MATERIAL SAFETY DATA SHEET
HTS 7120B Page: 1
PRODUCT NAME: HTS 7120B HMIS CODES: H F R P
PRODUCT CODE: EL-120-B-RG-05 211J
SECTION I - MANUFACTURER IDENTIFICATION
================== =================
MANUFACTURER'S NAME: HESTERMAN TECHNICAL SERVICES
ADDRESS : 190 HODSMAN ROAD
REGINA, SASK. CANADA S4N 5X4
EMERGENCY PHONE : 613-996-6666 DATE PRINTED : 8/19/96
DATE REVISED : 3/15/04
INFORMATION PHONE : (306) 721-1339 NAME OF PREPARER : ENVIRONMENTAL SECT.
SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION
========== =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP PERCENT
CASTOR OIL 8001-79-4 UNKNOWN N/A 65
OSHA PEL: NOT EST., ACGIH TLV: NOT EST., STEL: NOT EST.
2-PROPANOL 1-1, 1'-PHENYLAMINOBIS. 3077-13-2 NO DATA N/A 16
NO EXPOSURE GUIDELINES HAVE BEEN ESTABLISHED FOR THIS CHEMICAL.
BUTYL BENZYL PHTHALATE 85-68-7 8.6x10-6 68F/20C 12
OSHA PEL - 8 HOUR TIME-WEIGHTED AVERAGE: 5MG/M3
ACGIH TLV - 8 HOUR TIME-WEIGHTED AVERAGE: 5MG/M3
MANUFACTURER OF THIS RAW MATERIAL HAS ADOPTED A GENERAL GUIDELINE THAT
EXPOSURE TO PHTHALATE ESTERS SHOULD BE KEPT BELOW 5MG/M3 (8 HOUR TIME-
WEIGHTED AVERAGE).
TITANIUM DIOXIDE 13463-67-7 N/A N/A 4
TITANIUM DIOXIDE, >93%, CAS#13463-67-7, ACGIH TLV-10MG/M3, TOTAL DUST 8 HR
TWA, OSHA PEL-15MG/M3, TOTAL DUST, 8 HR TWA, AEL(ACCEPTABLE EXPOSURE LIMIT)
OF 10MG/M3, TOTAL DUST 8 HR TWA, 5MG/M3 RESPIRABLE DUST 8 HR TWA. (AEL IS
THE EXPOSURE LIMIT RECOMMENDED BY THE MANUFACTURER OF THIS CHEMICAL).
AMORPHOUS SILICA, 3%, CAS#7631-86-9, ACGIH TLV-10MG/M3, TOTAL DUST 8 HR TWA
OSHA PEL-80MG/M3 / % SiO2-8 HR TWA, AEL-3MG/M3, 8 HR TWA, RESPIRABLE DUST.
AEL-6MG/M3, 8 HR TWA, TOTAL DUST.
ALUMINUM HYDROXIDE, 2.5%, CAS#21645-51-2, NO EXPOSURE GUIDELINES HAVE BEEN
ESTABLISHED FOR THIS CHEMICAL.
SODIUM POTASSIUM ALUMINOSILICATE 12736-96-8 NA NA 2
SODIUM POTASSIUM ALUMINOSILICATE, CAS#12736-96-8, 95-100%, OSHA PEL/ACGIH
TLV-10MG/M3 TWA, TOTAL DUST.
*** No toxic chemical(s) subject to the reporting requirements of section 313 of
Title III and of 40 CFR 372 are present. ***
THE HAZARDS OF BOTH PART A AND PART B WILL BE EXHIBITED WHEN BOTH PARTS ARE
COMBINED. THIS MSDS MAY BE USED FOR OTHER COLORS AND CONTAINER SIZES OF THIS
PRODUCT.
