Material Safety Data Sheet
Transfer Agent II
Weyerhaeuser Company Emergency Phone: (253) 924-5000
PO Box 9777 Additional Information: (253) 924-3865
Federal Way, WA 98063-9777 CHEMTREC: (800) 424-9300
http://www.weyerhaeuser.com/environment/msds/default.asp Revised Date: September 26, 2006
1. Product Identification
Product Manufacturing Location(s)
Estimate Number: 16000011 Specialty Products Division
Ink Additive Description: HS Transfer Agent Oregon Ink Plant
5570 SW Western Avenue, Beaverton, OR 97005
(503) 644-8125 (information)
Ohio Ink Plant
865 Pittsburgh Drive, Delaware, OH 43015
(614) 363-9882
Synonyms: Flexo Ink Additive, HS Transfer Agent.
2. Hazardous Ingredients/Identity Information
Name CAS# Percent Agency Exposure Comments
Limits
Styrene Acrylic Mixture 8 - 5% OSHA Non Established Water is the remaining
Copolymer Not available ACGIH ingredient (92-95%)
3. Hazard Identification
Appearance and Odor: White milky liquid with a sweet odor.
Primary Health Hazards: Slight irritation to eyes and skin. Polymers are typically made up of high
molecular weight compounds (1000 MW or greater) and are unlikely to cross biological membranes
and cause systemic toxicity. Dermal exposure is expected to be the primary route of exposure.
Inhalation is not expected to be a significant route of exposure, however, inhalation of high volume of
mist or vapor can cause irritation of nose, throat and lungs.
Primary Route(s) of Exposure:
Ingestion: Not a likely source of exposure. This product is not intended to be ingested. Ingestion
could result in stomach cramps, nausea, or vomiting and act as a laxative. However, the
component materials are not known to be toxic.
Skin: Mild irritant, brief direct contact is harmless. Prolonged and/or repeated contact may cause
irritation, redness, burning, drying and cracking of the skin.
Inhalation: Not a likely source of exposure. This product is not known to be an inhalation hazard.
Where fogs or mists are created, the product may cause irritation.
Eye: Brief direct contact may cause irritation. Prolonged and/or repeated contact may cause
irritation or possible burns.
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3. Hazard Identification (cont鈥檇.)
Medical Conditions Generally Aggravated by Exposure: Dermatitis
Signs and Symptoms of Exposure:
Acute Health Hazards: None Known
Chronic Health Hazards: None Known
Carcinogenicity Listing:
NTP: Not listed
IARC Monographs: Not listed
OSHA Regulated: Not listed
4. Emergency and First-Aid Procedures
Ingestion: If large quantity swallowed, give two glasses of water (pint/0.5 liter) if victim completely
conscious/alert. Do not induce vomiting unless directed to do so by medical personnel. Seek
medical attention if symptoms develop. Provide copy of this MSDS to medical personnel.
Eye Contact: Flush with water to remove. Seek medical attention if irritation or discomfort persists.
Skin Contact: Immediately remove contaminated clothing. Wash skin with mild soap and water. Seek
medical assistance if irritation or discomfort persists. Provide copy of this MSDS to medical
personnel.
Skin Absorption: Not expected to occur. Wash with soap and water.
Inhalation: Remove to fresh air. Seek medical assistance if persistent irritation, severe coughing, or
breathing difficulty occurs. Provide copy of this MSDS to medical personnel.
Note to Physician: None
5. Fire and Explosion Data
Flash Point (Method Used) : > 232掳F SCC 鈥? considered noncombustible
LFL = NAP UFL = NAP
Flammable Limits:
Extinguishing Media: Water, dry chemical, carbon dioxide.
Autoignition Temperature: NAP
Special Firefighting Procedures: Self-contained breathing apparatus and protective clothing should be
worn in chemical fires. Water may be ineffective, serving only to spread product, but may be used to
cool containers.
Unusual Fire and Explosion Hazards: Material is aqueous and is not expected to burn. If heated to
dryness, the remaining organic polymers and pigments, although difficult to ignite, will burn as a class
III B fire. It is recommended that containers be tightly closed and isolated from heat, electrical
equipments and flame. A closed container could possible explode when exposed to extreme heat.
