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33126-00 MOBIL REGULAR UNLEADED GASOLINE
MATERIAL SAFETY DATA BULLETIN
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1. PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME: MOBIL REGULAR UNLEADED GASOLINE
SUPPLIER: EXXONMOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA 22037
24 - Hour Health and Safety Emergency (call collect): 609-737-4411
24 - Hour Transportation Emergency:
CHEMTREC: 800-424-9300 202-483-7616
LUBES AND FUELS: 281-834-3296
Product and Technical Information:
Lubricants and Specialties: 800-662-4525 800-443-9966
Fuels Products: 800-947-9147
MSDS Fax on Demand: 713-613-3661
MSDS Internet Website: http://www.exxon.com, http://www.mobil.com
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2. COMPOSITION/INFORMATION ON INGREDIENTS
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CHEMICAL NAMES AND SYNONYMS: HYDROCARBONS AND ADDITIVES
GLOBALLY REPORTABLE MSDS INGREDIENTS:
Substance Name Approx. Wt%
-------------- -----------
GASOLINE (8006-61-9) 100
COMPONENT(S) OF PRODUCT INGREDIENTS INCLUDE:
METHYL-TERT-BUTYL ETHER 15
(1634-04-4)
ETHANOL (64-17-5) 11
XYLENE (1330-20-7) 10
ISOPENTANE (78-78-4) 9
TRIMETHYL BENZENE 8
(25551-13-7)
TOLUENE (108-88-3) 5
BUTANE (106-97-8) 4
2-METHYLPENTANE (107-83-5) 4
PENTANE (109-66-0) 4
3-METHYLPENTANE (96-14-0) 2
BENZENE (71-43-2) 2
2,3-DIMETHYLBUTANE (79-29-8) 2
N-HEXANE (110-54-3) 2
ETHYL BENZENE (100-41-4) 2
3- METHYLHEXANE (589-34-4) 2
2- METHYLHEXANE (591-76-4) 1
METHYLCYCLOHEXANE (108-87-2) 1
NOTE: The concentration of the components shown above may vary
substantially. In certain countries benzene content may be limited to
lower levels (eg. US reformulated gasoline). Oxygenates such as
tertiary-amyl-methyl ether, ethanol, di-isopropyl ether, and
ethyl-tertiary-butyl ether may be present (eg. concentration to provide
a minimum oxygen content of 1.5 Wt% in the US). Because of volatility
considerations, gasoline vapor may have concentrations of components very
different from those of liquid gasoline. The major components of
gasoline vapor are: butane, isobutane, pentane and isopentane. The
reportable component percentages, shown in the Regulatory Information
section, are based on API's evaluation of a typical gasoline mixture.
See Section 8 for exposure limits (if applicable).
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3. HAZARDS IDENTIFICATION
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This product is considered hazardous according to regulatory guidelines
(See Section 15).
EMERGENCY OVERVIEW: Clear (May Be Dyed) Liquid. EXTREMELY FLAMMABLE,
HIGH HAZARD. Liquid can release considerable vapor at
temperatures below ambient which readily form flammable mixtures.
Vapors settle to ground level and may reach, via drains and other
underground passages, ignition sources remote from the point of
escape. Product can accumulate a static charge which may cause a
fire or explosion. DOT ERG No. : 128
POTENTIAL HEALTH EFFECTS: Skin irritation. May cause eye and
respiratory irritation, headache, dizziness, nausea, loss of
consciousness, and in cases of extreme exposure, possibly death.
Low viscosity material-if swallowed may enter the lungs and cause
lung damage. Overexposure to benzene may result in cancer, blood
disorders and damage to the bone marrow. Long-term exposure to
gasoline vapor has caused kidney and liver cancer in laboratory
animals. Case reports of chronic gasoline abuse (such as
sniffing) and chronic misuse as a solvent or as a cleaning agent
have shown a range of nervous system effects, sudden deaths from
heart attacks, blood effects and leukemia. These effects are not
expected to occur at exposure levels encountered in the
distribution and use of gasoline as a motor fuel.
