ChemWatch MSDS MSDS for HOUSE OF KOLOR SHIMRIN BASES - MB 01, 02, 03, 04, 05, 06
HOUSE OF KOLOR SHIMRIN BASES - MB 01, 02, 03, 04, 05,
06
ChemWatch Material Safety Data Sheet
CHEMWATCH 5090-24
Date of Issue: Tue 12-Aug-2003
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
Company:
Meguiar's Australia P/L
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUS
Telephone: (+61 2) 9737 9422
Telephone: 1800 804 182
Fax: (+61 2) 9737 9414
SYNONYMS
tinting tintable base universal paint coating automotive finish
SHIPPING NAME
PAINT None
Product Name: House of Kolor Shimrin Bases - MB 01, 02, 03, 04, 05, 06
Other Names: Product Codes: MB01, MB02, MB03, MB04
MB05, MB06
CAS RN No(s): None None
UN Number: 1263
Packing Group: II
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Dangerous Goods Class: 3
Subsidiary Risk: None, None
Hazchem Code: 3[Y]E
Poisons Schedule Number: None
USE
Used according to manufacturers directions.
The use of a quantity of material in an unventilated or confined space may
result in increased exposure and an irritating atmosphere developing
Before starting consider control of exposure by mechanical ventilation
For further information refer to the House of Kolor Technical Manual
PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
White to off-white highly flammable liquid with a stroong solvent odour; does not mix with water.
Boiling Point (掳C): 78-143
Melting Point (掳C): Not Available
Vapour Pressure (kPa): Not Available
Specific Gravity: 0.85-0.86
Flash Point (掳C): -5
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Solubility in Water (g/L): Immiscible
INGREDIENTS
NAME CAS RN %
solvent naphtha petroleum, medium aliphatic 64742-88-7 NotSpec
xylene 1330-20-7 5-15
n-butyl acetate 123-86-4 NotSpec
acrylic resin Various 1-9
cellulose acetate butyrate 9004-36-8 1-9
methyl ethyl ketone 78-93-3 1-9
solvent naphtha petroleum, heavy aromatic 64742-94-5 1-5
mica 12001-26-2 1-9
titanium dioxide 13463-67-7 1-9
stannous oxide 21651-19-4 1-9
ethyl-3-ethoxypropionate 763-69-9 NotSpec
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HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
The material is not thought to produce adverse health effects following
ingestion (as classified by EC Directives using animal models). Nevertheless,
adverse systemic effects have been produced following exposure of animals by at
least one other route and good hygiene practice requires that exposure be kept
to a minimum.
EYE
Although the liquid is not thought to be an irritant (as classified by EC
Directives), direct contact with the eye may produce transient discomfort
characterised by tearing or conjunctival redness (as with windburn).
SKIN
Skin contact with the material may be harmful; systemic effects may result
following absorption.
The liquid may be miscible with fats or oils and may degrease the skin,
producing a skin reaction described as non-allergic contact dermatitis. The
material is unlikely to produce an irritant dermatitis as described in EC
Directives .
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
Inhalation of aerosols (mists, fumes), generated by the material during the
course of normal handling, may be harmful.
The material is not thought to produce respiratory irritation (as classified by
EC Directives using animal models). Nevertheless inhalation of vapours, fumes or
aerosols, especially for prolonged periods, may produce respiratory discomfort
and occasionally, distress.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead
to narcosis, unconsciousness, even coma and possible death.
Xylene is a central nervous system depressant. Central nervous system (CNS)
depression may include nonspecific discomfort, symptoms of giddiness, headache,
dizziness, nausea, anaesthetic effects, slowed reaction time, slurred speech and
may progress to unconsciousness. Serious poisonings may result in respiratory
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depression and may be fatal.
