Material Safety Data Sheet
WHMIS Protective Clothing TDG Road / Rail
D-2A Not controlled under TDG (Canada).
Section 1. Product and Company Identification
Not available
ALLOY Sn/Pb
Common Name Code
Validation Date 2005-06-17
Metal alloy
Product type
Version number 3
Alloy Sn-Pb (5/95, 10/90, 20/90, 30/70, 25/75, 38/62, 40/60, 50/50, 60/40, 63/37, 70/30, 90/10, 95/5)
Synonym
Industry
Material Uses
AIM
Supplier In Case of INFOTRAC
Emergency (North America): (800) 535-5053
AIM
Manufacturer
(International): (352) 323-3500
Section 2. Hazardous Components
CAS #
Name % by Weight Toxicity Data ( LC50/LD50, TLV)
TWA: 2 (mg/m 3) from OSHA (PEL) [United States]
1) Tin 7440-31-5 5-95
(Variable) [1997] INHALATION Respirable.
TWA: 2 (mg/m 3) from ACGIH (TLV) [United States]
[1994] INHALATION Respirable.
TWA: 0.05 (mg/m 3) from ACGIH (TLV) [United States]
2) LEAD 7439-92-1 5-95
(Variable) [1995] INHALATION
TWA: <0.1 (ppm) from NIOSH INHALATION
Respirable.
Section 3. Hazards Identification
Physical State and Appearance Solid. (bar, ingot, solid wire, preforms)
Emergency Overview CAUTION!
Risk of cancer depends on duration and level of exposure Avoid exposure during pregnancy. Avoid contact of spilled
material and runoff with soil and surface waterways.
Not available.
Routes of Entry
Potential Acute Health Effects
Eyes Fumes and/or dusts produced by this product may be hazardous in case of eye contact (irritant).
Skin Fumes and/or dusts produced by this product may be hazardous in case of skin contact (irritant, sensitizer).
Inhalation Fumes and/or dusts produced by this product may be hazardous in case of inhalation.
Ingestion Fumes and/or dusts produced by this product may be hazardous in case of ingestion.
Chronic effects: Fumes and/or dusts produced by this product may be hazardous in case of ingestion, of inhalation.
Potential Chronic Health
This product may be hazardous in case of skin contact (irritant, sensitizer), of eye contact (irritant).
Effects
Medical Conditions Aggravated Repeated exposure to toxic material may produce general deterioration of health by an accumulation in one or
many human organs.
by Overexposure:
Overexposure /Signs/Symptoms Not available.
See Toxicological Information (section 11)
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ALLOY Sn/Pb Page: 2/6
Section 4. First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
Eye Contact
water for at least 15 minutes. Get medical attention if irritation occurs.
Wash skin with water and mild soap. Get medical attention if irritation occurs.
Skin Contact
MOLTEN METAL causes SEVERE BURNS. In case of burn : Rinse skin with water. Do not burst
Hazardous Skin Contact
blisters. Do not cover with greasy compound. Cover with a wet sterile gauze. Get medical attention
immediately.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen Get medical attention if symptoms appear.
Hazardous Inhalation Not available.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth
Ingestion
to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
attention if symptoms appear.
Not available.
Hazardous Ingestion
Not available.
Notes to Physician
Section 5. Fire Fighting Measures
Flammability of the Product Non-flammable.
Not applicable.
Auto-Ignition Temperature
Not applicable.
Flash Points
Not applicable.
Flammable Limits
Not available.
Products of Combustion
Not applicable.
Fire Hazards in Presence of
Various Substances
Non-explosive in presence of open flames and sparks, of shocks.
Explosion Hazards in
Presence of Various
Substances
Not applicable.
Fire Fighting Media
and Instructions
Protective Clothing (Fire) Not applicable.
Not available.
Special Remarks on Fire
Hazards
Not available.
Special Remarks on
Explosion Hazards
Section 6. Accidental Release Measures
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning
Small Spill and Leak
by spreading water on the contaminated surface and dispose of according to local and regional
authority requirements.
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by
Large Spill and Leak
spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.
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ALLOY Sn/Pb Page: 3/6
Section 7. Handling and Storage
Avoid contact of spilled material and runoff with soil and surface waterways.
Handling
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Section 8. Exposure Controls, Personal Protection
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne
Engineering Controls
levels below recommended exposure limits. If user operations generate dust, fume or mist, use
ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection
Eyes Safety glasses.
Body Lab coat.
Respiratory Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate
respirator when ventilation is inadequate.
Hands Gloves.
Feet Not applicable.
* Note:Suggested protective clothing may not be adequate for a specific process. Consult a specialist before using.
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus
Personal Protection in Case
should be used to avoid inhalation of the product. Suggested protective clothing might not be
of a Large Spill
sufficient; consult a specialist BEFORE handling this product.
Exposure Limits
Product Name
TWA: 2 (mg/m3) from OSHA (PEL) [United States] [1997] INHALATION Respirable.
1) TIN
TWA: 2 (mg/m3) from ACGIH (TLV) [United States] [1994] INHALATION Respirable.
TWA: 0.05 (mg/m3) from ACGIH (TLV) [United States] [1995] INHALATION
2) LEAD
TWA: <0.1 (ppm) from NIOSH INHALATION Respirable.