Health = 1 Fire = 0 Reactivity = 0 PPE = B
HMIS Rating (Scale 0-4):
Health = 1 Fire = 1 Reactivity = 0
NFPA Rating (Scale 0-4):
6. Accidental Release Measures
Steps to be Taken In Case Material Is Released or Spilled: Dike and contain spill with absorbent
material such as clay or other commercially available material. Place in container for disposal. Wear
safety glasses and chemical-resistant gloves to minimize exposure.
7. Handling and Storage
Precautions to be Taken In Handling and Storage: Follow standard industrial practices when handling
this product or empty containers. Avoid getting product on skin, eyes, or clothing. If contact with the
product occurs, remove effected clothing and wash with soap and water. Store in a cool, dry, well-
ventilated area away from incompatible materials. Avoid excessive hot or cold temperatures. Keep
containers tightly closed when not in use.
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8. Exposure Control Measures, Personal Protection
Personal Protective Equipment:
RESPIRATORY PROTECTION 鈥? Under normal conditions of use, respiratory protection is not required.
If a fog or mist is produced, use NIOSH/MSHA approved respirator with organic vapor absorbing
cartridges. The respirator program must comply with OSHA and ANSI standards.
EYE PROTECTION 鈥? Chemical safety glasses recommended.
PROTECTIVE GLOVES 鈥? Chemically-resistant gloves are recommended.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT 鈥? Eye wash station.
WORK/HYGIENE PRACTICES 鈥? Wash hands before eating, drinking, or smoking, and at the end of the
shift.
Ventilation:
LOCAL EXHAUST 鈥? Provide local exhaust as needed to limit exposure.
MECHANICAL (GENERAL) 鈥? Provide general ventilation in processing and storage areas to limit
exposures.
SPECIAL 鈥? None
OTHER 鈥? None
9. Physical/Chemical Properties
Physical Description: Clear to white liquid with a mild ammonia odor.
> 212掳F
Boiling Point (@ 760 mm Hg):
<1
Evaporation Rate (Butyl acetate = 1):
32掳F
Freezing Point:
NAV
Melting Point:
NAV
Molecular Formula:
NAV
Molecular Weight:
NAV
Oil-water distribution coefficient:
Not determined
Odor threshold:
8.5-10.0
pH:
100% - completely soluble
Solubility in Water (% by weight):
1.0 鈥? 1.2
Specific Gravity (H2O = 1):
NAV
Vapor Density (air = 1; 1 atm):
NAV
Vapor Pressure (mm Hg):
NAV
Viscosity:
% Volatile by Volume [@ 70oF (21oC)]: NAV
8.33
Density (lb/gal):
Volatile Organic Compounds (VOC鈥檚, %wt): 0%
10. Stability and Reactivity
鈱? Stable
Stability: Unstable
Conditions to Avoid: High temperatures and freezing conditions.
Incompatibility (Materials to Avoid): Strong bases, oxidizing or reducing agents and strong acids.
Hazardous Decomposition or By-Products: Carbon monoxide, carbon dioxide and oxides of nitrogen.
鈱? Will not occur
Hazardous Polymerization: May occur
Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: None
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11. Toxicological Information
Toxicity Data: None available for product in purchased form. The information available is based on the
toxicity profiles of a number of acrylic emulsions that are similar in composition to the acrylic polymer
of this product. Oral LD50 - rat: > 5000 mg/kg Dermal LD50 - rabbit: > 5000 mg/kg, Skin irritation -
rabbit practically non-irritating. Eye irritation 鈥? rabbit: inconsequential irritation.
Components: NAV
Target Organs: Not available for product in purchased form.
12. Ecological Information
Environmental Fate: Because the acrylic is chemically stable and non-toxic, it does not degrade into
harmful products. This product in purchased form has not been tested. However, the physical and
chemical nature of the product and toxicological data on ingredients indicate that this product is of
relatively low risk. No bioaccumulation of the polymer is expected because of the very large
molecular size which is likely to inhibit membrane permeability and prevent uptake during exposure.
Environmental Toxicity: None available for product in purchased form.
13. Disposal Considerations
Waste Disposal Method: Check with your local sewer authority before disposing to sewer. This
material is not RCRA hazardous waste. In liquid form, this product may be determined to be a
鈥渟pecial鈥? waste. Dispose of material in accordance with local, state, and federal regulations.