POTENTIAL ENVIRONMENTAL EFFECTS: Toxic to aquatic organisms; may cause
long-term adverse effects in the aquatic environment.
For further health effects/toxicological data, see Section 11.
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4. FIRST AID MEASURES
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EYE CONTACT: Flush thoroughly with water. If irritation occurs, call
a physician.
SKIN CONTACT: Wash contact areas with soap and water. Immediately
remove contaminated clothing, including shoes. (See Section 16 -
Injection Injury)
INHALATION: Remove from further exposure. If respiratory irritation,
dizziness, nausea, or unconsciousness occurs, seek immediate
medical assistance. If breathing has stopped, assist ventilation
with mechanical device or use mouth-to-mouth resuscitation.
INGESTION: Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIANS: Material if ingested may be aspirated into the
lungs and can cause chemical pneumonitis. PRE-EXISTING MEDICAL
CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE: Skin contact may
aggravate an existing dermatitis. Benzene- Individuals with
liver disease may be more susceptible to toxic effects. Hexane-
Individuals with neurological disease should avoid exposure.
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5. FIRE-FIGHTING MEASURES
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EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water Fog.
SPECIAL FIRE FIGHTING PROCEDURES: Evacuate area. For large spills,
fire fighting foam is the preferred agent and should be applied
in sufficient quantities to blanket the product surface. Water
may be ineffective, but water should be used to keep fire-exposed
containers cool. Water spray may be used to flush spill away
from exposures, but good judgement should be practiced to prevent
spreading of the product into sewers, streams or drinking water
supplies. If a leak or spill has not ignited, apply a foam
blanket to suppress the release of vapors. If foam is not
available, a water spray curtain can be used to disperse vapors
and to protect personnel attempting to stop the leak.
SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire
fighters must use self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: EXTREMELY FLAMMABLE, HIGH HAZARD.
Liquid can release considerable vapor at temperatures below
ambient which readily form flammable mixtures. Vapors settle to
ground level and may reach, via drains and other underground
passages, ignition sources remote from the point of escape.
Product can accumulate a static charge which may cause a fire or
explosion.
COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides,
aldehydes and other decomposition products, in the case of
incomplete combustion.
Flash Point C(F): < -40(-40) (ASTM D-56).
Flammable Limits (approx.% vol.in air) - LEL: 1.4%, UEL: 7.6%
NFPA HAZARD ID: Health: 1, Flammability: 3, Reactivity: 0
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6. ACCIDENTAL RELEASE MEASURES
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NOTIFICATION PROCEDURES: Report spills/releases as required to
appropriate authorities. U.S. Coast Guard and EPA regulations
require immediate reporting of spills/releases that could reach
any waterway including intermittent dry creeks. Report
spill/release to Coast Guard National Response Center toll free
number (800)424-8802. In case of accident or road spill notify
CHEMTREC (800) 424-9300.
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED:
LAND SPILL: Eliminate sources of ignition. Warn occupants in
downwind areas of fire and explosion hazard. Shut off source taking
normal safety precautions. Take measures to minimize the effects on
ground water. Recover by pumping using explosion-proof equipment or
contain spilled liquid with sand or other suitable absorbent and
remove mechanically into containers. If necessary, dispose of
adsorbed residues as directed in Section 13.
WATER SPILL: Eliminate sources of ignition. Advise occupants and
ships in the vicinity in downwind areas of fire and explosion hazard
and warn them to stay clear. Notify port and other relevant
authorities. Do not confine in area of leakage. Allow liquid to
evaporate from the surface. Do not use dispersants.
ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers,
water sources or low lying areas; advise the relevant authorities
if it has, or if it contaminates soil/vegetation.
