DATA
ETHYL-3-ETHOXYPROPIONATE:
No exposure limits set by NOHSC or ACGIH
CEL TWA: 50 ppm, 300mg/m鲁 [Eastman]
N-BUTYL ACETATE:
TLV TWA: 150 ppm [ACGIH]
TLV STEL: 200 ppm [ACGIH]
PEL TWA: 150 ppm, 710 mg/m鲁 [OSHA Z1]
TLV TWA: 150 ppm, 713 mg/m鲁; STEL: 200 ppm, 950 mg/m鲁
ES TWA: 150 ppm, 713 mg/m鲁; STEL: 200 ppm, 950 mg/m鲁
OES TWA: 150 ppm, 724 mg/m鲁; STEL: 200 ppm, 966 mg/m鲁
MAK value: 100 ppm, 480 mg/m鲁
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
Odour Threshold Value: 0.0063 ppm (detection), 0.038-12 ppm (recognition)
IDLH Level: 1700 ppm (lower explosive limit)
Exposure at or below the recommended TLV-TWA is thought to prevent
significant irritation of the eyes and respiratory passages as well as
narcotic effects. In light of the lack of substantive evidence regarding
teratogenicity and a review of acute oral data a STEL is considered
inappropriate.
METHYL ETHYL KETONE:
TLV TWA: 200 ppm BEI [ACGIH]
TLV STEL: 300 ppm BEI [ACGIH]
PEL TWA: 200 ppm, 590 mg/m鲁 [OSHA Z1]
TLV TWA: 200 ppm, 590 mg/m鲁; STEL: 300 ppm, 885 mg/m鲁
ES TWA: 150 ppm, 445 mg/m鲁; STEL: 300 ppm, 890 mg/m鲁
OES TWA: 200 ppm, 600 mg/m鲁; STEL: 300 ppm, 899 mg/m鲁 skin
MAK value: 200 ppm, 600 mg/m鲁
Designated H in List of MAK values: Danger of cutaneous absorption.
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Absorption of such substances through the skin can pose an incomparably larger
danger of toxicity than their inhalation. To avoid health risks when handling
such substances, meticulous cleaning of the skin, hair and clothing is
imperative.
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 3000 ppm
Odour Threshold Value: Variously reported as 2 ppm and 4.8 ppm
Odour threshold: 2 ppm (detection); 5 ppm (recognition)
25 ppm (easy recognition); 300 ppm IRRITATING
Exposures at or below the recommended TLV-TWA are thought to prevent
injurious systemic effects and to minimise objections to odour and
irritation. Where synergism or potentiation may occur stringent control of
the primary toxin (e.g. n-hexane or methyl butyl ketone) is desirable and
additional consideration should be given to lowering MEK exposures.
ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE:
TLV TWA: 20 ppm A3 [ACGIH]
TLV TWA: 20 ppm A3
CAUTION: This substance has been classified by the ACGIH as A3 Animal Carcinogen
(at relatively high doses)
MAK value: 20 ppm, 130 mg/m鲁 (skin)
Exposure limits with "skin" notation indicate that vapour and liquid may be
absorbed through intact skin. Absorption by skin may readily exceed vapour
inhalation exposure. Symptoms for skin absorption are the same as for
inhalation. Contact with eyes and mucous membranes may also contribute to
overall exposure and may also invalidate the exposure standard.
Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparably larger
danger of toxicity than their inhalation. To avoid health risks when handling
such substances, meticulous cleaning of the skin, hair and clothing is
imperative.
MAK Category II Peak Limitation: For substances with systemic effects and with a
half-life in humans of less than two hours.
Allows excursions of 2 times the MAK value, for 30 minutes (on average), four
times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
Threshold odour concentration: 50% recognition, 0.64 ppm.
Toxic doses cause red blood cell lysis, and in consequence,
haemoglobinuria and sometimes, kidney damage.