14. Transport Information
Mode: (Air, Land, water) Not regulated as a hazardous material by the U.S. Department of
Transportation.
NAP
Proper Shipping Name:
NAP
Hazard Class:
NAP
UN/NA ID Number:
Not a regulated product.
TDG:
NAP
Packing Group:
NAP
Information Reported for Product/Size:
NAP
USDOT Shipping Classification:
15. Regulatory Information
TSCA: All ingredients of this product are listed.
CERCLA: Product ingredients are not subject to reporting requirement of CERCLA
DSL: Product ingredients are listed.
STATE RIGHT-TO-KNOW:
California 鈥? Prop 65 鈥? This product does not contain substances identified on the Proposition 65 list at
levels that pose a significant risk for purposes of Section 25249.10(c) or result in an observable effect
for purposed of Section 25249.10(c) of the Act.
Minnesota 鈥? Hazardous Substance List 鈥? NAP
New Jersey 鈥? This product does not contain a substance identified on New Jersey鈥檚 environmental
hazardous substance list.
Pennsylvania 鈥? This product does not contain a substance identified on Pennsylvania鈥檚 environmental
hazardous substance list.
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15. Regulatory Information (cont鈥檇.)
SARA 313 Information: This product does not contain any chemical components with known CAS
numbers that exceed the De Minimis reporting levels established by SARA Title III, Section 313 and
40 CFR Part 372.
SARA 311/312 Hazard Category: This product has been reviewed according to the EPA 鈥淗azard
Categories鈥? promulgated under SARA Title III Section 311 and 312 and is considered, under
applicable definitions, to meet the following categories:
An immediate (acute) health hazard Yes
A delayed (chronic) health hazard No
A fire hazard No
A reactivity hazard No
A sudden release hazard No
FDA: This product complies with the Food and Drug Administration (FDA) requirement found in 21 CFR
搂175. These regulations indicate that adhesives, inks and related materials may be safely used for
food packaging purposes, when they are separated by a functional barrier that prevents migration of
the material into the food (Indirect Food Contact).
WHMIS Classification: Product does not meet WHMIS hazard classification criteria. The MSDS
contains all other information required by the Controlled Products Regulations.
CONEG: This product is certified to be in full compliance with the CONEG Model Legislation for
packaging and packaging ink components.
16. Additional Information
Date Prepared: 08/27/04
Date Revised: 09/26/2006
Prepared By: Weyerhaeuser Company Corporate Environment, Health & Safety
Weyerhaeuser MSDS available on: http://www.weyerhaeuser.com/environment/msds/default.asp
User鈥檚 Responsibility: The information contained in this Material Safety Data Sheet is based on the
experience of occupational health and safety professionals and comes from sources believed to be
accurate or otherwise technically correct. It is the user鈥檚 responsibility to determine if the product is
suitable for its proposed application(s) and to follow necessary safety precautions. The user has the
responsibility to make sure that this MSDS is the most up-to-date issue.
Definition of Common Terms:
ACGIH = American Conference of Governmental Industrial Hygienists
C = Ceiling Limit
CAS# = Chemical Abstracts System Number
DOT = U. S. Department of Transportation
DSL = Domestic Substance List
EC50 = Effective concentration that inhibits the endpoint to 50% of control population
EPA = U.S. Environmental Protection Agency
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LC50 = Concentration in air resulting in death to 50% of experimental animals
LCLo = Lowest concentration in air resulting in death
LD50 = Administered dose resulting in death to 50% of experimental animals
LDLo = Lowest dose resulting in death
LEL = Lower Explosive Limit
LFL = Lower Flammable Limit
MSHA = Mine Safety and Health Administration
NAP = Not Applicable
NAV = Not Available
NIOSH = National Institute for Occupational Safety and Health
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16. Additional Information (cont鈥檇.)
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation and Recovery Act
STEL = Short-Term Exposure Limit (15 minutes)
TCLo = Lowest concentration in air resulting in a toxic effect
TDG = Canadian Transportation of Dangerous Goods
TDLo = Lowest dose resulting in a toxic effect
TLV = Threshold Limit Value
TSCA = Toxic Substance Control Act
TWA = Time-Weighted Average (8 hours)
UFL = Upper Flammable Limit
WHMIS = Workplace Hazardous Materials Information System
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