Headache, fatigue, lassitude, irritability and gastrointestinal disturbances
(e.g., nausea, anorexia and flatulence) are the most common symptoms of xylene
overexposure. Injury to the heart, liver, kidneys and nervous system has also
been noted amongst workers. Transient memory loss, renal impairment, temporary
confusion and some evidence of disturbance of liver function was reported in
three workers overcome by gross exposure to xylene (10000 ppm). One worker died
and autopsy revealed pulmonary congestion, oedema and focal alveolar
haemorrhage. Volunteers inhaling xylene at 100 ppm for 5 to 6 hours showed
changes in manual coordination reaction time and slight ataxia. Tolerance
developed during the workweek but was lost over the weekend. Physical exercise
may antagonise this effect. Xylene body burden in humans exposed to 100 or 200
ppm xylene in air depends on the amount of body fat with 4% to 8% of total
absorbed xylene accumulating in adipose tissue.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure.
On the basis, primarily, of animal experiments, concern has been expressed that
the material may produce carcinogenic or mutagenic effects; in respect of the
available information, however, there presently exists inadequate data for
making a satisfactory assessment.
There is some evidence that human exposure to the material may result in
developmental toxicity. This evidence is based on animal studies where effects
have been observed in the absence of marked maternal toxicity, or at around the
same dose levels as other toxic effects but which are not secondary non-specific
consequences of the other toxic effects.
Exposure to the material for prolonged periods may cause physical defects in the
developing embryo (teratogenesis).
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
Repeated or prolonged exposure to mixed hydrocarbons may produce narcosis with
dizziness, weakness, irritability, concentration and/or memory loss, tremor in
the fingers and tongue, vertigo, olfactory disorders, constriction of visual
field, paraesthesias of the extremities, weight loss and anaemia and
degenerative changes in the liver and kidney. Chronic exposure by petroleum
workers, to the lighter hydrocarbons, has been associated with visual
disturbances, damage to the central nervous system, peripheral neuropathies
(including numbness and paraesthesias), psychological and neurophysiological
deficits, bone marrow toxicities (including hypoplasia possibly due to benzene)
and hepatic and renal involvement. Chronic dermal exposure to petroleum
hydrocarbons may result in defatting which produces localised dermatoses.
Surface cracking and erosion may also increase susceptibility to infection by
microorganisms. One epidemiological study of petroleum refinery workers has
reported elevations in standard mortality ratios for skin cancer along with a
dose-response relationship indicating an association between routine workplace
exposure to petroleum or one of its constituents and skin cancer, particularly
melanoma. Other studies have been unable to confirm this finding.
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FIRST AID
SWALLOWED
路 Immediately give a glass of water.
路 First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
路 Transport to hospital, or doctor.
ADVICE TO DOCTOR
Treat symptomatically.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or
inhalation, is respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g.
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cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.
Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm
Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported;
intravenous lines and cardiac monitors should be established in obviously
symptomatic patients. The lungs excrete inhaled solvents, so that
hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm
because of potential myocardial sensitisation to catecholamines. Inhaled
cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred
agents, with aminophylline a second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of
cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical
Toxicology]
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
No data for House of Kolor Shimrin Bases - MB 01, 02, 03, 04, 05, 06.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m鲁): 401.8136 mg/m鲁
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁
Mixture Conc: (%)
xylene 47.51 207.8346 15
methyl ethyl ketone 42.03 124.7008 9
solvent naphtha petroleum, heavy a 12.6 69.2782 5
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m鲁): 29 mg/m鲁
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture
Conc (%)
acrylic resin 124.7008 9 0
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cellulose acetate butyrate 124.7008 9 0
mica 124.7008 9 0
titanium dioxide 124.7008 9 0
stannous oxide 124.7008 9 0
INGREDIENT DATA
SOLVENT NAPHTHA PETROLEUM, MEDIUM ALIPHATIC:
TLV TWA: 300 ppm A3 [ACGIH]
CEL TWA: 100 ppm, 525 mg/m鲁 [Manufacturer]
as VM & P Naphtha (petroleum ether) (CAS RN: 8032-32-4)
TLV TWA: 300 ppm, A3
Naphthas of this type produce central nervous system depression and are mild
irritants of the eyes and upper respiratory tract. The carcinogenic potential of
middle petroleum distillates is recognised and is related to the content of
polynuclear aromatic hydrocarbons
(PAHs). The TLV is thought to be protective against the acute effects of upper
respiratory tract and eye irritation and chronic systemic effects.
