MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: STARRETT M-1 All Purpose Lubricant Low VOC
PART NUMBER: MI 95173
GENERAL USE: Aerosol lubricant
PRODUCT DESCRIPTION: Aerosol, amber liquid
DATE PREPARED: October 12, 2005
MANUFACTURER'S NAME
Page 1 of 4
The L.S. Starrett Company March 10, 2005
SUPERSEDES:
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION
121 Crescent St. (978) 249-3551
EMERGENCY TELEPHONE NUMBER
COUNTRY
(CITY, STATE AND ZIP CODE)
USA CHEM 鈥? TEL (800) 255-3924 Outside USA (813) 248-0585
Athol, MA 01331
DISTRIBUTOR'S NAME
Same
TELEPHONE NUMBER FOR INFORMATION
ADDRESS (NUMBER, STREET, P.O. BOX)
EMERGENCY TELEPHONE NUMBER
COUNTRY
(CITY, STATE AND ZIP CODE)
SECTION 2 - HAZARDOUS INGREDIENTS
Hazard RISK PHRASES
%
HAZARDOUS COMPONENTS CAS # EINECS #
Symbol Full Text Section 16
(by weight)
Hydrotreated light distillate 64742-47-8 265-149-8 R-65, 66, 67
60 - 90 Xn
Petrolatum 8009-03-8 232-373-2 Not classified
7 - 13 NC
PROPELLANT
Carbon dioxide 124-38-9 204-696-9 Not classified
NC
not specified
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Aerosol, amber liquid, potentially hazardous vapors. Contains carbon dioxide propellant. Flammable as defined by DOT and TDG for Air /
Ocean transport. Classified by DOT as Combustible for ground transport in containers less than 120 gallons. Classified as Combustible by
OSHA. Can cause serious or fatal complications if swallowed. Can cause eye and skin irritation upon contact. Inhalation of vapors can cause
anesthetic effect leading to death in poorly ventilated areas. Hazard symbols for this product - Xn. Risk Phrases - R10 65
POTENTIAL HEALTH EFFECTS
INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting and malaise.
SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis.
EYES: High vapor concentration or contact may cause irritation and discomfort.
INGESTION: May result in vomiting; aspiration of vomitus into the lungs must be avoided; DO NOT induce vomiting. Minute amounts
aspirated into the lungs can produce severe lung injury, chemical pneumonitis, pulmonary edema or death.
CARCINOGENICITY NTP? IARC MONOGRAPHS? OSHA REGULATED?
No No No
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: STARRETT M-1 All Purpose Lubricant Low VOC
Page 2 of 4
October 12, 2005
SECTION 4 - FIRST AID MEASURES
INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR
and seek emergency medical attention.
SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation
persists, seek medical attention.
EYES: Remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek
medical attention.
INGESTION: DO NOT induce vomiting; if vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs; seek
immediate medical attention. Vomiting may be induced only under the supervision of a physician.
SECTION 5 - FIRE FIGHTING MEASURES
GENERAL HAZARDS: Product is combustible. Products of combustion include compounds of carbon, hydrogen and oxygen, including
carbon monoxide.
EXTINGUISHING MEDIA
Carbon dioxide, water, water fog, dry chemical, chemical foam.
FIRE FIGHTING PROCEDURES
Self - contained respiratory equipment; cool containers to prevent pressure buildup and possible explosion when exposed to extreme heat.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers can explode due to buildup of pressure when exposed to extreme heat.
HAZARDOUS COMBUSTION PRODUCTS
Smoke, fumes, oxides of carbon
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: COMBUSTIBLE - Evacuate and ventilate area; remove all sources
of sparks, ignition and open flames; confine and absorb into approved absorbent; place material into approved containers for disposal; do not
wash to sewer or waterway.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: This material is combustible. It should be stored in tightly closed containers
in a cool, well ventilated area. Vapor may form explosive mixtures in air. All sources of ignition should be controlled. Keep this and other
chemicals out of reach of children. Avoid inhaling concentrated fumes or vapors.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
NIOSH ACGIH
HAZARDOUS COMPONENTS
TWA ppm TWA mg/m3 STEL ppm STEL mg/m3 TWA ppm TWA mg/m3 STEL ppm STEL mg/m3
Hydrotreated light distillate 500 2000
Petrolatum Not established Not established
PROPELLANT
Carbon dioxide 5000 9000 30000 54000 5000 9000 30000 54000
PERSONAL PROTECTION:
RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits are kept below maximum allowable concentrations; if
TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete
regulations.
PROTECTIVE GLOVES: Neoprene gloves, butyl or nitrile rubber gloves with cuffs.
