Material Safety Data Sheet
Flexo Printing Enhancer
Weyerhaeuser Company Emergency Phone: (253) 924-5000
PO Box 9777 Additional Information: (253) 924-3865
Federal Way, WA 98063-9777 CHEMTREC: (800) 424-9300
http://www.weyerhaeuser.com/environment/msds/default.asp Revised Date: April 1, 2005
1. Product Identification
Product Manufacturing Location(s)
Estimate Number: F16001400 Specialty Products Division
Ink Additive Description: Flexo Printing Enhancer Oregon Ink Plant
5570 SW Western Avenue; Beaverton, OR 97005
(503) 644-8125 (information)
Product Synonyms: Flexo Printing Enhancer-37, Printing Ink Additive
2. Hazardous Ingredients/Identity Information
Name CAS# Percent Agency Exposure Limits Comments
Ethylene Glycol Monoethyl 111-90-0 95-100% OSHA-PEL Not Established
Ether ACGIH-TLV Non Established
(Chemical Synonyms:
Diethylene glycol ethyl ether;
Ethanol, 2-(2-Ethoxyethoxy);
Carbitol; Diglycol monoethyl
ether; Ethanol, 2,2-oxybis-,
monoethyl ether; Ethoxy
diglycol; Carbitol; Carbitol
cellusolve; Ethyl diethylene
glycol; Ethyl digol; Ethylene
diglycol monoethyl ether;
solvolsol)
3. Hazard Identification
Appearance and Odor: Colorless liquid with a mild odor.
Primary Health Hazards: Eye and respiratory irritant. May be harmful or fatal if swallowed.
Primary Route(s) of Exposure:
Ingestion: Not a likely source of exposure.
Skin: Mild skin irritation. Prolonged or repeated contact may result in slight skin irritation.
Inhalation: Not a likely source of exposure. Avoid prolonged inhalation of mist or vapors. This
product has a low vapor pressure and is not expected to present an inhalation hazard at ambient
conditions. A hazard due to inhalation may exist in circumstances when handled hot or where
agitation or other mechanical operations may create an excessive fog or heavy mist. Caution
should be taken to prevent aerosolization or misting of this product.
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3. Hazard Identification (cont鈥檇.)
Eye: Slight eye irritation. This product has a low vapor pressure and is not expected to present a
hazard to the eyes at ambient conditions. Exposure to droplets mists and vapors may be irritating
to the eyes.
Medical Conditions Generally Aggravated by Exposure: Dermatitis, kidney disorders (edema or
proteinuria).
Signs and Symptoms of Exposure:
Acute Health Hazards: Slight eye irritant.
Chronic Health Hazards: Kidney 鈥? renal failure and CNS depressant.
Carcinogenicity Listing:
NTP: Not Listed
IARC Monographs: Not Listed
OSHA Regulated: Not Listed
4. Emergency and First-Aid Procedures
Ingestion: If swallowed, give two glasses of water (pint/0.5 liter) if victim completely conscious/alert. Do
not induce vomiting unless directed to do by medical personnel. Seek medical attention if symptoms
develop. Provide copy of MSDS to medical personnel.
Eye Contact: Flush with water to remove. Seek medical attention if irritation or discomfort persists.
Skin Contact: Immediately remove contaminated clothing. Wash skin with mild soap and water. Seek
medical assistance if irritation or discomfort persists. Provide copy of this MSDS to medical
personnel.
Skin Absorption: Not expected to occur. Wash with soap and water.
Inhalation: Remove to fresh air. Seek medical assistance if persistent irritation, severe coughing, or
breathing difficulty occurs. Provide copy of this MSDS to medical personnel.
Note to Physician: This material, if aspirated into the lungs, may cause chemical pneumonitis.
Treatment of over-exposure should be directed at the control of symptoms and the clinical condition
of the patient.
5. Fire and Explosion Data
Flash Point (Method Used): 187掳 F / 86掳 C Combustible Liquid
LFL = 1.2% UFL = 23.5
Flammable Limits:
Extinguishing Media: Foam, dry chemical, and carbon dioxide.
Autoignition Temperature: 400掳 F / 204掳 C
Special Firefighting Procedures: Self-contained breathing apparatus and protective clothing should be
worn in chemical fires. Water may be ineffective, serving only to spread product, but may be used to
cool containers.
Unusual Fire and Explosion Hazards: This product is a combustible liquid. It is recommended that
containers be tightly closed and isolated from heat, electrical equipment, and flame. A closed
container could possibly explode when exposed to extreme heat.
