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MSDS Material Safety Data Sheet
CAS

8008-20-6

File Name: ilrc_ucf_edu---MSDS_00000107.asp
Philjet庐 A Aviation Fuel                                                                                               Page 1 of 7


MATERIAL SAFETY DATA SHEET

Philjet庐 A Aviation Fuel

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Synonyms: Aviation Turbine Fuel A; Kerosine Turbine Fuel; Kerosine; Jet Fuel A; Jet Fuel
Formula: Mixture
Chemical Family: Hydrocarbon
CAS Number: 8008-20-6
SAP Code: 1014060; 1014061
Product Code: 30393; 30493
MSDS Number: 001975
NFPA Ratings: Health 2, Flammability 2, Reactivity 0
HMIS Ratings: Health 2, Flammability 2, Reactivity 0
Intended Use(s): Aviation Turbine Fuel

The intended use of this product is indicated above, if any additional use is known
please contact us at the Technical Information number listed below.

Manufactured By: Phillips 66 Company
A Division of Phillips Petroleum Company
Bartlesville, Oklahoma 74004

Phone Numbers
Emergency: (918) 661-8118
Technical Information: (918) 661-5355
For Additional MSDSs: (800) 762-0942

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Specification Weight % In ACGIH TLV ACGIH ACGIH ACGIH Skin OSHA OSHA - OSHA -
(TWA) Short Term Ceiling Designation Final PEL Final Final PELs
and CAS # Product*
Exposure Limits (TWA) PELs - - Skin
Limit Ceiling Notation
Limits
100% NE NE NE NE NE NE
NE
Kerosene 8008 -20-6 may
include:
n-Octane < 1% 375 ppm; NE NE 500 ppm; NE NE
300 ppm;
111 -65 -9 1750 2350
1400 mg/m3 mg/m3 mg/m3
n-Nonane < 2% NE NE NE NE NE NE
200 ppm;
111 -84 -2
1050 mg/m3
Naphthenes < 60% NE NE NE NE NE NE
NE

Aromatic hydrocarbons < 30% NE NE NE NE NE NE
NE
includes:
m-Xylene < 1% 150 ppm; NE NE 100 ppm NE NE
100 ppm;
108 -38-3 651 mg/m3
434 mg/m3
1,2,4-Trimethylbenzene < 2% NE NE NE NE NE NE
25 ppm as
95 -63-6
Trimethylbenzene
1,2,3-Trimethylbenzene < 1% NE NE NE NE NE NE
25 ppm as
526 -73-8
Trimethylbenzene
Toluene < 0.5% NE NE skin - 200 ppm 300 ppm NE
50 ppm
108 -88-3 potential for
cutaneous
absorption
Philjet庐 A Aviation Fuel Page 2 of 7


Sulfur compound < 0.3% NE NE NE NE NE NE
NE


* 1% = 10,000 ppm.


3. HAZARDS IDENTIFICATION
Emergency Overview

Combustible liquid. Eye Irritant. Skin Irritant. Liver Toxin. Nervous System Toxin. Lung Aspiration Hazard.

Potential Acute Health Effects

Eye Contact: Eye Irritant. May cause severe irritation.

Skin Contact: Skin Irritant. May cause severe irritation. Minimize skin contact. This chemical is readily
absorbed through the skin in liquid or vapor phase.

Inhalation: Inhaled hydrocarbons cause central nervous system depression at high concentrations
resulting in headache, dizziness, and ultimately unconsciousness.

Ingestion: May be irritating to intestines causing nausea and vomiting. If swallowed, may be
aspirated resulting in inflammation and possible fluid accumulation in the lungs.

Aggravated Medical Skin Disorders.
Conditions:

4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with running water for at least 15 minutes. If irritation or adverse
symptoms develop, seek medical attention.

Skin Contact: Immediately wash skin with soap and water for at least 15 minutes. If irritation or adverse
symptoms develop, seek medical attention.

Inhalation: Remove from exposure. If breathing is difficult, give oxygen. If breathing ceases,
administer artificial respiration followed by oxygen. Seek immediate medical attention.

Ingestion: DO NOT induce vomiting. Seek immediate medical attention.

Notes To Physician: Gastric lavage using a cuffed endotracheal tube may be performed at your discretion.

5. FIRE FIGHTING MEASURES
Emergency Response Guidebook ID No. 1863, Guide No. 128

Flash Point: 100-150F (38-66C)
FP Method: TCC, ASTM D-56
Ignition Temperature: 460F (238C)

Flammable Limits (% by Volume in Air)
Lower Explosive Limit - 0.6
Upper Explosive Limit - 4.7

Fire Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam
Philjet庐 A Aviation Fuel Page 3 of 7



Fire Fighting Procedures: Evacuate area and fight fire from a safe distance. Shut off source, if possible. Use
NIOSH approved self-contained breathing apparatus and other protective
equipment and/or garments described in Section 8 if conditions warrant. Use water
spray to cool nearby containers and structures exposed to fire. Do not spray water
directly on fire - product will float and could be reignited on surface of water.