PERSONAL PRECAUTIONS: See Section 8
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7. HANDLING AND STORAGE
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HANDLING: USE NON-SPARKING TOOLS AND EXPLOSION-PROOF EQUIPMENT. NEVER
SIPHON GASOLINE BY MOUTH. GASOLINE SHOULD NOT BE USED AS A
SOLVENT OR AS A CLEANING AGENT. Avoid contact with skin. Avoid
inhalation of vapors or mists. Use in well ventilated area away
from all ignition sources. This liquid is volatile and gives off
invisible vapors. Either the liquid or vapor may settle in low
areas or travel some distance along the ground or surface to
ignition sources where they may ignite or explode. Use product
with caution around heat, sparks, pilot lights, static
electricity, and open flames. It is unlawful and dangerous to
put gasoline into unapproved containers. Do not fill container
in or on a vehicle. Static electricity may ignite vapors and
cause fire. Place container on ground when filling and keep
nozzle in contact with container. See Section 8 for additional
personal protection advice when handling this product.
STORAGE: Drums must be grounded and bonded and equipped with
self-closing valves, pressure vacuum bungs and flame arresters.
Store away from all ignition sources in a cool, well ventilated
area equipped with an automatic sprinkling system. Outside or
detached storage preferred. Storage containers should be
grounded and bonded.
SPECIAL PRECAUTIONS: To prevent and minimize fire or explosion risk
from static accumulation and discharge, effectively bond and/or
ground product transfer system. Do not use electronic devices
(including but not limited to cellular phones, computers,
calculators, pagers, etc.) in or around any fueling operation or
storage area unless the devices are certified intrinsically safe
by an approved national testing agency and to the safety
standards required by national and/or local laws and regulations.
Electrical equipment and fittings must comply with local fire
prevention regulations for this class of product. Use the
correct grounding procedures. Refer to national or local
regulations covering safety at petroleum handling and storage
areas for this product.
EMPTY CONTAINER WARNING: Empty containers retain residue (liquid
and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION;
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to
refill or clean container since residue is difficult to remove.
Empty drums should be completely drained, properly bunged and
promptly returned to a drum reconditioner. All containers should
be disposed of in an environmentally safe manner and in
accordance with governmental regulations.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
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OCCUPATIONAL EXPOSURE LIMITS:
ExxonMobil recommends an 8-hour time-weighted average (TWA) exposure of
300 mg/m3 (100 ppm vapor).
---TWA--- ----STEL--- NOTE
Substance Name (CAS-No.) Source ppm mg/m3 ppm mg/m3
------ --- ----- --- ----- ----
GASOLINE (8006-61-9)
OSHA 300 900 500 1500
ACGIH 300 890 500 1480
XOM 100 300
METHYL-TERT-BUTYL ETHER
(1634-04-4)
ACGIH 40 144
XOM 25 75
ETHANOL (64-17-5)
OSHA 1000 1900
ACGIH 1000 1880
XYLENE (1330-20-7)
O, M, P, -Isomers OSHA 100 435 150 655
O, M, P, -Isomers ACGIH 100 434 150 651
ISOPENTANE (78-78-4)
All Isomers ACGIH 600 1770
TRIMETHYL BENZENE
(25551-13-7)
OSHA 25 125
ACGIH 25 123
TOLUENE (108-88-3)
OSHA 100 375 150 560
Skin ACGIH 50 188
XOM 200
BUTANE (106-97-8)
OSHA 800 1900
ACGIH 800 1900
XOM 1000 1500
2-METHYLPENTANE (107-83-5)
Isomer of N-Hexane ACGIH 500 1760 1000 3500
PENTANE (109-66-0)
OSHA 600 1800 750 2250
All Isomers ACGIH 600 1770
3-METHYLPENTANE (96-14-0)
Isomer of N-Hexane ACGIH 500 1760 1000 3500
BENZENE (71-43-2)
OSHA 1 5
Skin ACGIH 0.5 1.6 2.5 8
2,3-DIMETHYLBUTANE
(79-29-8)
Isomer of N-Hexane ACGIH 500 1760 1000 3500
N-HEXANE (110-54-3)
OSHA 50 180
Other Isomers OSHA 500 1800 1000 3600
N-Hexane Skin ACGIH 50 176
Other Isomers ACGIH 500 1760 1000 3500
ETHYL BENZENE (100-41-4)
OSHA 100 435 125 545
ACGIH 100 434 125 543
METHYLCYCLOHEXANE
(108-87-2)
OSHA 400 1600
ACGIH 400 1610
NOTE: Limits shown for guidance only. Follow applicable regulations.
