Material Safety Data Sheet
Flexo Slow Dry I
Weyerhaeuser Company Emergency Phone: (253) 924-5000
PO Box 9777 Additional Information: (253) 924-3865
Federal Way, WA 98063-9777 CHEMTREC: (800) 424-9300
http://weyerhaeuser.com/environment/msds/default.asp Revised Date: September 26, 2006
1. Product Identification
Product Manufacturing Location(s)
Estimate Number: F16001500 Specialty Products Division
Ink Additive Description: Flexo Slow Dry Oregon Ink Plant
5570 SW Western Avenue; Beaverton, OR 97005
(503) 644-8125 (information)
Ohio Ink Plant
865 Pittsburgh Drive; Delaware, OH 43015
(740) 363-9882
Product Synonyms: Flexo Ink Additive, Product Number 033, Flexo Slow Dry Agent.
2. Hazardous Ingredients/Identity Information
Name CAS# Percent Agency Exposure Limits Comments
Diethylene Glycol 111-46-6 100% OSHA Non Established Hazardous 鈥? toxic if
ACGIH swallowed
Synonyms:
Diglycol, Glycol Ether,
Ethylene diglycol,
Glycol Ethyl Ether,
DEG, Bis(Beta-
Hydroxyethyl) Ether, 2-
ethoxyethyl ether
3. Hazard Identification
Appearance and Odor: Clear liquid with mild odor.
Primary Health Hazards: Very toxic if swallowed.
Primary Route(s) of Exposure:
Ingestion: While not a likely source of exposure, diethylene glycol is considered toxic with irreversible
effects if swallowed. May also causes drowsiness and dizziness.
Skin: Moderate irritant, brief direct contact is harmless. Prolonged and/or repeated contact may
cause irritation, redness, burning, drying, and cracking of the skin.
Inhalation: Due to low vapor pressure inhalation is not a likely source of exposure unless heated.
Where fogs or mists are created, the product may cause irritation.
Eye: Moderately irritating to eyes.
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3. Hazard Identification (cont鈥檇.)
Medical Conditions Generally Aggravated by Exposure: Persons with pre-existing skin disorders or
eye problems or impaired liver or kidney function may be more susceptible to the effects of the
substance.
Signs and Symptoms of Exposure:
Acute Health Hazards: NAP
Chronic Health Hazards: Liver and kidney lesions and damage.
Carcinogenicity Listing:
NTP: Not Listed
IARC Monographs: Not Listed
OSHA Regulated: Not Listed
4. Emergency and First-Aid Procedures
Ingestion: Do not delay. If swallowed, give two glasses of water (pint/0.5 liter) if victim completely
conscious/alert. Do not induce vomiting unless directed to do by medical personnel. Seek medical
attention if symptoms develop. Provide copy of MSDS to medical personnel.
Eye Contact: Flush with water to remove. Seek medical attention if irritation or discomfort persists.
Skin Contact: Immediately remove contaminated clothing. Wash skin with mild soap and water. Seek
medical assistance if irritation or discomfort persists. Provide copy of MSDS to medical personnel.
Skin Absorption: Not expected to occur. Wash with soap and water.
Inhalation: Remove to fresh air. Seek medical assistance if persistent irritation, severe coughing, or
breathing difficulty occurs. Provide copy of MSDS to medical personnel.
Note to Physician: May cause significant renal respiratory, and CNS toxicity. May cause significant
acidosis.
5. Fire and Explosion Data
Flash Point (Method Used): 225掳F Closed Cup
LFL = 1.7% UFL = 10.6%
Flammable Limits:
Extinguishing Media: Alcohol resistant foam, water, dry chemical powder, carbon dioxide.
Autoignition Temperature: 444掳F/229掳C
Special Firefighting Procedures: Self-contained breathing apparatus and protective clothing should be
worn in chemical fires. Water may be ineffective, serving only to spread product, but may be used to
cool containers.
Unusual Fire and Explosion Hazards: Material is aqueous and is not expected to burn. If heated,
carbon monoxide may be evolved. It is recommended that containers be tightly closed and isolated
from heat, electrical equipment, and flame. A closed container could possibly explode when exposed
to extreme heat.
Health = 2 Fire = 1 Reactivity = 0 B
HMIS Rating (Scale 0-4): PPE =
Health = 1 Fire = 1 Reactivity = 0
NFPA Rating (Scale 0-4):
6. Accidental Release Measures
Steps to be Taken In Case Material Is Released or Spilled: Dike and contain spill with absorbent
material such as clay or other commercially available material. Place in container for disposal. Wear
safety glasses and chemical resistant gloves to minimize exposure. Ventilate contaminated area
thoroughly.
