MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
Material Safety Data Sheet
Copyright, 2008, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Super 77 Classic Spray Adhesive
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 01/23/2008
Supercedes Date: 11/15/2006
Document Group: 11-4257-9
Product Use:
Intended Use: Adhesive aerosol
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
NON-VOLATILE COMPONENTS Trade Secret 15 - 40
CYCLOHEXANE 110-82-7 10 - 30
2-METHYLPENTANE 107-83-5 10 - 30
DIMETHYL ETHER 115-10-6 7 - 13
ISOBUTANE 75-28-5 7 - 13
PROPANE 74-98-6 7 - 13
3-METHYLPENTANE 96-14-0 3- 7
2,2-DIMETHYLBUTANE 75-83-2 1- 5
2,3-DIMETHYLBUTANE 79-29-8 1- 5
HEXANE 110-54-3 0.5 - 1.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: light cream colored, sweet/fruity odor.
General Physical Form: Gas
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. Contains a
chemical or chemicals which can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Prolonged or repeated exposure may cause:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Intentional concentration and inhalation may be harmful or fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of
the hands and feet, tremors and muscle atrophy.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
HALOGEN ANALYSIS: The dry ingredients of 3M Super 77 Spray Adhesive were subjected to combustion in a Parr oxygen
bomb. The decomposition products were analyzed by Ion Chromotographic analysis for halogen and sulfur content. Chlorine 0.05%;
Fluorine <0.001%, Bromine <0.001%; Sulfur <0.035%.
SECTION 4: FIRST AID MEASURES
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
-42.00 潞F [Test Method: Tagliabue Closed Cup]
Flash Point
Approximately 1.5 % volume
Flammable Limits - LEL
Approximately 8.6 % volume
Flammable Limits - UEL
Class IA Flammable Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol
container contains gas under pressure. Aerosol container contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an
operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or
its contents is available.
Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill.
Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all
ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with
fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with
good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill
area to burn or explode. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not
remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools.
Clean up residue. Collect the resulting residue containing solution. Place in a metal container approved for transportation by
appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking while
handling this material. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the
reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors.
Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation,
vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. Use
general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If
ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Use with functioning spray booth or local exhaust. Do not use in a confined area or
areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to
below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection
equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use
appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits
and/or control spray or mist.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Nitrile Rubber.
8.2.3 Respiratory Protection
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
CYCLOHEXANE ACGIH TWA 100 ppm
CYCLOHEXANE OSHA TWA 300 ppm Table Z-1
DIMETHYL ETHER AIHA TWA 1000 ppm
DIMETHYL ETHER CMRG TWA 1000 ppm
HEXANE ACGIH TWA 50 ppm Skin Notation*
HEXANE OSHA TWA, Vacated 50 ppm Table Z-1A
HEXANE OSHA TWA 500 ppm Table Z-1A
HEXANE (ISOMERS OTHER THAN N- ACGIH TWA 500 ppm
HEXANE)
HEXANE (ISOMERS OTHER THAN N- ACGIH STEL 1000 ppm
HEXANE)
ISOBUTANE ACGIH TWA 1000 ppm
PROPANE ACGIH TWA 1000 ppm
PROPANE OSHA TWA 1000 ppm Table Z-1
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
light cream colored, sweet/fruity odor.
Odor, Color, Grade:
Gas
General Physical Form:
No Data Available
Autoignition temperature
-42.00 潞F [Test Method: Tagliabue Closed Cup]
Flash Point
Approximately 1.5 % volume
Flammable Limits - LEL
Approximately 8.6 % volume
Flammable Limits - UEL
2.97 [Ref Std: AIR=1]
Vapor Density
0.697 [Ref Std: WATER=1]
Specific Gravity
Approximately 6.7 Units not avail. or not appl.
pH
No Data Available
Melting point
Nil
Solubility in Water
1.90 [Ref Std: ETHER=1]
Evaporation rate
<=1 % weight
Hazardous Air Pollutants
75 % [Test Method: tested per SCAQMD method 305]
Volatile Organic Compounds
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
75 % weight
Percent volatile
527 g/l [Test Method: tested per SCAQMD method 305]
VOC Less H2O & Exempt Solvents
Not Applicable
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Toxic Vapor, Gas, Particulate During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
The facility should be equipped to handle gaseous waste.
Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill.
RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
62-4437-0921-7 62-4437-0922-5 00-21200-25463-5
62-4437-0925-8 00-21200-30091-2 62-4437-0926-6
62-4437-0927-4 00-21200-25463-5 62-4437-0928-2 00-21200-25463-5
62-4437-0929-0 00-21200-25463-5 62-4437-0930-8
62-4437-0931-6 62-4437-0933-2 00-21200-25463-5
62-4437-0934-0 00-21200-25463-5 62-4437-4026-1 00-21200-76098-3
62-4437-4030-3 00-21200-76098-3 62-4437-4830-6 00-21200-85853-6
62-4437-4835-5 00-21200-45142-3 62-4437-4840-5 00-21200-85853-6
62-4437-4925-4 62-4437-4926-2 00-21200-45160-7
62-4437-4930-4 00-21200-96315-5 62-4437-4931-2 00-21200-39245-0
62-4437-4933-8 00-21200-85846-8 62-4437-4935-3
62-4437-4936-1 00-21200-21210-8 62-4437-4937-9 00-21200-89541-8
62-4437-4938-7 00-21200-39240-5 62-4437-4939-5
62-4437-9999-4 CS-0406-2131-3
CS-0406-6984-1
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
CYCLOHEXANE 110-82-7 10 - 30
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
CYCLOHEXANE 110-82-7 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
Additional Information: Synthetic polymer, resin and antioxidant. Not hazardous according to Canadian WHMIS criteria. Non-
WHMIS controlled.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).
Revision Changes:
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MATERIAL SAFETY DATA SHEET 3M(TM) Super 77 Classic Spray Adhesive 01/23/2008
Copyright was modified.
Section 3: Potential effects from skin contact information was modified.
Section 3: Potential effects from inhalation information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 6: Release measures information was modified.
Section 7: Handling information was modified.
Section 8: Prevention of swallowing information was modified.
Section 4: First aid for ingestion (swallowing) - decontamination - was modified.
Section 4: First aid for ingestion (swallowing) - medical assistance - was modified.
Section 3: Immediate other hazard(s) was modified.
Section 3: Other health effects information was modified.
Section 3: Other health effects information (reproductive hazards) was added.
Section 14: ID Number(s) and/or UPC(s) Template 1 was added.
Section 2: Ingredient table was added.
Section 15: TSCA section 12[b] text was added.
Section 15: EPCRA 313 information was added.
Section 15: EPCRA 313 text was added.
Section 8: Exposure guidelines ingredient information was added.
Section 8: Exposure guidelines legend was added.
Section 8: Exposure guideline note was added.
Section 15: TSCA section 12[b] information was added.
Section 8: Exposure guidelines data source legend was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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