VENTILATION: Ventilation equipment must be explosion proof.
RESPIRATORY PROTECTION: Approved respiratory equipment must be used
when airborne concentrations are unknown or exceed the
recommended exposure limit. Self-contained breathing apparatus
may be required for use in confined or enclosed spaces.
EYE PROTECTION: If splash with liquid is possible, chemical type
goggles should be worn.
SKIN PROTECTION: Impervious gloves should be worn. Good personal
hygiene practices should always be followed.
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9. PHYSICAL AND CHEMICAL PROPERTIES
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Typical physical properties are given below. Consult Product Data Sheet
for specific details.
APPEARANCE: Liquid
COLOR: Clear (May Be Dyed)
ODOR: Gasoline
ODOR THRESHOLD-ppm: NE
pH: NA
BOILING POINT C(F): > 35(95)
MELTING POINT C(F): NA
FLASH POINT C(F): < -40(-40) (ASTM D-56)
FLAMMABILITY (solids): NE
AUTO FLAMMABILITY C(F): NE
EXPLOSIVE PROPERTIES: NA
OXIDIZING PROPERTIES: NA
VAPOR PRESSURE-mmHg 20 C: > 200.0
VAPOR DENSITY: 3.0
EVAPORATION RATE: NE
RELATIVE DENSITY, 15/4 C: 0.79
SOLUBILITY IN WATER: Negligible
PARTITION COEFFICIENT: > 1
VISCOSITY AT 40 C, cSt: < 1.0
VISCOSITY AT 100 C, cSt: NA
POUR POINT C(F): NA
FREEZING POINT C(F): NE
VOLATILE ORGANIC COMPOUND: NE
DMSO EXTRACT, IP-346 (WT.%): NA
NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES
FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE
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10. STABILITY AND REACTIVITY
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STABILITY (THERMAL, LIGHT, ETC.): Stable.
CONDITIONS TO AVOID: Heat, sparks, flame and build up of static
electricity.
INCOMPATIBILITY (MATERIALS TO AVOID): Halogens, strong acids,
alkalies, and oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at
ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
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11. TOXICOLOGICAL DATA
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---ACUTE TOXICOLOGY---
ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000
mg/kg). ---Based on testing of similar products and/or the
components.
DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than
2000 mg/kg). ---Based on testing of similar products and/or the
components.
INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater
than 5 mg/l). ---Based on testing of similar products and/or the
components.
EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score:
greater than 6 but 15 or less). ---Based on testing of similar
products and/or the components.
SKIN IRRITATION (RABBITS): Irritant. (Primary Irritation Index: 3
or greater but less than 5). ---Based on testing of similar
products and/or the components.
OTHER ACUTE TOXICITY DATA: Inhalation of high concentrations of vapors
or aerosols/mists, especially deliberate or abuse exposure, may
cause respiratory system irritation and damage. These exposures
may also result in central nervous system depression and damage,
possibly leading to death. Prolonged skin contact with gasoline
may cause severe skin irritation similar to a chemical burn. The
above effects, which may result from the whole gasoline or some
of the gasoline components, are well documented in the medical
literature. HAZARDS OF COMBUSTION PRODUCTS: Exposure to high
concentrations of carbon monoxide can cause loss of
consciousness, heart damage, brain damage and death.
---SUBCHRONIC TOXICOLOGY (SUMMARY)---
Two dermal studies resulted in significant irritation in rabbits but
no significant systemic toxicity. 90-day inhalation exposures
(approximately 1500 ppm vapor) in rats and monkeys produced light
hydrocarbon nephropathy in male rats, but no other significant
systemic toxicity.