Fire and explosion hazards: Carbon oxides and various hydrocarbons forms when burned. Highly flammable
vapors which are heavier than air may accumulate in low areas and/or spread
along ground away from handling site.Flash back along vapor trail is possible.

6. ACCIDENTAL RELEASE MEASURES
Evacuate area of all unnecessary personnel. Wear protective equipment and/or garments described in Section 8
exposure conditions warrant. Shut off source, if possible and contain spill. Protect from ignition. Keep out of water
sources and sewers. Absorb in a dry, inert material (sand, clay, etc.). Transfer to disposal drums using non-
sparking equipment.

7. HANDLING AND STORAGE
DO NOT get in eyes, on skin, or on clothing. DO NOT breathe vapor, mist, fume or dust. DO NOT swallow. May
be aspirated into lungs. Wear protective equipment and/or garments described in Section 8 if exposure conditions
warrant. Wash thoroughly after handling. Immediately remove and launder contaminated clothing before reuse.
Use only with adequate ventilation.

Keep away from heat, sparks, and flame. Store in well-ventilated area. Store in closed container. Bond and
ground during transfer.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection: Use safety glasses with side shields.

Respiratory Protection: For concentrations exceeding an applicable exposure limit, use NIOSH approved
air purifying respirator equipped with:
- Organic vapor cartridges.

Air purifying respirators should NOT be used in:
- Situations that exceed the maximum use concentrations of the respirator or air-
purifying element established by regulatory standards.
- Atmospheres containing less than 19.5 percent oxygen.
- Atmospheres immediately dangerous to life or health (IDLH)

When entering or exiting from areas where the exposure concentration is unknown
or if conditions immediately dangerous to life or health (IDLH) exist, use a NIOSH
approved self-contained breathing apparatus (SCBA) or equivalent operated in a
pressure demand or other positive pressure mode.

Skin Protection: Use gloves resistant to the material being used (Viton, nitrile). This material is a
skin irritant. Use additional protective garments to prevent skin contact based on
use.

Ventilation: Use adequate ventilation to control concentrations below applicable exposure
limits.

Other Personal Protection: Personal protection information shown in Section 8 is based upon general
information as to normal uses and conditions. Where special or unusual uses or
conditions exist, it is suggested that the expert assistance of an industrial hygienist
Philjet庐 A Aviation Fuel Page 4 of 7

or other qualified professional be sought.

Exposure Limits: See Section 2 (Composition/Information on Ingredients).

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: Colorless
Odor: Mild
Odor Threshold (ppm): Unknown
Boiling Point: 300 -572F (149-300C)
Melting/Freeze Point: < -40C
Vapor Pressure: <1
Vapor Density (Air=1): Not Established
Specific Gravity @ 20 C (Water=1): 0.775 -0.840
Percent Volatile by Volume: 100
Evaporation Rate (Butyl Acetate=1): <1
Water Solubility: Negligible
Viscosity: 1.5 to 2.5 typical; 8 Max. cSt @ -4F (-20C)

10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will Not Occur
Incompatability (Materials to Avoid): Oxygen and strong oxidizing agents.
Hazardous Decomposition Products: Carbon oxides and various hydrocarbons are formed when burned.

11. TOXICOLOGICAL INFORMATION
Subchronic and Chronic Effects:

Jet Fuel A contains Benzene, a known human carcinogen. However, Jet Fuel A studies in Sweden and Canada
have resulted in contradictory reports. The Swedish Air Force reported no increased cancer risk during 10 years
of follow-up. A study in Canada reported an elevated risk of kidney cancer in men exposed to jet fuel.

No embryotoxic, fetotoxic or teratogenic effect was observed following exposure of rats by inhalation to 100 and
400 ppm Jet Fuel A.

Jet Fuel A applied to the skin of rabbits for 2 weeks caused skin corrosion and liver toxicity.

In a study of 30 workers exposed to jet fuel vapor (avg., 300 mg/m3; 17 years employed), a higher prevalence of
psychiatric symptoms, poorer performance in some psychological tests and reduced sensorimotor speed were
reported.

Other Health Effects:

Combustion (burning) of most carbon-containing material forms carbon monoxide. Carbon monoxide inhalation
may cause carboxyhemoglobinemia. Chronic exposure to carbon monoxide causes fatigue, poor memory, loss of
sensation in fingers, visual disturbances and insomnia. Carboxyhemoglobinemia is frequently misdiagnosed as
flu.

Sensitive sub-populations to the inhalation of carbon monoxide exist. Carbon monoxide displaces oxygen in the
bloodstream and therefore, can adversely effect people with pre-existing heart disease, pregnant women and
smokers.

Jet Fuel A did not interact with genetic material in a test tube assay (Ames bacterial test). However, it did cause
changes in genetic material in the bone marrow of male and female rats when they were exposed by inhalation
Philjet庐 A Aviation Fuel Page 5 of 7

20 days to 100 ppm or 5 days to 400 ppm.

Acute Data:

Jet Fuel A: Dermal LD50 > 5 ml/kg; LC50 = No data available; Oral LD50 > 25 ml/kg (Rat).