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
=============== ============
BOILING RANGE: 464F/240C - 595F/312.8C SPECIFIC GRAVITY (H2O=1): 1.03
VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER
COATING V.O.C.: COATING V.O.C.:
0.01 lb/gl 1 g/l
MATERIAL V.O.C.: MATERIAL V.O.C.:
0.01 lb/gl 1 g/l
SOLUBILITY IN WATER: NOT ESTABLISHED.
APPEARANCE AND ODOR: VISCOUS, OFF-WHITE LIQUID, AROMATIC ODOR.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
================= ==============
FLASH POINT: >275F/135C(TCC).
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: .26% UPPER: N/A
EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG
SPECIAL FIREFIGHTING PROCEDURES
DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT FULL PROTECTIVE
EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING APPARATUS(PRESSURE-DEMAND
MSHA/NIOSH APPROVED OR EQUIVALENT)TO PROTECT AGAINST THE HAZARDOUS EFFECTS OF
COMBUSTION PRODUCTS AND OXYGEN DEFICIENCY. USE WATER SPRAY TO COOL FIRE EXPOSED
STRUCTURES AND TO COOL FIRE EXPOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND
POSSIBLE RUPTURE OF CONTAINER.
MATERIAL SAFETY DATA SHEET
HTS 7120B Page: 2
UNUSUAL FIRE AND EXPLOSION HAZARDS
HEAT FROM FIRE CAN GENERATE FLAMMABLE VAPORS. WHEN MIXED WITH AIR AND EXPOSED TO
IGNITION SOURCE, VAPORS CAN BURN IN OPEN OR EXPLODE IF CONFINED. VAPORS MAY BE
HEAVIER THAN AIR AND MAY TRAVEL LONG DISTANCES ALONG GROUND BEFORE
IGNITING/FLASHING BACK TO VAPOR SOURCE. FINE SPRAYS/MISTS MAY BE COMBUSTIBLE AT
TEMPERATURES BELOW NORMAL FLASH POINT.
SECTION V - REACTIVITY DATA
======================== =======================
STABILITY: STABLE
CONDITIONS TO AVOID
AVOID PROLONGED HEATING ABOVE 160 DEGREES F. KEEP AIR TIGHT AND FREE OF
MOISTURE.
INCOMPATIBILITY (MATERIALS TO AVOID)
AVOID CONTACT WITH STRONG OXIDIZING AGENTS. CONTACT WITH THE FOLLOWING MATERIALS
MAY CAUSE A REACTION GENERATING HEAT OR DECOMPOSITION: WATER.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE, ANILINE, OXIDES OF NITROGEN AND OTHER
UNIDENTIFIED ORGANIC COMPOUNDS IN SMOKE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
SECTION VI - HEALTH HAZARD DATA
==================== =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
VAPOR OR SPRAY MIST CAN CAUSE HEADACHE, NAUSEA AND IRRITATION OF THE NOSE,
THROAT AND LUNGS.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
EYE: MAY CAUSE SEVERE IRRITATION WITH CORNEAL INJURY WHICH MAY RESULT IN
PERMANENT IMPAIRMENT OF VISION, EVEN BLINDNESS. SKIN: PROLONGED OR REPEATED
EXPOSURE IS EXPECTED TO BE TOXIC BY DERMAL ABSORBTION AND MAY CAUSE SKIN
IRRITATION AND DERMATITIS.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
NONE KNOWN
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
SWALLOWING THE LIQUID MAY RESULT IN VOMITING. IF VOMITING OCCURS SPONTANEOUSLY,
DO NOT ALLOW VOMITUS TO BE BREATHED INTO THE LUNGS, AS EVEN A SMALL QUANTITY IN
THE LUNGS MAY RESULT IN CHEMICAL PNEUMONITIS & PULMONARY/EDEMA HEMORRHAGE.
