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MSDS Material Safety Data Sheet
CAS

14286-02-3

File Name: jmcatalysts_com---449.asp
                              Johnson Matthey
DIAMMINEDINITROPLATINUM(II) IN AQUEOUS SUSPENSION
155061 1.00 EC Current 30.07.1999

1. PRODUCT AND COMPANY IDENTIFICATION
155061
Product Code
DIAMMINEDINITROPLATINUM(II) IN AQUEOUS SUSPENSION
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
Dinitrodiammineplatinum(II), Pt(NH鈥?)沤(NO沤)沤 in aqueous suspension.
Composition
This material is supplied as a 10% approx. suspension.
1
JM Version Number
25/03/93
Date of First Issue

2. COMPOSITION/INFORMATION ON THE COMPONENTS
DIAMMINEDINITROPLATINUM(II) IN AQUEOUS SUSPENSION
Product Formal Name
.Not Specified
Product Chemical Family
14286-02-3
CAS Number

3. HAZARD IDENTIFICATION
This Platinum ammine complex is thought to be of low acute toxicity, and by
analogy with the corresponding Palladium compound is thought to be non-
irritating to the skin but a positive eye irritant. It is not thought to be a sensitizer.
As a dry solid this material is explosive and is readily ignitable, sensitive to
friction and deflagrates in a similar manner to gun powder.
DO NOT allow this material to dry out.

4. FIRST AID MEASURES
Over-exposure may produce the following acute symptoms -
First Aid
Ingestion - Nausea and vomiting.
Inhalation - Irritation of the respiratory tract.
Eye contact - Redness and irritation.

Remove from exposure and allow to rest in fresh air. Seek medical advice if
First Aid - Inhalation
symptoms persist.
Rinse mouth with clean water and give milk or water to drink. Seek medical
First Aid - Ingestion
advice.
Irrigate with clean water or isotonic saline for 10 minutes. Seek medical attention
First Aid - Eyes
if symptoms persist.
Skin : Remove contaminated clothing. Wash skin with soap and water.
First Aid - Skin

5. FIRE FIGHTING MEASURES
This material is not flammable. If involved in a fire it may decompose producing
toxic fumes. Alternatively, if the material has dried without decomposition, it may
explode in a manner similar to gun powder.
Fire fighters should wear self contained breathing apparatus and personel
protective equipment. Use any extinguishing medium suitable for the
surrounding fire. Containers of this material exposed to heat should be cooled by
water spray.

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Johnson Matthey
DIAMMINEDINITROPLATINUM(II) IN AQUEOUS SUSPENSION
155061 1.00 EC Current 30.07.1999

6. ACCIDENTAL RELEASE MEASURES
The liquid portion of this material should be absorbed in a suitable absorbant
medium. The solid portion should be collected up and stored, covered with
water, in a suitable sealed container.
Wash the site of spillage with large amounts of water, ensuring that no solid
remains and that none is allowed to dry out.

7. HANDLING AND STORAGE
Local exhaust extraction should be used and protective clothing, including gloves
Handling (JM)
and eye protection should be worn. Do not eat, drink, smoke or apply cosmetics
whilst handling.
Store in an air-tight container in a cool, dry place.
Storage (JM)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
The following exposure controls have been established for Platinum compounds
-

UK HSE MEL - Halogeno-platinum compounds,(as Pt) - 0.002 mg/m鈥?
UK HSE OES - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?
USA ACGIH TLV - Platinum, soluble salts (as Pt) - 0.002 mg/m鈥?
Germany MAK - Platinum compounds (total dust) - 0.002 mg/m鈥?
Denmark ELV - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?

If a risk of inhalation exists, users should wear an appropriate filter type
respirator. Suitable gloves and eye protection should also be worn.

9. PHYSICAL AND CHEMICAL PROPERTIES
White solid in suspension.
Appearance
No odour.
Odour
7 approx.
pH
no data.
Boiling Range/Point
no data.
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
As supplied not explosive, explosive as a dry compound.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
no data.
Density
Water - very slightly soluble.
Solubility in Water
Fat - no data.
no data.
Partition Coefficient

10. STABILITY AND REACTIVITY
Explosivity tests have shown that the DRY compound is readily ignitable,
sensitive to friction and deflagrates in a manner similar to gunpowder. Its' impact
sensitivity is greater than that for dinitrobenzene. The suspension as supplied is
not explosive.

11. TOXICOLOGICAL INFORMATION

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Johnson Matthey
DIAMMINEDINITROPLATINUM(II) IN AQUEOUS SUSPENSION
155061 1.00 EC Current 30.07.1999

11. TOXICOLOGICAL INFORMATION (continued)

There is no specific toxicological data available for this material. The following
data refers to the Palladium analogue -
LD50 (oral rat) 500 - 2000 mg/kg, Skin rabbit - mild irritant, Eye rabbit -
positive irritant.

12. ECOLOGICAL INFORMATION
No specific data is available for this material. Platinum impairs the reproduction
of Daphnids when present at very low levels. Do not allow this material to enter
natural watercourses.

13. DISPOSAL
Return accumulated waste material to the refinery for metal recovery, or dispose
of in accordance with local and national regulations.

14. TRANSPORT INFORMATION
Not restricted.


15. REGULATORY INFORMATION
DANGER, this product is explosive when dry, giving rise to a risk of explosion by
R phrases
shock, friction, fire or other sources of ignition.
S48 Keep wet with: S24/25 Avoid contact with skin and eyes.
S phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
2382033
EINECS Number
None.
EC Annex I Classification

16. OTHER INFORMATION
30 July 1999
MSDS first issued
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process. Such information is given in good faith, being based on the latest information available to
Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at the time of
preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or completness and Johnson
Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage or injury howsoever arising (
including in respect of any claim brought by any third party) incurred using this information. The product is supplied on thecondition
that the user accepts responsibility to satisfy himself as to the suitability and completness of such information for his own particular
use. Freedom from patent or any other proprietary rights of any third party must not be assumed.
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health. USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.

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Johnson Matthey
DIAMMINEDINITROPLATINUM(II) IN AQUEOUS SUSPENSION
155061 1.00 EC Current 30.07.1999

16. OTHER INFORMATION (continued)
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets. JMAC Approved applications -
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0181 8048111, Fax:-
0181 8041918

S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061

Johnson Matthey S.A., Vallespir, 193-195, 08014 BARCELONA, Espa帽a, Tel:- (93) 490 86 86, Fax:- (93) 490 68 98

Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01

Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733

Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674

Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22 99,
Fax:- 1 48 63 27 02

Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807

Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795

Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933

Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302 4701

Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96) 70
38 12


17. 000000000




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