Material Safety Data Sheet
Revision Date: 08/04/2006 Issue date: 08/05/2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Loctite(R) Relaxed Fits Bearing Mount 680 Item No. : 37485 / IDH No. 492148
Product Use: Adhesive Region: Canada
Company address: Contact Information:
Henkel Canada Corporation Telephone: (905) 814-6511
2225 Meadowpine Boulevard Emergency telephone: (905) 814-6511
Mississauga, Ontario L5N 7P2 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Aromatic dimethacrylate ester 30-60 None None None
24448-20-2
Hydroxyalkyl methacrylate 30-60 None None 1 ppm TWA; 3 ppm STEL
27813-02-1
Bisphenol A fumarate resin 10-30 None None None
39382-25-7
3
Cumene hydroperoxide 1-5 None None 1 ppm (6 mg/m ) Skin
80-15-9 (WEEL), 1ppm, skin TWA,
(WEEL)
Polyglycol dimethacrylate 1-5 None None None
25852-47-5
1-Acetyl-2-phenylhydrazine 0.1-1 None None None
114-83-0
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Physical state: Liquid WHMIS hazard class: D.2.B
Color: Green
Odor: Mild
CAUSES EYE IRRITATION.
WARNING:
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
MAY CAUSE SKIN IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health Effects
Inhalation: May cause respiratory tract irritation.
Skin contact: May cause skin irritation. May cause allergic skin reaction.
Eye contact: Contact with eyes will cause irritation.
Ingestion: May be harmful if swallowed.
Existing conditions aggravated by Eye, skin, and respiratory disorders.
exposure:
See Section 11 for additional toxicological information.
Item No. : 37485 / IDH No. 492148 Product name: Loctite(R) Relaxed Fits Bearing Mount 680
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4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.
Skin contact: Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse.
Get medical attention if symptoms occur.
Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding
eyelids open all the time. Get medical attention.
Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 93潞C (200潞F) Tagliabue closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: None
Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapors.
Sensitivity to mechanical impact: Not available.
Sensitivity to static discharge: Not available.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Ensure adequate ventilation. Soak up with inert absorbent. Store in a partly filled, closed container until
disposal.
7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Avoid breathing vapor
and mist. Wash thoroughly after handling.
Storage: For safe storage, store at or below 38掳C (100掳F). Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Canada Customer Service at (905) 814-6511.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne
contamination below occupational exposure limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). The recommended air
purifying respirator cartridge is an organic vapor/particulate filter combination cartridge (OV/P100).
Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene
gloves.
Eye/face protection: Safety goggles or safety glasses with side shields.
Item No. : 37485 / IDH No. 492148 Product name: Loctite(R) Relaxed Fits Bearing Mount 680
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See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Green
Odor: Mild
Odor Threshold: Not available
Vapor pressure: Less than 5 mm Hg at 27潞C (80潞F)
pH: Not applicable
Boiling point/range: Greater than 149潞C (300潞F)
Melting point/range: Not available
Specific gravity: 1.11 at 26.6潞C (80潞F)
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available
VOC content: 4.2216%; 40.2971 grams/liter
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: Oxides of carbon. Irritating organic vapors. Phenols.
Incompatability: Strong oxidizers. Reducing agents. Acids. Bases. Rust. Zinc. Aluminum. Iron. Copper. Alkalis.
Aldehydes. Amines. Free radical initiators. Peroxides.
Conditions to avoid: Exposure to sunlight. Heat, flames and sparks. See "Handling and Storage" (Section 7) and
"Incompatabilty" (Section 10).
11. TOXICOLOGICAL INFORMATION
Product toxicity data: Acute oral LD50 greater than 5000mg/kg (rat)(estimated). Acute dermal LD50 greater than 2000 mg/kg
(rabbit) (estimated).
Toxicologically synergistic products: Not available.
Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and
Mutagenicity.
Item No. : 37485 / IDH No. 492148 Product name: Loctite(R) Relaxed Fits Bearing Mount 680
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Ingredient Toxicity Data & Carcinogen Status
Hazardous components LD50s & LC50s Other LD50s NTP IARC OSHA ACGIH -
and LC50s Carcinogen Carcinogen Carcinogen Carcinogens
Aromatic dimethacrylate ester None None No No No No
24448-20-2
Hydroxyalkyl methacrylate Oral LD50 (Rat) None No No No No
27813-02-1 = 11200 mg/kg
Dermal LD50
(Rabbit) > 3000
mg/kg
Bisphenol A fumarate resin None None No No No No
39382-25-7
Cumene hydroperoxide Inhalation LC50 None No No No No
80-15-9 (Rat) = 220 ppm
Oral LD50 (Rat)
= 382 mg/kg
Polyglycol dimethacrylate None None No No No No
25852-47-5
1-Acetyl-2-phenylhydrazine Oral LD50 None No No No No
114-83-0 (Mouse) = 270
mg/kg
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Aromatic dimethacrylate ester Allergen, Irritant
24448-20-2
Hydroxyalkyl methacrylate Allergen, Irritant
27813-02-1
Bisphenol A fumarate resin Allergen, Irritant
39382-25-7
Cumene hydroperoxide Allergen, Central nervous system, Corrosive, Irritant, Mutagen
80-15-9
Polyglycol dimethacrylate Allergen, Irritant
25852-47-5
1-Acetyl-2-phenylhydrazine Allergen, Blood, Kidney, Mutagen, Some evidence of carcinogenicity
114-83-0
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of in accordance with federal and local regulations.
14. TRANSPORT INFORMATION
Canada Transportation of Dangerous Goods - Ground:
Proper shipping name: Unrestricted
Hazard class or division: None
Identification number: None
Packing group: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Unrestricted
Hazard class or division: None
Identification number: None
Packing group: None
WaterTransportation (IMO/IMDG):
Proper shipping name: Unrestricted
Item No. : 37485 / IDH No. 492148 Product name: Loctite(R) Relaxed Fits Bearing Mount 680
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Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None
15. REGULATORY INFORMATION
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 8
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains
all the information required by the Controlled Product Regulations.
Prepared by: Regulatory Affairs
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from
sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
Item No. : 37485 / IDH No. 492148 Product name: Loctite(R) Relaxed Fits Bearing Mount 680
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