---NEUROTOXICOLOGY (SUMMARY)---
Exposure to high concentrations of unleaded gasoline in rodents caused
reversible central nervous system depression, however, no
persistent neurotoxic effects were observed in subchronic
inhalation studies of gasoline blending streams. No neurotoxic
effects, as measured by a functional observation battery, motor
activity, and neuropathology, were observed in rats exposed to
light alkylate naphtha for 13 weeks at concentrations up to 6600
ppm. The medical literature clearly documents neurotoxic effects
in humans from abusive gasoline inhalation (sniffing).
---REPRODUCTIVE TOXICOLOGY (SUMMARY)---
Two separate inhalation teratology studies of unleaded gasoline vapor
at exposures up to 1600 ppm and 9000 ppm for 6 hours/day on days
6-20 did not result in any significant developmental effects in
rats. No significant effects were observed in the mothers or
offspring. A two-generation inhalation reproductive study
(CONCAWE) of unleaded gasoline showed no reproductive or
developmental effects in rats exposed to concentrations up to 20,
000 mg/m3 (approx. 8000 ppm).
---CHRONIC TOXICOLOGY (SUMMARY)---
A lifetime mouse skin painting study of unleaded gasoline applied at
50 microliters, three times weekly, resulted in some severe skin
irritation and changes, but no statistically significant increase
in skin cancer or cancer to any other organ. A lifetime
inhalation study of vaporized unleaded gasoline at up to 2000 ppm
caused liver tumors in female mice and increased kidney tumors in
male rats. The kidney tumors resulted from the formation of a
compound unique to male rats, and are not considered relevant to
humans. The U.S. EPA Risk Assessment Forum concluded that the
male rat kidney tumor results are not relevant for human risk
assessment. The implications for the female mice liver tumor
data for human risk assessment have not been fully determined.
Multiple short-term cancer predicative tests (Ames Test, etc.)
have routinely been negative (no cancer or mutagenic potential)
for unleaded gasoline.
---SENSITIZATION (SUMMARY)---
Unleaded gasoline was not a skin sensitizer in tests in a Buehler
Guinea Pig Sensitization Assay.
---OTHER TOXICOLOGY DATA---
Gasoline and Refinery Streams: Isolated constituents of gasoline may
display these or other potential hazards in laboratory tests.
Gasoline consists of a complex blend of petroleum/processing
derived paraffinic, olefinic, naphthenic and aromatic
hydrocarbons which include up to 5% benzene (with 1-2 % typical
in the U.S.), n-hexane, mixed xylenes, toluene, ethylbenzene and
trimethyl benzene. Benzene has also caused damage to the fetus
of test animals in developmental studies. Benzene has tested
positive (mutagenic) in a number of short-term cancer/mutation
predicative tests. Repeated exposures to low levels of benzene
(50-500 ppm) have been reported to result in blood abnormalities
including anemia and, in rare cases, leukemia in both animals and
humans. Prolonged exposure to n-hexane may result in a condition
known as peripheral neuropathy. This is nervous system damage
and is characterized by numbness of the extremities and, in
extreme cases, paralysis. This product contains ethylbenzene.
The International Agency for Research on Cancer (IARC) has
evaluated ethylbenzene and classified it as possibly carcinogenic
to humans (Group 2B) based on sufficient evidence for
carcinogenicity in experimental animals, but inadequate evidence
for cancer in exposed humans. Methyl Tertiary Butyl Ether (MTBE)
was tested for carcinogenicity, neurotoxicity, chronic,
reproductive, and developmental toxicity. The NOAEL for all end
points evaluated in three animal species was 400 ppm or greater.
An increase in kidney tumors/damage and liver tumors was observed
in animals exposed to high concentrations of MTBE. Some
embryo/fetal toxicity and birth defects were observed in the
offspring of pregnant mice exposed to maternally toxic doses of
MTBE, however the offspring of exposed pregnant rabbits were
unaffected. The significance of the animal findings at high
exposures are not believed to be directly related to potential
human health hazards in the workplace.
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12. ECOLOGICAL INFORMATION
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ENVIRONMENTAL FATE AND EFFECTS:
In the absence of specific environmental data for this product, this
assessment is based on information for representative substances.
