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MSDS Material Safety Data Sheet
CAS

13782-33-7

File Name: jmcatalysts_com---448.asp
                                     SAFETY DATA SHEET
PD-02 TRANS-DIAMMINEDICHLOROPALLADIUM(II)
170224 2.00 EC Current 10.08.1999

1. PRODUCT AND COMPANY IDENTIFICATION
170224
Product Code
PD-02 TRANS-DIAMMINEDICHLOROPALLADIUM(II)
Trade Name
13782-33-7
CAS Number
2374373
EINECS Number
1
JM Version Number
25/11/91
Date of First Issue
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number

2. COMPOSITION/INFORMATION ON THE COMPONENTS
100% trans-diamminedichloropalladium(II) trans-Pd(NH鈥?)沤Cl沤.
Composition

3. HAZARD IDENTIFICATION
The trans isomer is non-irritating to the skin and non-toxic to abraded skin. However, solutions of the chemical in organic
solvents able to penetrate the skin may show enhanced toxicity. Reaction products and decomposition products, such as
palladium dichloride, may be skin irritants and cause dermatitis. On heating, the material decomposes above 200掳C, giving
toxic fumes and leaving a palladium residue.

4. FIRST AID MEASURES
Symptoms of overexposure may include the following-
Inhalation - irritation of the respiratory tract.
Ingestion - nausea, vomiting, abdominal pain and diarrhoea.
Eye contact - redness and irritation.
Skin contact - possible irritation and dermatitis.

First-aid treatment for acute overexposure.

remove from exposure and allow to rest in fresh air. Seek medical attention.
First Aid - Inhalation
rinse mouth with clean water and give water or milk to drink. Seek medical
First Aid - Ingestion
attention.
irrigate with water or isotonic saline solution for 15 minutes. Seek medical
First Aid - Eyes
attention.
remove contaminated clothing and wash skin with soap and water. If
First Aid - Skin
symptoms persist, seek medical attention.Launder clothing before re-use.


5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if involved in a fire. The residue, ash or char left after a
fire may have catalytic properties and may promote the re-ignition of flammable materials and vapours. Wear self-contained
breathing apparatus and personal protective equipment. Use any extinguisher suitable for the surrounding fire.

6. ACCIDENTAL RELEASE MEASURES
Wearing personal protective equipment, (see section 8), collect up the spillage and store in a suitable, sealed container.
Wash the site of the spillage with large volumes of water. Do not allow wash water to enter natural water courses.


MSDS_EC Page 1 of 4
SAFETY DATA SHEET
PD-02 TRANS-DIAMMINEDICHLOROPALLADIUM(II)
170224 2.00 EC Current 10.08.1999

7. HANDLING AND STORAGE
Handling (JM)
Local exhaust extraction should be used and protective clothing, including gloves and eye protection should be worn. Do not
eat, drink, smoke or apply cosmetics whilst handling.
Storage (JM)
Store in an air-tight container in a cool, dry place.


8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No Occupational Exposure Limit, MAK or TLV has been established for this material. If a risk of inhalation exists, users should
wear an appropriate filter type respirator. Alternatively, local exhaust extraction should be used. Suitable eye protection and
chemical resistant gloves should be worn. Vapour and fumes from all operations should be vented to external atmosphere via
a suitable collection or scrubbing system. Wash hands after using this material.

9. PHYSICAL AND CHEMICAL PROPERTIES
mustard-yellow coloured crystals or powder.
Appearance
No odour.
Odour
not applicable
pH
not applicable.
Boiling Range/Point
stable to 200掳C, but decomposes above 210掳C.
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
2.5 gm/cc.
Density
Water - Sparingly soluble in water. Soluble in aqueous ammonia.
Solubility in Water
Soluble in acids, with decomposition.
Insoluble in chloroform or acetone.
Fat - no data.
no data.
Partition Coefficient

10. STABILITY AND REACTIVITY
The material is supplied in a stable condition and no reactive hazards are known.


12. ECOLOGICAL INFORMATION
No ecological hazards are known and this material is not thought to present a significant hazard.


14. TRANSPORT INFORMATION
Not restricted.


15. REGULATORY INFORMATION
Xn - Harmful
EC Annex I Classification



MSDS_EC Page 2 of 4
SAFETY DATA SHEET
PD-02 TRANS-DIAMMINEDICHLOROPALLADIUM(II)
170224 2.00 EC Current 10.08.1999

15. REGULATORY INFORMATION (continued)
R20/22 Harmful by inhalation and if swallowed.
R phrases
S25 Avoid contact with eyes.
S phrases

16. OTHER INFORMATION
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0181 8048111,
Fax:- 0181 8041918

S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061

Johnson Matthey S.A., Vallespir, 193-195, 08014 BARCELONA, Espa帽a, Tel:- (93) 490 86 86, Fax:- (93) 490 68 98

Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01

Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733

Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674

Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02

Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807

Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795

Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933

Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701

Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12

REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health.
USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation.
Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.


MSDS_EC Page 3 of 4
SAFETY DATA SHEET
PD-02 TRANS-DIAMMINEDICHLOROPALLADIUM(II)
170224 2.00 EC Current 10.08.1999

16. OTHER INFORMATION (continued)
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets. JMAC Approved applications -

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed.




MSDS_EC Page 4 of 4

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