CAUTION: This substance has been classified by the ACGIH as A3
Animal carcinogen (at relatively high doses).
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m鲁 (compare OSHA TWA)
XYLENE:
TLV TWA: 100 ppm A4;BEI [ACGIH]
TLV STEL: 150 ppm A4;BEI [ACGIH]
PEL TWA: 100 ppm, 435 mg/m鲁 [OSHA Z1]
TLV TWA: 100 ppm, 434 mg/m鲁; STEL: 150 ppm, 651 mg/m鲁 A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
ES TWA: 80 ppm, 350 mg/m鲁; STEL: 150 ppm, 655 mg/m鲁 (Under review)
OES TWA: 100 ppm, 441 mg/m鲁; STEL: 150 ppm, 662 mg/m鲁 skin
Exposure limits with "skin" notation indicate that vapour and liquid may be
absorbed through intact skin. Absorption by skin may readily exceed vapour
inhalation exposure. Symptoms for skin absorption are the same as for
inhalation. Contact with eyes and mucous membranes may also contribute to
overall exposure and may also invalidate the exposure standard.
IDLH Level: 900 ppm
Odour Threshold Value: 20 ppm (detection), 40 ppm (recognition)
NOTE: Detector tubes for o-xylene, measuring in excess of 10 ppm, are
available commercially. (m-xylene and p-xylene give almost the same
response)
Xylene vapour is an irritant to the eyes, mucous membranes and skin and
causes narcosis at high concentrations. Exposure to doses sufficiently high
to produce intoxication and unconsciousness also produces transient liver
and kidney toxicity. Neurologic impairment is NOT evident amongst
volunteers inhaling up to 400 ppm though complaints of ocular and upper
respiratory tract irritation occur at 200 ppm for 3 to 5 minutes.
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Exposure to xylene at or below the recommended TLV-TWA and STEL is thought
to minimise the risk of irritant effects and to produce neither significant
narcosis or chronic injury. An earlier skin notation was deleted because
percutaneous absorption is gradual and protracted and does not
substantially contribute to the dose received by inhalation.
N-BUTYL ACETATE:
TLV TWA: 150 ppm [ACGIH]
TLV STEL: 200 ppm [ACGIH]
PEL TWA: 150 ppm, 710 mg/m鲁 [OSHA Z1]
TLV TWA: 150 ppm, 713 mg/m鲁; STEL: 200 ppm, 950 mg/m鲁
ES TWA: 150 ppm, 713 mg/m鲁; STEL: 200 ppm, 950 mg/m鲁
OES TWA: 150 ppm, 724 mg/m鲁; STEL: 200 ppm, 966 mg/m鲁
MAK value: 100 ppm, 480 mg/m鲁
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
Odour Threshold Value: 0.0063 ppm (detection), 0.038-12 ppm (recognition)
IDLH Level: 1700 ppm (lower explosive limit)
Exposure at or below the recommended TLV-TWA is thought to prevent
significant irritation of the eyes and respiratory passages as well as
narcotic effects. In light of the lack of substantive evidence regarding
teratogenicity and a review of acute oral data a STEL is considered
inappropriate.
For each of the following
ACRYLIC RESIN:
CELLULOSE ACETATE BUTYRATE:
TLV TWA: 10 mg/m鲁 (Value for particulate matter containing no asbestos and <1%
crystalline
silica,Inhalable fraction) [ACGIH]
TLV TWA: 3 mg/m鲁 (Value for particulate matter containing no asbestos and <1%
crystalline
silica,Respirable fraction) [ACGIH]
No exposure limits set by NOHSC or ACGIH.
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁
METHYL ETHYL KETONE:
TLV TWA: 200 ppm BEI [ACGIH]
TLV STEL: 300 ppm BEI [ACGIH]
PEL TWA: 200 ppm, 590 mg/m鲁 [OSHA Z1]
TLV TWA: 200 ppm, 590 mg/m鲁; STEL: 300 ppm, 885 mg/m鲁
ES TWA: 150 ppm, 445 mg/m鲁; STEL: 300 ppm, 890 mg/m鲁
OES TWA: 200 ppm, 600 mg/m鲁; STEL: 300 ppm, 899 mg/m鲁 skin
MAK value: 200 ppm, 600 mg/m鲁
Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparably larger
danger of toxicity than their inhalation. To avoid health risks when handling
such substances, meticulous cleaning of the skin, hair and clothing is
imperative.