ECOTOXICITY: Based on test results for similar products, this
substance may be toxic to aquatic organisms such as algae and
daphnia (EL50/ IrL50 =1-10 mg/L). This substance has also been
shown to be toxic to fish (LL50 = 1-10 mg/L).
MOBILITY: Dissolution of the higher molecular weight hydrocarbon
components in water will be limited, but losses through sediment
adsorption may be significant.
PERSISTENCE AND DEGRADABILITY: The majority of the components in this
product would be expected to be inherently biodegradable. When
released into the environment, some of the constituents of
gasoline will volatilize and be photodegraded in the atmosphere.
The less volatile, more water-soluble components which are
aromatic hydrocarbons will also undergo aqueous photodegradation.
BIOACCUMULATIVE POTENTIAL: Not established.
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13. DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL: Product is suitable for burning for fuel value in
compliance with applicable laws and regulations and consideration
of product characteristics at time of disposal.
RCRA INFORMATION: Disposal of unused product may be subject to RCRA
regulations (40 CFR 261). Disposal of the used product may also
be regulated due to ignitability, corrosivity, reactivity, or
toxicity as determined by the Toxicity Characteristic Leaching
Procedure (TCLP).
BENZENE: 2.3200 PCT (TCLP)
FLASH: < -40(-40) C(F)
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14. TRANSPORT INFORMATION
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USA DOT:
SHIPPING NAME: Gasoline
HAZARD CLASS & DIV: 3
ID NUMBER: UN1203
ERG NUMBER: 128
PACKING GROUP: PG II
STCC: NE
DANGEROUS WHEN WET: No
POISON: No
LABEL(s): Flammable Liquid
PLACARD(s): Flammable
PRODUCT RQ: NA
MARPOL III STATUS: NA
RID/ADR:
HAZARD CLASS: 3
PACKING GROUP: II
LABEL: 3
DANGER NUMBER: 33
UN NUMBER: 1203
SHIPPING NAME: Motor Spirit
REMARKS: NA
IMO:
HAZARD CLASS & DIV: 3
UN NUMBER: 1203
PACKING GROUP: PG II
SHIPPING NAME: Gasoline
LABEL(s): Flammable Liquid
MARPOL III STATUS: NA
ICAO/IATA:
HAZARD CLASS & DIV: 3
ID/UN Number: 1203
PACKING GROUP: PG II
SHIPPING NAME: Gasoline
SUBSIDIARY RISK: NA
LABEL(s): Flammable Liquid
STATIC ACCUMULATOR (50 picosiemens or less): YES
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15. REGULATORY INFORMATION
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US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance
with OSHA 29 CFR 1910.1200 and determined to be hazardous.
EU Labeling: Product is dangerous as defined by the European Union
Dangerous Substances/Preparations Directives.
Symbol: F+ T N Extremely flammable, Toxic, Dangerous for
the environment.
Risk Phrase(s): R12-45-38-65-67-51/53.
Extremely flammable. May cause cancer. Irritating to skin.
Harmful: may cause lung damage if swallowed. Vapors may cause
drowsiness and dizziness. Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrase(s): S16-53-45-2-23-24-29-43-62.
Keep away from sources of ignition - No smoking. Avoid exposure -
obtain special instructions before use. In case of accident or if
you feel unwell, seek medical advice immediately (show the label
where possible). Keep out of the reach of children. Do not breathe
vapor. Avoid contact with skin. Do not empty into drains. In case
of fire use foam/drypowder/CO2. If swallowed, do not induce
vomiting: seek medical advice immediately and show this container
or label.
Contains: Low Boiling Point Naphtha.
Governmental Inventory Status: All components comply with TSCA, and
EINECS/ELINCS.
U.S. Superfund Amendments and Reauthorization Act (SARA) Title III:
This product contains no "EXTREMELY HAZARDOUS SUBSTANCES".
SARA (311/312) REPORTABLE HAZARD CATEGORIES:
FIRE CHRONIC ACUTE
This product contains the following SARA (313) Toxic Release
Chemicals:
CHEMICAL NAME CAS NUMBER CONC.
