REVISION DATE:30 Mar 2001
10595 - ARCHIVA 600,630,700 INK - BLACK
SAFETY DATA SHEET
ARCHIVA 600,630,700 INK - BLACK
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY:
ARCHIVA 600,630,700 INK - BLACK
PRODUCT NAME:
GX165 DYE BASED
CHEMICAL NAME 2:
IP00-INK165B
PART No.:
Mrs T. Donaldson (01565 684022 Direct)
CONTACT PERSON:
Swiss Toxicological Information Centre (24 hours)
EMERGENCY TELEPHONES:
Tel: +41 (0)1 251 51 51, Fax: +41 (0)1 252 88 33
E-mail : stic@access.ch, Internet : www.toxi.ch
ILFORD Imaging Limited, Mobberley, Knutsford, Cheshire
MANUFACTURER:
WA16 7JL, ENGLAND. Tel: +44 (0)1565 650000 Fax: +44 (0)1565 872734
ILFORD (Australia) Pty Ltd, Ferntree Gully, Mt Waverley, Vic 3149
Australia. Tel. 03 9541 4511 Fax 03 9544 3002
2. COMPOSITION/INFORMATION ON INGREDIENTS:
NAME CAS No.: CONTENT SYMBOL: RISK:
DYE - BLUE DT 90295-11-7 0-1 % - -
ETHANEDIOL 107-21-1 1-5 % Xn R-22
PROPYLENE GLYCOL 57-55-6 1-5 % - -
GLYCEROL 56-81-5 1-5 % - -
2-PYRROLIDONE 616-45-5 1-5 % Xn R-22, 36
HEXANEDIOL 6920-22-5 1-5 % - -
GLYCIDOL ETHER 68072-38-8 0-1 % Xi R-36
DIETHANOLAMINE 111-42-2 1-5 % Xn R-22, 38, 41,
48/22
DYE - BLACK 85585-91-7 1-5 % - -
1,2-BENZOISOTHIAZOL-3(2H)-ONE 2634-33-5 0-1 % Xn ,N R-22, 38, 41,
43, 50
3. HAZARDS IDENTIFICATION:
May cause sensitisation by skin contact.
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REVISION DATE:30 Mar 2001
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4. FIRST AID MEASURES:
No recommendation given, but first aid may still be required in case of accidental
INHALATION:
exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL
ATTENTION PROMPTLY!
Rinse mouth thoroughly. Drink plenty of water. Get medical attention if any
INGESTION:
discomfort continues.
Rinse with water.
SKIN:
Make sure to remove any contact lenses from the eyes before rinsing. Promptly
EYES:
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at
least 15 minutes. Get medical attention if any discomfort continues.
5. FIRE FIGHTING MEASURES:
This material is not flammable. Use extinguishing media appropriate for
EXTINGUISHING MEDIA:
surrounding fire.
No unusual fire or explosion hazards noted.
UNUSUAL FIRE & EXPLOSION
HAZARDS:
6. ACCIDENTAL RELEASE MEASURES:
Non-hazardous substance. Do not contaminate water sources or sewer. Absorb in
SPILL CLEANUP METHODS:
vermiculite, dry sand or earth and place into containers. Contain Spill. Use large
quantities of water to flush small spills to sanitary sewer if local regulations
permit. Do not flush to septic tank. See Section 13 for disposal considerations.
Flush with plenty of water to clean spillage area. Prevent discharge of larger
quantity to drain.
7. HANDLING AND STORAGE:
Read and follow manufacturer`s recommendations. Avoid spilling, skin and eye
USAGE PRECAUTIONS:
contact. Provide good ventilation.
Keep in cool, dry, ventilated storage and closed containers. Keep in original
STORAGE PRECAUTIONS:
container.
Chemical storage.
STORAGE CRITERIA:
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION:
INGREDIENT NAME: CAS No.: STD LT EXP 8 Hrs ST EXP 15 Min
ETHANEDIOL 107-21-1 OES. 60 mg/m3 125 mg/m3
PROPYLENE GLYCOL 57-55-6 OES. 150 ppm No std.
GLYCEROL 56-81-5 OES. 10 mg/m3 No std.
DIETHANOLAMINE 111-42-2 13 mg/m3
PROTECTIVE EQUIPMENT:
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REVISION DATE:30 Mar 2001
10595 - ARCHIVA 600,630,700 INK - BLACK
Provide eyewash station and it is recommended that a safety shower is also
PROCESS CONDITIONS:
available.
Provide adequate general and local exhaust ventilation. Must not be handled in
VENTILATION:
confined space without sufficient ventilation. It is recommended that general
room ventilation should provide for 10 - 15 room air changes per hour.
No specific recommendation made, but respiratory protection may still be
RESPIRATORS:
required under exceptional circumstances when excessive air contamination
exists.
Use protective gloves made of: Neoprene, nitrile, polyethylene Butyl rubber. Use
PROTECTIVE GLOVES:
thin cotton gloves inside the rubber gloves if allergy risk.
If risk of splashing, wear safety goggles or face shield.
EYE PROTECTION:
Wear appropriate clothing to prevent any possibility of skin contact.
OTHER PROTECTION:
9. PHYSICAL AND CHEMICAL PROPERTIES:
Liquid.
APPEARANCE:
Black.
COLOUR:
No characteristic odour.