HEALTH HAZARDS (ACUTE AND CHRONIC)
ACUTE: SEVERE EYE IRRITATION. SKIN IRRITATION. PROLONGED OR REPEATED INHALATION
OF VAPOR OR SPRAY MIST MAY CAUSE NASAL AND RESPIRATORY IRRITATION AND
HEADACHE.CHRONIC: CORNEAL INJURY WHICH MAY RESULT IN PERMANENT IMPAIRMENT OF
VISION, EVEN BLINDNESS. SKIN DISORDERS SUCH AS DERMATITIS.
CARCINOGENICITY: NTP CARCINOGEN: NO IARC MONOGRAPHS: NO OSHA REGULATED: YES
PRODUCT INGREDIENTS ARE AT OR LESS THAN de minimis LEVELS OR ARE NOT CONSIDERED
TO BE CARCINOGENS BY THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), THE
NATIONAL TOXICOLOGY PROGRAM (NTP) OR BY THE OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA).
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
PRE-EXISTING EYE, SKIN, ALLERGIES, AND RESPIRATORY DISORDERS.
EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT: IMMEDIATE AND CONTINUOUS IRRIGATION WITH FLOWING WATER FOR AT LEAST
30 MINUTES IS IMPERATIVE. PROMPT MEDICAL CONSULTATION IS ESSENTIAL. SKIN:
IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES AND WASH BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING,
IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN USING TRAINED MEDICAL PERSONNEL AND
GET IMMEDIATE MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DO NOT INDUCE
VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
MATERIAL SAFETY DATA SHEET
HTS 7120B Page: 3
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
=========== ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
WEAR SKIN, EYE & RESPIRATORY PROTECTION DURING CLEAN-UP. EVACUATE AREA OF ALL
NON-ESSENTIAL PERSONNEL. SHUT OFF OR REMOVE ALL IGNITION SOURCES. VENTILATE
SPILL AREA. DIKE, AND CONTAIN AND/OR ABSORB WITH INERT MATERIAL (SAND, EARTH OR
OTHER SUITABLE NON-COMBUSTIBLE MATERIAL) TO PREVENT ENTRY INTO STORM DRAINS,
SEWERS AND OTHER UNAUTHORIZED TREATMENT/DRAINAGE SYSTEMS AND NATURAL WATERWAYS.
SCOOP UP AND PLACE IN APPROVED CONTAINERS FOR PROPER DISPOSAL. COVER WITH LID.
IF SPILL OCCURS NEAR AIR INLETS OR INSIDE, TURN OFF HEATING OR AIR-CONDITIONING
EQUIPMENT TO PREVENT CONTAMINATING BUILDING.
WASTE DISPOSAL METHOD
DISPOSE OF UNUSED PRODUCT OR CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING
UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE
FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL
PROCEDURES. INCINERATION IS ACCEPTABLE AND THE PREFERRED METHOD OF DISPOSAL,
HOWEVER; NITROGEN OXIDE EMISSIONS CONTROLS MAY BE REQUIRED TO MEET
SPECIFICATIONS. CHEMICAL AND BIOLOGICAL DEGRADATION IS POSSIBLE. A SUITABLE
INDUSTRIAL OR MUNICIPAL WASTE TREATMENT SYSTEM CAN BE USED DEPENDING ON THE
QUALITY AND QUANTITY OF WASTE TO BE TREATED, THE TREATMENT PLANT CAPABILITY, AND
DISCHARGE WATER QUALITY STANDARDS. DISPOSE OF IN AN APPROVED LANDFILL IF
ALLOWED LOCALLY. EMPTY CONTAINERS WILL RETAIN PRODUCT RESIDUE AND VAPORS AND
ARE SUBJECT TO PROPER WASTE DISPOSAL, AS ABOVE.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
KEEP FROM FREEZING. KEEP CONTAINER COOL AND DRY. USE AND STORE THIS PRODUCT WITH
ADEQUATE VENTILATION. KEEP PRODUCT CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
AVOID SUBJECTING THIS PRODUCT TO EXTREME TEMPERATURE VARIATIONS.