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MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
IDLH Level: 3000 ppm
Odour Threshold Value: Variously reported as 2 ppm and 4.8 ppm
Odour threshold: 2 ppm (detection); 5 ppm (recognition)
25 ppm (easy recognition); 300 ppm IRRITATING
Exposures at or below the recommended TLV-TWA are thought to prevent
injurious systemic effects and to minimise objections to odour and
irritation. Where synergism or potentiation may occur stringent control of
the primary toxin (e.g. n-hexane or methyl butyl ketone) is desirable and
additional consideration should be given to lowering MEK exposures.
SOLVENT NAPHTHA PETROLEUM, HEAVY AROMATIC:
REL TWA: 100 ppm [Manufacturer]
CEL TWA: 100 ppm, 550 mg/m鲁
MICA:
TLV TWA: 3 mg/m鲁 (Respirable fraction) [ACGIH]
PEL: (Mica) [OSHA Z3]20 mppcf
PEL: (Soapstone) [OSHA Z3]20 mppcf
vermiculite, containing no asbestos, as mica and <1% crystalline silica
TLV TWA: 3 mg/m鲁 respirable dust
The concentration of respirable dust for application of this limit is to
be determined from the fraction that penetrates a separator whose size
collection efficiency is described by a cumulative lognormal function with
a median aerodynamic volume of 4.0 碌m (+-) 0.3 碌m and with a geometric
standard deviation of 1.5 碌m (+-) 0.1 碌m, i.e.. less than 5 碌m.
ES TWA: 2.5 mg/kg inspirable dust (under review)
OES TWA: 10 mg/m鲁 total inhalable dust
OES TWA: 4 mg/m鲁 respirable dust
IDLH Level: 1500 mg/m鲁
The TLV-TWA is thought to be sufficiently low to prevent changes in pre-
employment chest X-ray findings in exposed employees, in some cases
following decades of exposure. The limit is thought to be protective
against disabling pneumoconiosis.
TITANIUM DIOXIDE:
TLV TWA: 10 mg/m鲁 A4 [ACGIH]
PEL Total dust: 15)mg/m鲁 [OSHA Z1]
TLV TWA: 10 mg/m鲁 A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
ES TWA: 10 mg/m鲁
(total dust containing no asbestos and < 1% crystalline silica)
OES TWA: 10 mg/m鲁 total inhalable dust
OES TWA: 4 mg/m鲁 respirable dust
IDLH Level: 5000 mg/m鲁
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Animal studies at 10 mg/m鲁 show no significant fibrosis, possibly reversible
tissue reaction and the architecture of lung air spaces remains intact.
STANNOUS OXIDE:
TLV TWA: 2 mg/m鲁 Oxide and inorganic compounds [ACGIH]
tin inorganic compounds, as Sn (A.Wt: 118.69)
ES TWA: 2 mg/m鲁
TLV TWA: 2 mg/m鲁
OES TWA: 2 mg/m鲁; STEL: 4 mg/m鲁
IDLH Level: 100 mg/m鲁 (as Sn)
A TLV-TWA is recommended so as to minimise the risk of stannosis. The STEL (4.0
mg/m鲁) has been eliminated (since 1986) so that additional toxicological data
and industrial hygiene experience may become available to provide a better base
for quantifying on a toxicological basis what the STEL should in fact be.
ETHYL-3-ETHOXYPROPIONATE:
No exposure limits set by NOHSC or ACGIH
CEL TWA: 50 ppm, 300mg/m鲁 [Eastman]
ENGINEERING CONTROLS
For flammable liquids and flammable gases, local exhaust ventilation or a
process enclosure ventilation system may be required. Ventilation equipment
should be explosion-resistant.
Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min.)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
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2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood-local control only
motion
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
PERSONAL PROTECTION
EYE
Safety glasses with side shields
Chemical goggles.
Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber
OTHER
Overalls.
PVC Apron.
PVC protective suit may be required if exposure severe.
Eyewash unit.
Ensure there is ready access to a safety shower.
RESPIRATOR
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Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor (Min) Half-Face Respirator Full-Face Respirator
5 x ES A-AUS -
A-PAPR-AUS
25 x ES Air-line* A-2
A-PAPR-2
50 x ES - A-3
50+ x ES - Air-line**
* - Continuous-flow; ** - Continuous-flow or positive pressure demand
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Packing as supplied by manufacturer. Plastic containers may only be used if
approved for flammable liquid. Check that containers are clearly labelled and
free from leaks.
路 For low viscosity materials (i) : Drums and jerry cans must be of the
non-removable head type. (ii) : Where a can is to be used as an inner package,
the can must have a screwed enclosure.
路 For materials with a viscosity of at least 2680 cSt. (23 deg. C)
路 For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
路 Manufactured product that requires stirring before use and having a viscosity
of at least 20 cSt (25 deg. C)
(i) : Removable head packaging;
(ii) : Cans with friction closures and
(iii) : low pressure tubes and cartridges may be used.
路 Where combination packages are used, and the inner packages are of glass,
there must be sufficient inert cushioning material in contact with inner and
outer packages
路 In addition, where inner packagings are glass and contain liquids of packing
group I there must be sufficient inert absorbent to absorb any spillage, unless
the outer packaging is a close fitting moulded plastic box and the substances
are not incompatible with the plastic.
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STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents
STORAGE REQUIREMENTS
路 Store in original containers in approved flame-proof area.
路 No smoking, naked lights, heat or ignition sources.
路 DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
路 Keep containers securely sealed.
路 Store away from incompatible materials in a cool, dry well ventilated area.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
TRANSPORTATION
Class 3 - Flammable liquids shall not be loaded in the same vehicle or packed in
the same vehicle or packed in the same freight container with:
Class 1 - Explosives;
Class 2.1 - Flammable gases (where both flammable liquids and flammable gases
are in bulk);
Class 2.3 - Poisonous gases;
Class 4.2 - Spontaneously combustible substances;
Class 5.1 - Oxidising agents;
Class 5.2 - Organic peroxides;
Class 7 - Radioactive substances.
SPILLS AND DISPOSAL
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb small quantities with vermiculite or other absorbent
material.
路 Wipe up.
路 Collect residues in a flammable waste container.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
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ChemWatch MSDS MSDS for HOUSE OF KOLOR SHIMRIN BASES - MB 01, 02, 03, 04, 05, 06
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water
course.
路 Consider evacuation (or protect in place).
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse /absorb vapour.
路 Contain spill with sand, earth or vermiculite.
路 Use only spark-free shovels and explosion proof equipment.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
DISPOSAL
路 Recycle wherever possible.
路 Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility
can be identified.
路 Dispose of by: Burial in a licenced land-fill or Incineration in a licenced
apparatus (after admixture with suitable combustible material)
路 Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorised landfill.
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water
course.
路 Consider evacuation (or protect in place).
路 Fight fire from a safe distance, with adequate cover.
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ChemWatch MSDS MSDS for HOUSE OF KOLOR SHIMRIN BASES - MB 01, 02, 03, 04, 05, 06
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control the fire and cool adjacent
area.
路 Avoid spraying water onto liquid pools.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
路 Liquid and vapour are highly flammable.
路 Severe fire hazard when exposed to heat, flame and/or oxidisers.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition leading to violent rupture of
containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result
HAZCHEM
3[Y]E
CONTACT POINT
COMPANY CONTACT
(+61 2) 9737 9422
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEW ZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: 0800 764 766
NZ EMERGENCY SERVICES: 111
End of Report
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ChemWatch MSDS MSDS for HOUSE OF KOLOR SHIMRIN BASES - MB 01, 02, 03, 04, 05, 06
Issue Date: Tue 12-Aug-2003
Print Date: Mon 25-Aug-2003
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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