--------------------------- -------------- -------
BENZENE(COMPONENT ANALYSIS) 71-43-2 2.3%
PSEUDOCUMENE (1,2, 95-63-6 4.6%
4-TRIMETHYLBENZENE)(COMPONENT
ANALYSIS)
ETHYL BENZENE(COMPONENT 100-41-4 1.6%
ANALYSIS)
TOLUENE(COMPONENT ANALYSIS) 108-88-3 4.7%
N-HEXANE(COMPONENT ANALYSIS) 110-54-3 1.7%
XYLENES(COMPONENT ANALYSIS) 1330-20-7 9.9%
METHYL-TERT-BUTYL 1634-04-4 15.1%
ETHER(COMPONENT ANALYSIS)
The following product ingredients are cited on the lists below:
CHEMICAL NAME CAS NUMBER LIST CITATIONS *
------------- ---------- --------------
ETHYL ALCOHOL (COMPONENT ANALYSIS) 64-17-5 1, 6, 10, 18, 19,
20, 21, 23, 25, 26
BENZENE (COMPONENT ANALYSIS) 71-43-2 1, 2, 4, 6, 9, 10,
(2.32%) 16, 17, 18, 19, 20,
21, 22, 23, 24, 25,
26
ISOPENTANE (COMPONENT ANALYSIS) 78-78-4 1, 19, 24, 25
2,3-DIMETHYLBUTANE (COMPONENT 79-29-8 1, 19, 25
ANALYSIS)
PSEUDOCUMENE (1,2, 95-63-6 1, 20, 24, 25
4-TRIMETHYLBENZENE) (COMPONENT
ANALYSIS)
PENTANE, 3-METHYL- (COMPONENT 96-14-0 1, 19, 25
ANALYSIS)
METHYL CYCLOPENTANE (COMPONENT 96-37-7 19, 25, 26
ANALYSIS)
ETHYL BENZENE (COMPONENT ANALYSIS) 100-41-4 1, 8, 10, 18, 19,
20, 21, 23, 24, 25,
26
BUTANE (COMPONENT ANALYSIS) 106-97-8 1, 10, 18, 19, 20,
21, 23, 24, 25, 26
PENTANE, 2-METHYL- (COMPONENT 107-83-5 1, 19, 23, 25
ANALYSIS)
METHYLCYCLOHEXANE (COMPONENT 108-87-2 1, 10, 18, 19, 20,
ANALYSIS) 21, 23, 25, 26
TOLUENE (COMPONENT ANALYSIS) 108-88-3 1, 10, 17, 18, 19,
(4.65%) 20, 21, 22, 23, 24,
25, 26
PENTANE (COMPONENT ANALYSIS) 109-66-0 1, 10, 18, 19, 20,
21, 23, 24, 25, 26
N-HEXANE (COMPONENT ANALYSIS) 110-54-3 1, 10, 18, 19, 20,
21, 23, 24, 25, 26
2-METHYL 2-BUTENE (COMPONENT 513-35-9 19, 25
ANALYSIS)
3-METHYLHEXANE (COMPONENT ANALYSIS) 589-34-4 19, 25
HEXANE, 2-METHYL- (COMPONENT 591-76-4 19, 25
ANALYSIS)
1-HEXENE (COMPONENT ANALYSIS) 592-41-6 1, 19, 25
XYLENES (COMPONENT ANALYSIS) 1330-20-7 1, 10, 18, 19, 20,
(9.90%) 21, 22, 23, 24, 25,
26
METHYL-TERT-BUTYL ETHER (COMPONENT 1634-04-4 1, 21, 24, 25
ANALYSIS)
GASOLINE 8006-61-9 1, 8, 10, 18, 19,
20, 21, 23, 26
TRIMETHYL BENZENE (COMPONENT 25551-13-7 1, 10, 18, 19, 20,
ANALYSIS) 21, 23, 25, 26
--- REGULATORY LISTS SEARCHED ---
1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK
2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293
3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK
4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK
5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK
26=RI RTK
* EPA recently added new chemical substances to its TSCA Section 4 test rules.