Health = 1 Fire = 2 Reactivity = 0 B
HMIS Rating (Scale 0-4): PPE =
Health = 1 Fire = 1 Reactivity = 0
NFPA Rating (Scale 0-4):
6. Accidental Release Measures
Steps to be Taken In Case Material Is Released or Spilled: Dike and contain spill with absorbent
material such as clay or other commercially available material. Place in container for disposal. Wear
safety glasses and chemical resistant gloves to minimize exposure.
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7. Handling and Storage
Precautions to be Taken In Handling and Storage: Follow standard industrial practices when handling
this product or empty containers. Avoid getting product on skin, eyes, or clothing. If contact with the
product occurs, remove effected clothing and wash with soap and water. Store in a cool, dry, well
ventilated area away from incompatible materials. Avoid excessive hot or cold temperatures. Keep
containers tightly closed when not in use.
8. Exposure Control Measures, Personal Protection
Personal Protective Equipment:
RESPIRATORY PROTECTION 鈥? Under normal conditions of use, respiratory protection is not required.
If a fog or mist is produced, use NIOSH approved respirator with organic vapor absorbing cartridges.
The respirator program must comply with OSHA and ANSI standards.
EYE PROTECTION 鈥? Chemical safety glasses recommended.
PROTECTIVE GLOVES 鈥? Chemically resistant gloves are recommended.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT 鈥? Eye wash station.
WORK/HYGIENE PRACTICES 鈥? Wash hands before eating, drinking, smoking, and at the end of the
shift.
Ventilation:
LOCAL EXHAUST 鈥? If handling results in mist or aerosols local exhaust ventilation may be needed so
that exposure limits are met.
MECHANICAL (GENERAL) 鈥? Provide general ventilation in processing and storage areas so that
exposure limits are met.
SPECIAL 鈥? None
OTHER 鈥? None
9. Physical/Chemical Properties
Physical Description: Colorless liquid with a mild odor
> 385掳 F (> 196掳 C)
Boiling Point (@ 760 mm Hg):
NAV
Evaporation Rate (Butyl acetate = 1):
- 54掳 C (-65掳 F)
Freezing Point:
-76掳 C (-105掳 F)
Melting Point:
C6H14O3
Molecular Formula:
134.7
Molecular Weight:
-0.15 as Log Pow (estimated)
Oil-water Distribution Coefficient:
NAV
Odor Threshold:
NAV
pH:
100% (miscible in water at 20掳 C)
Solubility in Water (% by weight):
1.0
Specific Gravity (H2O = 1):
4.64
Vapor Density (air = 1; 1 atm):
0.126 mmHg at 77 潞F (25 潞C)
Vapor Pressure (mm Hg):
8.34
Density (pounds/gallon)
3.9 cP at 77掳 F (25掳 C)
Viscosity:
% Volatile by Volume [@ 70oF (21oC)]: NAV
Wt% VOC: 100%; 8.24lb./gal; 8.24 lb/gal (less water)
Volatile Organic Compounds (VOC鈥檚; %wt):
Wt% HAPs: 100%
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10. Stability and Reactivity
Stability: Unstable Stable
Conditions to Avoid: High temperatures and freezing conditions.
Incompatibility (Materials to Avoid): Strong oxidizing agents, strong acids, acid chlorides, acid
anhydrides.
Hazardous Decomposition or By-Products: Carbon dioxide and carbon monoxide may form when
heated to decomposition. May produce acrid smoke and irritating fumes when heated to
decomposition.
Hazardous Polymerization: May occur Will not occur
Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: None
11. Toxicological Information
Toxicity Data: Diethylene glycol monoethyl ether LD 50 oral-rat: 8690 mg/kg, slightly toxic; LD 50 skin-
rat: 600 mg/kg. Non-rodent studies have found that using a 100-fold margin of safety, an acceptable
daily intake for human is 2.1 ml/day (approximately 2.1 g/day) for a 70 kg person.
Target Organs: Kidneys
12. Ecological Information
Environmental Fate: Diethylene glycol monoethyl ether will have very high mobility in soil. Volatilization
from moist soil surfaces should not occur. Volatilization may be significant from dry soil surfaces
based on the vapor pressure of this compound. In water, diethylene glycol monoethyl ether is not
expected to adsorb to sediment or particulate matter. This compound is not expected to volatilize
from water surfaces. Vapor-phase diethylene glycol monoethyl ether is degraded in the atmosphere
by reaction with photochemically-produced hydroxyl radicals with a half-life of about 12 hours.