ODOUR/TASTE:
>100 760mmHg
BOILING POINT (掳C, interval): Pressure:
<0
MELT./FREEZ. POINT (掳C,
interval):
Not Known
VAPOUR PRESSURE: Temperature (掳C):
1 H2O (water)=1
EVAPORATION RATE: Reference:
8.2
pH-VALUE, CONC. SOLUTION:
Soluble in water.
SOLUBILITY DESCRIPTION:
PARAMETER TEST TEST UNIT REFERENCE
METHOD RESULT
VOC's: SWISS - 814.018 0.0 %
VOC's: EU Vapour pressure 5.0 %
>0.01kPa
10. STABILITY AND REACTIVITY:
Normally stable.
STABILITY:
Avoid excessive heat for prolonged periods of time.
CONDITIONS TO AVOID:
Will not polymerize.
HAZARDOUS
POLYMERIZATION:
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REVISION DATE:30 Mar 2001
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No specific hazardous decomposition products noted.
HAZARDOUS DECOMP.
PRODUCTS:
11. TOXICOLOGICAL INFORMATION:
ethylene glycol 4700.00, 1,2 propanediol 2000.00, glycerine 12600.00,
TOXIC DOSE - LD 50:
2-pyrrolidone 328.00, diethanolamine 710.0 mg/kg (oral rat)
This chemical formulation has not been tested for health effects. Exposure effects
TOXICOLOGICAL
listed are based on existing health data for the individual components which
INFORMATION:
comprise the mixture.
No specific health warnings noted.
INHALATION:
No specific health warnings noted.
INGESTION:
No specific health warnings noted.
SKIN:
No specific health warnings noted.
EYES:
No specific health warnings noted. No specific acute or chronic health impact
HEALTH WARNINGS:
noted, but this chemical may still have adverse impact on human health, either in
general or on certain individuals with pre-existing or latent health problems.
Diethanolamine IARC 3 IARC Int. Agency for Cancer Research.
OTHER HEALTH EFFECTS:
Ingestion. Skin and/or eye contact.
ROUTE OF ENTRY:
12. ECOLOGICAL INFORMATION:
49000.00 ethylene glycol, 1000.00 1,2 propanediol, 54000.00 glycerine, 4600
LC 50, 96 HRS, FISH mg/l:
2-pyrrolidone, 1480.00 diethanolamine
41100.00 ethylene glycol, 10000.00 1,2 propanediol, 500.00 2-pyrrolidone,
EC 50, 48 HRS, DAPHNIA, mg/l:
55.00 diethanolamine
10000.00 ethylene glycol, 250.00 2-pyrrolidone,
IC 50, 72 HRS, ALGAE, mg/l:
Not regarded as dangerous for the environment.
ECOLOGICAL INFORMATION:
13. DISPOSAL CONSIDERATIONS:
Unused and spent solutions may be allowed to be discharged to sanitary sewer by
DISPOSAL METHODS:
permit IF allowed by local regulations. Consult your local authority for advice.
Waste may have to be pre-treated before discharge. Consult local authorities
before discharging any waste to sewer. Do not discharge to septic system. Waste
that cannot be discharged to sewer may have to handled by a licensed hazardous
waste contractor.
14. TRANSPORT INFORMATION:
0
UN No. ROAD:
Not classified for transportation.
ADR CLASS:
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REVISION DATE:30 Mar 2001
10595 - ARCHIVA 600,630,700 INK - BLACK
Not classified for road transport
ROAD TRANSPORT NOTES:
Not classified for rail transport
RAIL TRANSPORT NOTES:
Not classified for sea transport
SEA TRANSPORT NOTES:
Not classified for air transport
AIR TRANSPORT NOTES:
15. REGULATORY INFORMATION:
NC Not classified
Not classified.
RISK PHRASES:
Not classified.
SAFETY PHRASES:
Dangerous Substance Directive 67\548. Dangerous Preparations Directive 88\379.
EU DIRECTIVES:
Classification and Labelling of Substances and Preparations Dangerous for
APPROVED CODE OF
Supply.
PRACTICE:
Occupational Exposure Limits EH40. CHIP for everyone HSG(108).
GUIDANCE NOTES:
16. OTHER INFORMATION:
ILFORD IMAGING BELIEVE THE INFORMATION AND
USER NOTES:
RECOMMENDATIONS CONTAINED HEREIN ARE BASED ON CORRECT
AND FACTUAL DATA. HOWEVER, NO EXPRESS OR IMPLIED
GUARANTEE OR WARRANTY OF ANY KIND IS MADE WITH RESPECT
TO THIS INFORMATION. USE THIS INFORMATION ONLY TO
SUPPLEMENT OTHER INFORMATION YOU HAVE GATHERED AND
THEN MAKE AN INDEPENDENT DETERMINATION ABOUT THE
COMPLETENESS AND SUITABILITY OF ALL INFORMATION TO ENSURE
THE PROPER USE AND DISPOSAL OF THIS PRODUCT AND THE HEALTH
AND SAFETY OF EMPLOYEES AND CUSTOMERS.
European Photographic Chemical Industry Code of Practice For Classification
INFORMATION SOURCES:
And Labelling Material Safety Data Sheet, Misc. manufacturers.
Dr D W Butcher, ILFORD IMAGING Limited, Mobberley, Knutsford, Cheshire,
ISSUED BY:
WA16 7JL. ENGLAND.
30 Mar 2001
REVISION DATE:
Approved.
SAFETY DATA SHEET STATUS:
2001-04-03
PRINTING DATE:
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