12. ECOLOGICAL INFORMATION
No data at this time.

13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION
Ground Transportation
DOT Shipping Description: Fuel, aviation, turbine engine, 3 or Combustible liquid*, UN1863, III
Non-Bulk Package Marking: Fuel, aviation, turbine engine, UN 1863
Bulk Package Placard/Marking: Flammable or Combustible / 1863
Hazardous Substance/RQ: Not Applicable
Packaging References: 49 CFR 173.150, 173.203, 173.241
Additional Remarks: *NOTE: This product may be reclassed as a combustible liquid when
shipped domestically by rail or highway. If reclassed as a combustible
liquid, this product is not regulated by DOT when shipped in non-bulk
quantities.

15. REGULATORY INFORMATION

Kerosene 100% 8008-20-6
Regulated Substance on TSCA Inventory: Listed
Pennsylvania Right to Know List: Listed
New Jersey Right-to-Know List: Listed
NJ Environmental Hazardous Substances List: Listed
Massachusetts Right To Know List: Listed
Florida Toxic Substances List: Listed
Canada - Domestic Substances List: Listed

n-Octane < 1% 111-65-9
Regulated Substance on TSCA Inventory: Listed
Pennsylvania Right to Know List: Listed
New Jersey Right-to-Know List: Listed
Massachusetts Right To Know List: Listed
Florida Toxic Substances List: Listed
Canada - Domestic Substances List: Listed

n-Nonane < 2% 111-84-2
Regulated Substance on TSCA Inventory: Listed
Pennsylvania Right to Know List: Listed
New Jersey Right-to-Know List: Listed
Massachusetts Right To Know List: Listed
Florida Toxic Substances List: Listed
Canada - Domestic Substances List: Listed

Naphthenes < 60%
Regulated Substance on TSCA Inventory: Listed
Philjet庐 A Aviation Fuel Page 6 of 7



Aromatic hydrocarbons < 30%
Regulated Substance on TSCA Inventory: Listed
Canada - Domestic Substances List: Listed

m-Xylene < 1% 108 -38-3
Section 313 of Title III of the SARA and 40 CFR Part 372: Listed
Regulated Substance on TSCA Inventory: Listed
Clean Water Act - Hazardous Substances: Listed
Pennsylvania Right to Know List: Listed
New Jersey Right-to-Know List: Listed
NJ Environmental Hazardous Substances List: Listed
Massachusetts Right To Know List: Listed
Florida Toxic Substances List: Listed
Canada - Domestic Substances List: Listed

1,2,4-Trimethylbenzene < 2% 95-63-6
Section 313 of Title III of the SARA and 40 CFR Part 372: Listed
Regulated Substance on TSCA Inventory: Listed
Pennsylvania Right to Know List: Listed
New Jersey Right-to-Know List: Listed
NJ Environmental Hazardous Substances List: Listed
Massachusetts Right To Know List: Listed
Canada - Domestic Substances List: Listed

1,2,3-Trimethylbenzene < 1% 526 -73-8
Regulated Substance on TSCA Inventory: Listed
Canada - Domestic Substances List: Listed

Sulfur compound < 0.3%
Regulated Substance on TSCA Inventory: Listed

Toluene < 0.5% 108 -88-3
Section 313 of Title III of the SARA and 40 CFR Part 372: Listed
Regulated Substance on TSCA Inventory: Listed
Clean Water Act - Toxic Pollutants: Listed
Clean Water Act - Hazardous Substances: Listed
Clean Water Act S307 Priority Pollutant: Listed
Pennsylvania Right to Know List: Listed
New Jersey Right-to-Know List: Listed
NJ Environmental Hazardous Substances List: Listed
Michigan Critical Materials List: Listed
Massachusetts Right To Know List: Listed
Florida Toxic Substances List: Listed
California - Prop. 65 - Developmental Toxicity: Listed
Canada - Domestic Substances List: Listed

EPA SARA 311/312 (Title III Hazard Categories)
Acute Health: Yes
Chronic Health: Yes
Fire Hazard: Yes
Pressure Hazard: No
Reactivity Hazard: No

WHMIS Hazard Class:

Class B - Flammable and Combustible Material. Class D, Division 2 Poisonous and Infectious Material: Other
toxic effects. Subdivision B.
Philjet庐 A Aviation Fuel Page 7 of 7




Additional Information:

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation and
the MSDS contains all of the information required by the Controlled Products Regulation.



16. OTHER INFORMATION

Revision Summary: Section(s): 3, 4, 15.

Preparer: Health, Environment and Safety Department
Date Prepared: 12/19/2001
Supersedes: 12/03/2001

Phillips Petroleum Company (references to Phillips Petroleum Company or Phillips includes its divisions, affiliates and subsidiaries) believes
that the information contained herein (including data and statements) is accurate as of the date hereof. NO WARRANTY OF
MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE AS
CONCERNS THE INFORMATION HEREIN PROVIDED. The information provided herein relates only to the specific product designated and
may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and
methods of use of the product and information referred to herein are beyond the control of Phillips, Phillips expressly disclaim any and all
liability as to any results obtained or arising from any use of the product or such information. No statement made herein shall be construed as
a permission or recommendation for the use of any product in a manner that might infringe existing patents.

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