Bioconcentration in aquatic organisms is expected to be low based on an estimated BCF value of 0.2.
Environmental Toxicity: Diethylene glycol monoethyl ether LC50 fathead minnow 26 .5 g/l 96-hour.
13. Disposal Considerations
Waste Disposal Method: This material, if discarded is not expected to be a RCRA hazardous waste. In
liquid form, this product may be determined to be a 鈥渟pecial鈥? waste. Dispose of material in
accordance with local, state, and federal regulations
14. Transport Information
Mode: (Air, Land, water)
Not Regulated
Proper Shipping Name:
Not Regulated
Hazard Class:
Not Regulated
UN/NA ID Number:
Not Regulated
Packing Group:
Not Regulated
Information Reported for Product/Size:
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15. Regulatory Information
TSCA: Diethylene glycol monoethyl ether is listed.
CERCLA: Diethylene glycol monoethyl ether is not subject to reporting requirements.
DSL: Diethylene glycol monoethyl ether is listed.
STATE RIGHT-TO-KNOW: This product is known to contain substances subject to the disclosure
requirements of:
California: This product does not contain substances identified on the Proposition 65 list at levels that
pose a significant risk for purposes of Section 25249.10(c) or result in an observable effect for
purposes of Section 25249.10(c) of the Act.
Minnesota: Hazardous Substance List 鈥? NAP
New Jersey: This product does not contain a substance identified on New Jersey鈥檚 environmental
hazardous substance list.
Pennsylvania: This product does not contain substances identified on Pennsylvania鈥檚 environmental
hazardous substance list.
SARA 313 Information: This product does not contain a substance that exceeds the De Minims
reporting levels established by SARA Title III, section 313 and 40-CFR 372.
SARA 311/312 Hazard Category: This product has been reviewed according to the EPA "Hazard
Categories" promulgated under SARA Title III Sections 311 and 312 and is considered, under
applicable definitions, to meet the following categories:
An immediate (acute) health hazard Yes
A delayed (chronic) health hazard No
A corrosive hazard No
A fire hazard No
A reactivity hazard No
A sudden release hazard No
FDA: This product is not intended to be ingested.
WHMIS Classification: This product contains diethylene glycol monoethyl ether which carries a WHIMS
classification as B3 combustible liquid and D2B, toxic material causing other toxic effects. The MSDS
contains all other information required by the Controlled Products Regulations.
CONEG: This product is certified to be in full compliance with CONEG Model Legislation for packaging
and packaging ink components
16. Additional Information
Date Prepared: 04/01/2005
Date Revised: N/A
Prepared By: Weyerhaeuser Company Corporate Environment, Health & Safety
Weyerhaeuser MSDS available on: http://www.weyerhaeuser.com/environment/msds/default.asp
User鈥檚 Responsibility: The information contained in this Material Safety Data Sheet is based on the
experience of occupational health and safety professionals and comes from sources believed to be
accurate or otherwise technically correct. It is the user鈥檚 responsibility to determine if the product is
suitable for its proposed application(s) and to follow necessary safety precautions. The user has the
responsibility to make sure that this MSDS is the most up-to-date issue.
Definition of Common Terms:
ACGIH = American Conference of Governmental Industrial Hygienists
C = Ceiling Limit
CAS# = Chemical Abstracts System Number
DOT = U. S. Department of Transportation
DSL = Domestic Substance List
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16. Additional Information (cont鈥檇.)
EC50 = Effective concentration that inhibits the endpoint to 50% of control population
EPA = U.S. Environmental Protection Agency
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LC50 = Concentration in air resulting in death to 50% of experimental animals
LCLo = Lowest concentration in air resulting in death
LD50 = Administered dose resulting in death to 50% of experimental animals
LDLo = Lowest dose resulting in death
LEL = Lower Explosive Limit
LFL = Lower Flammable Limit
MSHA = Mining Safety and Health Administration
NAP = Not Applicable
NAV = Not Available
NIOSH = National Institute for Occupational Safety and Health
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation and Recovery Act
STEL = Short-Term Exposure Limit (15 minutes)
TCLo = Lowest concentration in air resulting in a toxic effect
TDG = Canadian Transportation of Dangerous Goods
TDLo = Lowest dose resulting in a toxic effect
TLV = Threshold Limit Value
TSCA = Toxic Substance Control Act
TWA = Time-Weighted Average (8 hours)
UFL = Upper Flammable Limit
WHMIS = Workplace Hazardous Materials Information System
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