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ENGINEERING CONTROLS
For flammable liquids and flammable gases, local exhaust ventilation or a
process enclosure ventilation system may be required. Ventilation equipment
should be explosion-resistant.
Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min.)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood-local control only
motion
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
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PERSONAL PROTECTION
EYE
Safety glasses with side shields
Chemical goggles.
Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber
OTHER
Overalls.
PVC Apron.
PVC protective suit may be required if exposure severe.
Eyewash unit.
Ensure there is ready access to a safety shower.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor (Min) Half-Face Respirator Full-Face Respirator
5 x ES A-AUS -
A-PAPR-AUS
25 x ES Air-line* A-2
A-PAPR-2
50 x ES - A-3
50+ x ES - Air-line**
* - Continuous-flow; ** - Continuous-flow or positive pressure demand
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
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SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Packing as supplied by manufacturer. Plastic containers may only be used if
approved for flammable liquid. Check that containers are clearly labelled and
free from leaks.
路 For low viscosity materials (i) : Drums and jerry cans must be of the
non-removable head type. (ii) : Where a can is to be used as an inner package,
the can must have a screwed enclosure.
路 For materials with a viscosity of at least 2680 cSt. (23 deg. C)
路 For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
路 Manufactured product that requires stirring before use and having a viscosity
of at least 20 cSt (25 deg. C)
(i) : Removable head packaging;
(ii) : Cans with friction closures and
(iii) : low pressure tubes and cartridges may be used.
路 Where combination packages are used, and the inner packages are of glass,
there must be sufficient inert cushioning material in contact with inner and
outer packages
路 In addition, where inner packagings are glass and contain liquids of packing
group I there must be sufficient inert absorbent to absorb any spillage, unless
the outer packaging is a close fitting moulded plastic box and the substances
are not incompatible with the plastic.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents
STORAGE REQUIREMENTS
路 Store in original containers in approved flammable liquid storage area.
路 DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
路 No smoking, naked lights, heat or ignition sources.
路 Keep containers securely sealed.
路 Store away from incompatible materials in a cool, dry, well-ventilated area.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
TRANSPORTATION
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Class 3 - Flammable liquids shall not be loaded in the same vehicle or packed in
the same vehicle or packed in the same freight container with:
Class 1 - Explosives;
Class 2.1 - Flammable gases (where both flammable liquids and flammable gases
are in bulk);
Class 2.3 - Poisonous gases;
Class 4.2 - Spontaneously combustible substances;
Class 5.1 - Oxidising agents;
Class 5.2 - Organic peroxides;
Class 7 - Radioactive substances.
SPILLS AND DISPOSAL
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb small quantities with vermiculite or other absorbent
material.
路 Wipe up.
路 Collect residues in a flammable waste container.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water
course.
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse / absorb vapour.
路 Contain spill with sand, earth or vermiculite.
路 Use only spark-free shovels and explosion proof equipment.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
DISPOSAL
路 Recycle wherever possible.
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路 Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility
can be identified.
路 Dispose of by: Burial in a licenced land-fill or Incineration in a licenced
apparatus (after admixture with suitable combustible material)
路 Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorised landfill.
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water
course.
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
WARNING: In use may form flammable/ explosive vapour-air mixtures.
路 Liquid and vapour are flammable.
路 Moderate fire hazard when exposed to heat or flame.
路 Vapour forms an explosive mixture with air.
路 Moderate explosion hazard when exposed to heat or flame.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition leading to violent rupture of
containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include.
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carbon dioxide (CO2).
other pyrolysis products typical of burning organic material.
WARNING: Long standing in contact with air and light may result in the formation
of potentially explosive peroxides.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result
HAZCHEM
3[Y]
CONTACT POINT
COMPANY CONTACT
(+61 2) 9737 9422
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEW ZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: 0800 764 766
NZ EMERGENCY SERVICES: 111
End of Report
Issue Date: Tue 12-Aug-2003
Print Date: Mon 25-Aug-2003
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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