EYE PROTECTION: Protective eyeglasses or chemical safety goggles. Refer to 29 CFR 1910.133 or European Standard EN166.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: STARRETT M-1 All Purpose Lubricant Low VOC
Page 3 of 4
October 12, 2005
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR VAPOR PRESSURE
Amber liquid, pleasant characteristic odor < 0.5 mm Hg @ 20掳 C (liquid) / 856 psia @ 70掳 F (propellant)
VOLATILE ORGANIC COMPOUNDS (Total VOC's) SPECIFIC GRAVITY (WATER = 1)
327 grams / liter 0.8 (liquid phase)
BOILING POINT / BOILING RANGE SOLUBILITY IN WATER
370 - 470掳 F (187.8 - 243.3掳 C) (liquid phase) Negligible
FLASH POINT VISCOSITY
152掳 F ( 67掳 C) TCC Like that of water
FLAMMABLE LIMITS VAPOR DENSITY (AIR = 1)
LEL: 1.0% UEL: 6.0% >1
AUTOIGNITION TEMPERATURE EVAPORATION RATE (WATER = 1)
Not determined <1
SECTION 10 - STABILITY AND REACTIVITY
STABILITY UNSTABLE: CONDITIONS TO AVOID: Extreme temperatures, open flames.
STABLE: XXX
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of
carbon, hydrocarbons, fumes or vapors, and smoke may be produced.
CONDITIONS TO AVOID: None
HAZARDOUS POLYMERIZATION MAY OCCUR:
WILL NOT OCCUR: XXX
SECTION 11 - TOXICOLOGICAL INFORMATION
CAS # LD50 of Ingredient LC50 of Ingredient
Hazardous Components
EINECS # (Specify Species and Route) (Specify Species)
64742-47-8 > 5000 mg / kg Not determined
Hydrotreated light distillate
265-149-8 Oral - rat
8009-03-8 Not established Not established
Petrolatum
232-373-2
PROPELLANT
124-38-9 Information not found Information not found
Carbon dioxide
204-696-9
SECTION 12 - ECOLOGICAL INFORMATION
No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the
chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in
limited quantities. However, such treatment should be evaluated and approved for each specific biological system. None of the ingredients in
this mixture are classified as a Marine Pollutant.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: According to the European Waste Catalogue, waste codes are application specific and should be assigned by
the user based on the application for which the product is used.Dispose of in accordance with Local, State, and Federal Regulations. This
product may produce hazardous vapors in a closed disposal container creating a dangerous environment. Refer to "40 CFR Protection of
Environment Parts 260 - 299" for complete waste disposal regulations. Consult your local, state, or Federal Environmental Protection Agency
before disposing of any chemicals. Do not flush to sanitary sewer or waterway.
SECTION 14 - TRANSPORT INFORMATION
PROPER SHIPPING NAME: Consumer Commodity
DOT HAZARD CLASS / Pack Group: ORM - D / None IATA HAZARD CLASS / Pack Group: See Note below
REFERENCE: 49 CFR 173.306 IMDG HAZARD CLASS: See Note below
UN / NA IDENTIFICATION NUMBER: None RID/ADR Dangerous Goods Code: See Note below
LABEL: CONSUMER COMMODITY UN TDG Class / Pack Group: See Note below
HAZARD SYMBOLS: None Hazard Identification Number (HIN): None
Note: Transportation information provided is for reference only. Client is urged to consult CFR 49 parts 100 - 177, IMDG, IATA, EU, United
Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes,
packaging materials and methods of shipping.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: STARRETT M-1 All Purpose Lubricant Low VOC
Page 4 of 4
October 12, 2005
SECTION 15 - REGULATORY INFORMATION
TSCA (USA - Toxic Substance Control Act)
All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted
from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50.
SARA TITLE III (USA - Superfund Amendments and Reauthorization Act)
311/312 Hazard Categories
Immediate health, sudden release of pressure
313 Reportable Ingredients:
None
CERCLA (USA - Comprehensive Response Compensation and Liability Act)
None
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
There are no chemicals present known to the state of California to cause cancer or reproductive toxicity.
CPR (Canadian Controlled Products Regulations)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the
information required by the Controlled Products Regulations. WHMIS Classification: A, B3
IDL (Canadian Ingredient Disclosure List)
Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 2.
DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)
Components of this product identified by CAS number are listed on the DSL or NDSL, or are otherwise in compliance with the New
Substances Notification (NSN) regulations. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated.
EINECS (European Inventory of Existing Commercial Chemical Substances)
Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.
WGK Water Quality Index: nwg VbK Index: Not applicable
SAFETY PHRASES:
SYMBOL(S) REQUIRED FOR
RISK PHRASES:
LABEL
R65 Damaging to lungs when swallowed S2 Keep out of the reach of children.
R66 Repeated exposure may cause skin
dryness or cracking. Harmful
R67 Vapours may cause drowsiness and
dizziness.
SECTION 16 - OTHER INFORMATION
R65 Damaging to lungs when swallowed
Notes & full R-Phrase text
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
HMIS HAZARD RATINGS HEALTH * = Chronic Health Hazard 2 = MODERATE
1
FLAMMABILITY 0 = INSIGNIFICANT 3 = HIGH
2
PHYSICAL HAZARD 1 = SLIGHT 4 = EXTREME
0
PERSONAL PROTECTIVE EQUIPMENT Safety Glasses, Gloves
B
REVISION SUMMARY:
This MSDS has been revised in the following Section 14 - DOT Transportation
sections: Section 15 - Text
MSDS Prepared by: Chem-Tel, Inc.
1305 N. Florida Ave.
Tampa, Florida USA 33602 (800) 255-3924 Outside USA (813) 248-0573
The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the
manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current,
applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use of
this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as
described in Section 1.
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