OTHER PRECAUTIONS
CLOSED CONTAINERS MAY EXPLODE DUE TO PRESSURE BUILD-UP IF EXPOSED TO EXTREME
HEAT. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID PROLONGED OR REPEATED
BREATHING OF VAPOR OR SPRAY MIST. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
EMPTY CONTAINERS, ESPECIALLY DRUMS, SHOULD BE COMPLETELY DRAINED, PROPERLY
BUNGED AND PROMPTLY RETURNED TO A DRUM RECONDITIONER, OR PROPERLY DISPOSED OF.
USE ONLY IN A WELL VENTILATED AREA. KEEP OUT OF THE REACH OF CHILDREN.
SECTION VIII - CONTROL MEASURES
===================== ======================
RESPIRATORY PROTECTION
WEAR A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE VAPOR OR MIST CONCENTRATION
AT THE POINT OF USE. APPROPRIATE RESPIRATORS MAY BE A FULL FACE PIECE OR A HALF
MASK AIR-PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR ORGANIC VAPORS/MISTS, A
SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, OR A SUPPLIED-
AIR RESPIRATOR. REFER TO PART A MSDS FOR PROTECTION FROM ISOCYANATES. REFER TO
OSHA STANDARD 29 CFR 1910.134 FOR ADDITIONAL INFORMATION.
VENTILATION
IF CURRENT VENTILATION PRACTICES DURING MIXING AND APPLICATION OPERATIONS ARE
NOT ADEQUATE TO MINIMIZE EXPOSURE, USE LOCAL EXHAUST VENTILATION CAPABLE OF
MAINTAINING EMISSIONS AT THE POINT OF USE BELOW THE PEL OR TLV OR OTHER EXPOSURE
GUIDELINES, AS APPROPRIATE. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
MECHANICAL EXHAUST VENTILATION, WITH VOLUME AND PATTERN CAPABLE OF MAINTAINING A
FRESH AIR SUPPLY, MAY BE NECESSARY IN CONFINED SPACES. REFER TO OSHA STANDARD 29
CFR 1910.94 AND/OR ACGIH INDUSTRIAL VENTILATION FOR GUIDANCE ABOUT ADEQUATE
VENTILATION. TURN OFF HEATING AND/OR AIR CONDITIONING EQUIPMENT TO PREVENT
CONTAMINATING BUILDING.
PROTECTIVE GLOVES
THE USE OF GLOVES IMPERMEABLE TO THE SPECIFIC MATERIAL HANDLED IS ADVISED TO
PREVENT SKIN CONTACT AND POSSIBLE IRRITATION. NOTE THAT PVA DEGRADES IN WATER.
EYE PROTECTION
CHEMICAL GOGGLES. IF SPLASHING MAY OCCUR OR DURING SPRAY OPERATIONS WEAR A FACE
SHIELD, UNLESS A FULL FACE PIECE RESPIRATOR IS USED. DO NOT WEAR CONTACT LENSES
AS THEY MAY CONTRIBUTE TO THE SEVERITY OF INJURY TO THE EYE FROM EXPOSURE TO
LIQUID AND/OR VAPORS AND SPRAY MIST.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
LONG SLEEVED SHIRT, TROUSERS, SAFETY SHOES AND GLOVES. AN EYEWASH STATION AND
SAFETY SHOWER SHOULD BE AVAILABLE & READY FOR USE. IMPERVIOUS CLOTHING SHOULD BE
WORN AS NEEDED. PROTECTIVE CLOTHING SHOULD BE SELECTED AND USED IN ACCORDANCE
WITH "GUIDELINES FOR THE SELECTION OF CHEMICAL PROTECTIVE CLOTHING" PUBLISHED BY
ACGIH. (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS).
MATERIAL SAFETY DATA SHEET
HTS 7120B Page: 4
WORK/HYGIENIC PRACTICES
WASH AT THE END OF EACH WORK SHIFT AND BEFORE EATING, SMOKING OR USING THE
TOILET. PROMPTLY REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE WEARING.