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7. Handling and Storage
Precautions to be Taken In Handling and Storage: Follow standard industrial practices when handling
this product or empty containers. Avoid getting product on skin, eyes, or clothing. If contact with the
product occurs, remove effected clothing and wash with soap and water. Store in a cool, dry, well
ventilated area away from incompatible materials. Avoid excessive hot or cold temperatures. Keep
containers tightly closed when not in use. Stainless steel, mild steel, and carbon steel are
recommended materials for product storage.
8. Exposure Control Measures, Personal Protection
Personal Protective Equipment:
RESPIRATORY PROTECTION 鈥? Under normal conditions of use, respiratory protection is not required.
If a fog or mist is produced, use NIOSH/MSHA approved respirator with organic vapor absorbing
cartridges. The respirator program must comply with OSHA and ANSI standards.
EYE PROTECTION 鈥? Chemical safety glasses recommended.
PROTECTIVE GLOVES 鈥? Chemically resistant gloves are recommended.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT 鈥? Eye wash station.
WORK/HYGIENE PRACTICES 鈥? Wash hands before eating, drinking, smoking, and at the end of the
shift.
Ventilation:
LOCAL EXHAUST 鈥? Provide local exhaust as needed to limit exposure.
MECHANICAL (GENERAL) 鈥? Provide general ventilation in processing and storage areas to limit
exposures.
SPECIAL 鈥? None
OTHER 鈥? None
9. Physical/Chemical Properties
Physical Description: Clear liquid with mild odor.
Boiling Point (@ 760 mm Hg): 472掳F
< 0.0011
Evaporation Rate (Butyl acetate = 1):
Freezing Point: -10掳C / 14掳F
Melting Point: -10掳C / 14掳F
CH20HCH2OCH2 CH2OH
Molecular Formula:
106.12
Molecular Weight:
NAV
Oil-water distribution coefficient:
Not Determined
Odor threshold:
NAV
pH:
100% - completely soluble
Solubility in Water (% by weight):
1.0 鈥? 1.2
Specific Gravity (H2O = 1):
3.7
Vapor Density (air = 1; 1 atm):
Vapor Pressure (mm Hg): < 1.3 Pa at 20掳C
20-35 seconds (#2 Zahn cup)
Viscosity:
% Volatile by Volume [@ 70oF (21oC)]: 100%
9.33
Density (lb/gal):
Volatile Organic Compounds (VOC鈥檚; %wt): 100%
10. Stability and Reactivity
鈱? Stable
Stability: Unstable
Conditions to Avoid: High temperatures and freezing conditions.
Incompatibility (Materials to Avoid): Strong bases or oxidizing or reducing agents. Strong Acids.
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10. Stability and Reactivity (cont鈥檇.)
Hazardous Decomposition or By-Products: Carbon monoxide, carbon dioxide, and oxides of nitrogen.
鈱? Will not occur
Hazardous Polymerization: May occur
Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: None
11. Toxicological Information
Toxicity Data: Oral rat LD50: 12565 mg/kg. Skin rabbit LD50: 11.89 g/kg Irritation: eye rabbit, standard
Draize: 50 mg mild. There is a significant difference in acute oral toxicity between animals and man,
with man being more susceptible than animals. The estimated fatal oral dose for man is 100
milliliters (1/2 cup)
Components: NAP
Target Organs: Kidney damage based on repeated dose toxicity. Tumors produced in animals are not
considered relevant to humans.
12. Ecological Information
Environmental Fate: If released to soil, diethylene glycol is expected to have very high mobility.
Volatilization of diethylene glycol is not expected to be important from moist or dry soil surfaces.
Diethylene glycol will not be susceptible to direct photolysis on soil surfaces based on its absorption
of light at wavelengths >290 nm. According to a biodegradation study conducted in a sandy loam,
diethylene glycol is expected to biodegrade quickly in soil. If released to water, diethylene glycol is
not expected to adsorb to suspended solids and sediment. Diethylene glycol will be essentially non-
volatile from water surfaces. Bioconcentration of diethylene glycol is expected to be low in aquatic
organisms. Although biodegradation test results vary, biodegradation of diethylene glycol is expected
be an important fate process in water. If released to the atmosphere, diethylene glycol will exist as a
vapor based on its vapor pressure. Vapor-phase diethylene glycol is degraded in the atmosphere by
reaction with photochemically produced hydroxyl radicals with an estimated half-life of about 13
hours.