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Solid. (bar, ingot, solid wire, preforms) Not applicable
Physical State and Odor
Appearance
Taste Not applicable.
Not applicable.
Molecular Weight
Colorless.
Color
Not applicable.
Chemical formula
Not applicable. Specific Gravity 7.6 to 11.2 (Water = 1)
pH (1% Soln/Water)
Not available.
Acid Value (IPC TM-650,
2.3.13)
Not available.
Boiling/Condensation Point
not available
Melting/Freezing Point
Not available.
Critical Temperature
Vapor Pressure Not applicable.
Not available.
Vapor Density
Not available.
Volatility
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ALLOY Sn/Pb Page: 4/6
Not available.
Odor Threshold
Not available.
Evaporation Rate
Not available.
VOC
Not available.
Viscosity
The product is insoluble in water and oil.
LogKow
Non-ionic.
Ionicity (in Water)
Dispersion Properties Is not dispersed in cold water, hot water, methanol, diethyl ether, n-octanol, acetone.
Insoluble in cold water, hot water, methanol, diethyl ether, n-octanol, acetone.
Solubility
Physical Chemical Comments Not available.
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Stable in normal conditions. Over melting point, toxic metallic oxides may be evolved.
Conditions of Instability
Incompatibility with Various Slightly reactive with oxidizing agents, metals, acids, moisture.
Substances
Not available.
Hazardous Decomposition
Products
Will not occur.
Hazardous Polymerization
Not considered to be corrosive for metals and glass according to our database.
Corrosivity
Not available.
Special Remarks on
Corrosivity
Section 11. Toxicological Information
Toxic and Chronic Effects on Fumes and/or dusts produced by this product may be hazardous in case of ingestion, of inhalation.
Humans This product may be hazardous in case of skin contact (irritant, sensitizer), of eye contact (irritant).
CARCINOGENIC EFFECTS: Classified NONE by NIOSH [Tin]. Classified A3 (Proven for animal) by
ACGIH, 2B (Possible for human) by IARC [LEAD]. Classified NONE by NIOSH [LEAD].
MUTAGENIC EFFECTSNot available.
:
TERATOGENIC EFFECTS Classified 1 by European Union [LEAD].
:
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive
system/toxin/male [PROVEN] [LEAD].
The product may be toxic to blood, kidneys, lungs, the nervous system, the reproductive system,
spleen, brain, digestive system, gastrointestinal tract, upper respiratory tract, skin, central nervous
system (CNS), eye, lens or cornea.
Repeated or prolonged exposure to the substance can produce target organs damage.
LD50: Not available.
Toxicity to Animals
LC50: Not available.
Special Remarks on Chronic Human: LEAD crosses the placental barrier.
Effects on Humans CHRONIC OVEREXPOSURE EFFECTS; Increase of LEAD LEVEL in blood, muscle soreness, metallic
taste, abdominal cramps, headaches.
Special Remarks on Other MOLTEN METAL can cause severe BURNS!
Toxic Effects on Humans Prolonged and repeated contact with bare skin may cause irritation or dermatitis.
Fumes and dust may irritate eyes, digestive system and respiratory tract.
Special Remarks on Toxicity No additional remark. (Tin)
to Animals
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ALLOY Sn/Pb Page: 5/6
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Not available.
Biodegradable/OECD
Not available.
Mobility
Possibly hazardous short term degradation products are not likely. However, long term degradation
products may arise.
The product itself and its products of degradation are not toxic.
Toxicity of the Products of
Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control
Waste Information
regulations.
Not available.
Waste Stream
Consult your local or regional authorities.
Section 14. Transport Information
TDG Classification Not controlled under TDG (Canada).
Not regulated
Not applicable.
Special Provisions for
Transport
Not controlled under IMDG.
IMO/IMDG Classification
Not available.
Marine Pollutant
Not controlled under ADR (Europe).
ADR/RID Classification
Not controlled under IATA.
ICAO/IATA Classification
Section 15. Regulatory Information
CLASS D-2A: Material causing other toxic effects
WHMIS (Canada)
(VERY TOXIC).
CEPA DSL: Tin; LEAD
Canadian NPRI: LEAD
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ALLOY Sn/Pb Page: 6/6
Section 16. Other Information
BIRTH DEFECT HAZARD
Label statements
HARMFUL IF SWALLOWED OR INHALED
MAY CAUSE EYES AND SKIN IRRITATION
MAY CAUSE TARGET ORGANS DAMAGE
CONTAINS MATERIAL WHICH CAN CAUSE CANCER BASED ON ANIMAL DATA
-CHEMTOX database
References
-ALL COMPONENTS WITH SUSCEPTIBLE HAZARDS THAT ARE PRESENT IN A CONCENTRATION
Other Special
GREATER THAN 1 % (GREATER THAN 0.1 % FOR CARCINOGENS) HAVE BEEN DISCLOSED IN THIS
Considerations
SAFETY DOCUMENT.
Document
Modifications
Validated by Robert Richard on 2005-06-17. Verified by Robert Richard.
Printed 2005-06-17.
Information/Contact AIM
9100 Henri-Bourassa east, Montreal, Quebec, Canada, H1E 2S4
(514) 494-2000 (800) 361-0783
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever
for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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