DISCARD CONTAMINATED LEATHER ARTICLES. EXAMINE PROTECTIVE GLOVES AND CLOTHING
BEFORE USE. DISCARD UPON FINDING EVIDENCE OF HOLES CRACKS OR LEAKS.
ADDITIONAL REGULATORY INFORMATION
STATUS OF SUBSTANCE LISTS: THE CONCENTRATIONS SHOWN IN SECTION II ARE MAXIMUM
FOR CEILING LEVELS (WEIGHT %) TO BE USED FOR CALCULATIONS FOR REGULATIONS. FEDERAL
EPA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY
ACT OF 1980 (CERCLA) REQUIRES NOTIFICATION OF THE NATIONAL RESPONSE CENTER OF
RELEASE OF QUANTITIES OF HAZARDOUS SUBSTANCES EQUAL TO OR GREATER THAN THE
REPORTABLE QUANTITIES (RQs) IN 40 CFR 302.4
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL THAT COULD REQUIRE REPORTING UNDER
THE STATUTE ARE
1,3-BUTADIENE, CAS# 106-99-0. RQ 10#.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) TITLE III
REQUIRES EMERGENCY PLANNING BASED ON THRESHOLD PLANNING QUANTITIES (TPQs) AND
RELEASE REPORTING BASED ON REPORTABLE QUANTITIES (RQs) IN 40 CFR 355 (USED FOR
SARA 302, 304, 311 AND 312).
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL THAT COULD REQUIRE REPORTING UNDER
THE STATUTE ARE
1,3-BUTADIENE, CAS# 106-99-0. RQ 10#.
REQUIRES SUBMISSION OF ANNUAL REPORTS OF RELEASE OF TOXIC CHEMICALS THAT APPEAR
IN 40 CFR 372 (FOR SARA 313). THIS INFORMATION MUST BE INCLUDED IN ALL MSDSs
THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL THAT COULD REQUIRE REPORTING UNDER
THE STATUTE ARE:
SEE SECTION II
STATE RIGHT TO KNOW:
CALIFORNIA PROPOSITION 65:
1,3-BUTADIENE, CAS# 106-99-0, KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
IN ADDITION TO THE ABOVE NAMED CHEMICALS, IF ANY, THIS PRODUCT MAY CONTAIN TRACE
AMOUNTS OF SOME CHEMICALS CONSIDERED BY THE STATE OF CALIFORNIA TO BE
CARCINOGENS OR REPRODUCTIVE TOXICANTS
TOXIC SUBSTANCES CONTROL ACT (TSCA) STATUS
THE COMPONENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON THE
U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
THE REMAINING PERCENTAGE OF UNSPECIFIED INGREDIENTS, IF ANY, ARE NOT CONTAINED
IN ABOVE de minimis CONCENTRATIONS OR ARE BELIEVED TO BE NON-HAZARDOUS UNDER THE
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200), AND MAY CONSIST OF
PIGMENTS, FILLERS, DEFOAMERS, WETTING AGENTS, ANTI-BACTERIAL AGENTS, RESINS,
DRYERS, WATER AND/OR SOLVENTS IN VARYING CONCENTRATIONS.
========================= SECTION IX - DISCLAIMER ==========================
THE INFORMATION CONTAINED HEREIN IS FURNISHED WITHOUT WARRANTY OF ANY KIND.
USERS SHOULD CONSIDER THESE DATA ONLY AS A SUPPLEMENT TO OTHER INFORMATION
GATHERED BY THEM & DETERMINE THE SUITABILITY & COMPLETENESS OF INFORMATION FROM
ALL SOURCES TO ASSURE PROPER USE & DISPOSAL OF THESE MATERIALS & THE SAFETY &
HEALTH OF EMPLOYEES & CUSTOMERS.
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