Environmental Toxicity:
Fish: Low toxicity: LC/EC/IC50 > 1000 mg/l
Aquatic Vertebrates: Low toxicity: LC/EC/IC50 > 1000 mg/l
Algae: Expected to have low toxicity Low toxicity: LC/EC/IC50 > 1000 mg/l
13. Disposal Considerations
Waste Disposal Method: Check with your local sewer authority before disposing to sewer. This
material is not a RCRA hazardous waste. In liquid form, this product may be determined to be a
鈥渟pecial鈥? waste. Dispose of material in accordance with local, state, and federal regulations
14. Transport Information
Mode: (Air, Land, water) Not regulated as a hazardous material by the U.S. Department of
Transportation. This material is not subject to DOT regulations under 49 CFR Parts 171-180
NAP
Proper Shipping Name:
NAP
Hazard Class:
NAP
UN/NA:
Not a regulated product.
TDG:
NAP
Packing Group:
NAP
Information Reported for Product/Size:
NAP
USDOT Shipping Classification:
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15. Regulatory Information
TSCA: All ingredients of this product are listed.
CERCLA: Product ingredients are not subject to reporting requirements of CERCLA
DSL: All ingredients of this product are listed.
STATE RIGHT-TO-KNOW:
California 鈥? Prop 65 - This product does not contain substances identified on the Proposition 65 list at
levels that pose a significant risk for purposes of Section 25249.10(c) or result in an observable effect
for purposes of Section 25249.10(c) of the Act.
Minnesota 鈥? Hazardous Substance List - NAP
New Jersey 鈥? This product does not contain a substance identified on New Jersey鈥檚 environmental
hazardous substance list.
Pennsylvania 鈥? This product contains diethylene glycol a substance identified on Pennsylvania鈥檚
environmental hazardous substance list.
SARA 313 Information: This product does not contain any chemical components with known CAS
numbers that exceed the De Minimis reporting levels established by SARA Title III, Section 313 and
40 CFR Part 372.
SARA 311/312 Hazard Category: This product has been reviewed according to the EPA "Hazard
Categories" promulgated under SARA Title III Sections 311 and 312 and is considered, under
applicable definitions, to meet the following categories:
An immediate (acute) health hazard Yes
A delayed (chronic) health hazard No
A fire hazard No
A reactivity hazard No
A sudden release hazard No
FDA: This product complies with the Food and Drug Administration (FDA) requirements found in 21 CFR
搂 175. These regulations indicate that adhesives, inks, and related materials may be safely used for food
packaging purposes, when they are separated by a functional barrier that prevents migration of the
material into the food (Indirect Food Contact).
WHMIS Classification: Product does not meet WHMIS hazard classification criteria. The MSDS
contains all other information required by the Controlled Products Regulations.
CONEG: This product is certified to be in full compliance with CONEG Model Legislation for packaging
and packaging ink components.
16. Additional Information
Date Prepared: 08/20/04
Date Revised: 09/26/2006
Prepared By: Weyerhaeuser Corporate Environment, Health & Safety
Weyerhaeuser MSDS available on: http://weyerhaeuser.com/environment/msds/default.asp
User鈥檚 Responsibility: The information contained in this Material Safety Data Sheet is based on the
experience of occupational health and safety professionals and comes from sources believed to be
accurate or otherwise technically correct. It is the user鈥檚 responsibility to determine if the product is
suitable for its proposed application (s) and to follow necessary safety precautions. The user has the
responsibility to make sure that this sheet is the most up-to-date issue.
Definition of Common Terms:
ACGIH = American Conference of Governmental Industrial Hygienists
C = Ceiling Limit
CAS# = Chemical Abstracts System Number
DOT = U. S. Department of Transportation
DSL = Domestic Substance List
EC50 = Effective concentration that inhibits the endpoint to 50% of control population
EPA = U.S. Environmental Protection Agency
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16. Additional Information (cont鈥檇.)
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LC50 = Concentration in air resulting in death to 50% of experimental animals
LCLo = Lowest concentration in air resulting in death
LD50 = Administered dose resulting in death to 50% of experimental animals
LDLo = Lowest dose resulting in death
LEL = Lower Explosive Limit
LFL = Lower Flammable Limit
MSHA = Mine Safety and Health Administration
NAP = Not Applicable
NAV = Not Available
NIOSH = National Institute for Occupational Safety and Health
NPRI = Canadian National Pollution Release Inventory
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation and Recovery Act
STEL = Short-Term Exposure Limit (15 minutes)
STP = Standard Temperature and Pressure
TCLo = Lowest concentration in air resulting in a toxic effect
TDG = Canadian Transportation of Dangerous Goods
TDLo = Lowest dose resulting in a toxic effect
TLV = Threshold Limit Value
TSCA = Toxic Substance Control Act
TWA = Time-Weighted Average (8 hours)
UFL = Upper Flammable Limit
WHMIS = Workplace Hazardous Materials Information System
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