Please contact the supplier to confirm whether the ingredients in this product
currently appear on a TSCA 4 or TSCA 12b list.
Code key:CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive
--------------------------------------------------------------------------
16. OTHER INFORMATION
--------------------------------------------------------------------------
USE: UNLEADED MOTOR FUEL
NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES
ARE NOT FORMULATED TO CONTAIN PCBS.
Health studies have shown that many hydrocarbons pose potential human
health risks which may vary from person to person. Information provided
on this MSDS reflects intended use. This product should not be used for
other applications. In any case, the following advice should be
considered:
INJECTION INJURY WARNING: If product is injected into or under the skin,
or into any part of the body, regardless of the appearance of the wound
or its size, the individual should be evaluated immediately by a
physician as a surgical emergency. Even though initial symptoms from
high pressure injection may be minimal or absent, early surgical
treatment within the first few hours may significantly reduce the
ultimate extent of injury.
Precautionary Label Text:
CONTAINS GASOLINE
DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE.
CAUSES SKIN IRRITATION. RESPIRATORY IRRITATION, HEADACHE, DIZZINESS,
NAUSEA, LOSS OF CONSCIOUSNESS, AND IN CASES OF EXTREME EXPOSURE, POSSIBLY
DEATH. LOW VISCOSITY MATERIAL-IF SWALLOWED, MAY BE ASPIRATED AND CAN
CAUSE SERIOUS OR FATAL LUNG DAMAGE.
OVEREXPOSURE TO BENZENE MAY RESULT IN CANCER, BLOOD DISORDERS, AND DAMAGE
TO THE BONE MARROW. LONG-TERM EXPOSURE TO GASOLINE VAPOR HAS CAUSED
KIDNEY AND LIVER CANCER IN LABORATORY ANIMIALS, BLOOD EFFECTS, AND
NERVOUS SYSTEM DAMAGE.
Keep away from heat, sparks, and flame. Avoid all personal contact.
Avoid prolonged breathing of vapor. Use with adequate ventilation. Keep
container closed. Approved portable containers must be properly grounded
when transferring fuel. For use as a motor fuel only. Misuse of
gasoline may cause serious injury or illness. Never siphon by mouth.
Not to be used as a solvent or skin cleaning agent.
FIRST AID: In case of contact, wash skin with soap and water.
Immediately remove contaminated clothing, including shoes. Destroy or
wash clothing before reuse. If swallowed, seek immediate medical
attention. Do not induce vomiting. Only induce vomiting at the
instruction of a physician.
This warning is given to comply with California Health and Safety Code
25249.6 and does not constitute an admission or a waiver of rights. This
product contains a chemical known to the State of California to cause
cancer, birth defects, or other reproductive harm. Chemicals known to
the State of California to cause cancer, birth defects, or other
reproductive harm are created by the combustion of this product. Refer
to product Material Safety Data Sheet for further safety and health
information.
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*************************************************************************
For Internal Use Only: MHC: 1* 1* 1* 1* 2*, MPPEC: CF, TRN: 33126-00,
CMCS97: 97C112, REQ: US - MARKETING, SAFE USE: G
EHS Approval Date: 18FEB2003
*************************************************************************
Information given herein is offered in good faith as accurate, but
without guarantee. Conditions of use and suitability of the product for
particular uses are beyond our control; all risks of use of the product
are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL
WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE
USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a
recommendation for uses which infringe valid patents or as extending
license under valid patents. Appropriate warnings and safe handling
procedures should be provided to handlers and users. Alteration of this
document is strictly prohibited. Except to the extent required by law,
republication or retransmission of this document, in whole or in part, is
not permitted. Exxon Mobil Corporation and its affiliated companies
assume no responsibility for accuracy of information unless the document
is the most current available from an official ExxonMobil distribution
system. Exxon Mobil Corporation and its affiliated companies neither
represent nor warrant that the format, content or product formulas
contained in this document comply with the laws of any other country
except the United States of America.
Prepared by: ExxonMobil Oil Corporation
Environmental Health and Safety Department, Clinton, USA
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