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                                   Johnson Matthey
TETRAMMINE PLATINUM(II)CHLORIDE SOLUTION
184010 1.00 EC Current 30.07.1999

1. PRODUCT AND COMPANY IDENTIFICATION
184010
Product Code
TETRAMMINE PLATINUM(II)CHLORIDE SOLUTION
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
Tetrammine Platinum(II)chloride, Pt(NH ) Cl in aqueous solution.
Composition
The Platinum content is in the range 8 - 10%.
1
JM Version Number
31/03/93
Date of First Issue

2. COMPOSITION/INFORMATION ON THE COMPONENTS
TETRAMMINE PLATINUM(II)CHLORIDE SOLUTION
Product Formal Name
Product Chemical Family .Not Specified


3. HAZARD IDENTIFICATION
The Platinum ammino complex is of low acute toxicity if ingested. The
solution is irritating to the eyes and the skin. The solid compound does not
produce an allergenic (Type 1 sensitization) response and the solution is
assumed to be similar.
If this material is used to prepare other Platinum compounds, it should be
noted that ionic Platinum-halogeno compounds are normally highly allergenic.


4. FIRST AID MEASURES
First Aid Over-exposure may produce the following symptoms-
Inhalation- Irritation of the respiratory tract.
Eye contact- Redness and irritation.
Skin contact- Irritation. 聽 聽

Remove from exposure and allow to rest in fresh air. Seek medical advice if
First Aid - Inhalation
symptoms persist. 聽
Rinse mouth with clean water, give milk or water to drink. Seek medical
First Aid - Ingestion
advice if symptoms persist.
Irrigate with clean water or isotonic saline solution for 15 minutes.Seek
First Aid - Eyes
medical advice if symptoms persist. 聽
Remove contaminated clothes and wash skin with soap and water. 聽
First Aid - Skin

5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽

6. ACCIDENTAL RELEASE MEASURES
Evacuate non-protected personnel. Wear protective clothing, impervious
gloves, eye protection and filter-type respiratory protection when dealing with
spillages. Solid spills should be carefully collected into a sealable, plastic


\ Page 1
Johnson Matthey
TETRAMMINE PLATINUM(II)CHLORIDE SOLUTION
184010 1.00 EC Current 30.07.1999

6. ACCIDENTAL RELEASE MEASURES (continued)
lined drum. Solutions should be absorbed in sand or other inert absorbant
and carefully transferred to a plastic lined drum. The site of the spillage may
be treated with an aqueous solution of a reducing agent, to convert any
remaining platinum compounds to the metal. Store accumulated rags, wipes,
mops, sand, vermiculite etc. in suitably labelled containers for return to the
refinery for precious metal recovery. Afterwards, wash the site of the spillage
with copious amounts of water. If the spill has resulted in the dispersion of
dust through the air, the area must be decontaminated by thorough washing
with water. 聽 聽 聽

7. HANDLING AND STORAGE
Good industrial hygiene practices should be observed. Avoid direct contact.
Handling (JM)
Do not eat, drink, smoke or apply cosmetics whilst handling. Exposure to air-
borne particulates must be kept within permissible limits. Use only under
conditions of good local ventilation. 聽 聽 聽 聽 聽 聽
Keep in a secure store, in a sealed, plastic container, away from incompatible
Storage (JM)
materials such as reducing agents. 聽 聽 聽

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
The following exposure controls have been established for Platinum
compounds -

UK HSE MEL - Halogeno-platinum compounds,(as Pt) - 0.002 mg/m鈥?
UK HSE OES - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?
USA ACGIH TLV - Platinum, soluble salts (as Pt) - 0.002 mg/m鈥?
Germany MAK - Platinum compounds (total dust) - 0.002 mg/m鈥?
Denmark ELV - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?

If a risk of inhalation exists, users should wear an appropriate filter type
respirator. Suitable gloves and eye protection should also be worn. 聽

9. PHYSICAL AND CHEMICAL PROPERTIES
Colourless/very pale yellow solution.
Appearance
Slight ammoniacal.
Odour
6.5-8.0
pH
100掳C approximately.
Boiling Range/Point
Melting Point 0掳C approximately.
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
1.12gm/cc
Density
Solubility in Water Water - miscible
Fat - no data.
no data.
Partition Coefficient

10. STABILITY AND REACTIVITY
The material is supplied in a stable condition and no reactive hazards are
known.

11. TOXICOLOGICAL INFORMATION

\ Page 2
Johnson Matthey
TETRAMMINE PLATINUM(II)CHLORIDE SOLUTION
184010 1.00 EC Current 30.07.1999

11. TOXICOLOGICAL INFORMATION (continued)
There is no toxicological data available for this material. The following data
refers to the solid Platinum compound -
LD50 (oral rat) >15gm/kg, Eye rabbit - strong irritant. Skin rabbit - moderate
irritant. Magnusson and Kligman test - negative, no sensitization.
聽聽

12. ECOLOGICAL INFORMATION
The reproduction of daphnids is impaired (16%) by 0.014 ppm Pt in 3 weeks.
Hydrogen hexachloroplatinate is reported to be lethal to certain freshwater
species. The complex may persist for some time in the environment. 聽 聽

13. DISPOSAL
Return accumulated waste material to the refinery for metal recovery, or
dispose of in accordance with local and national regulations. 聽

14. TRANSPORT INFORMATION
Not restricted.


15. REGULATORY INFORMATION
R36 Irritating to eyes.
R phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and
S phrases
seek medical advice.
S39 Wear eye/face protection.
Xi - Irritant
EC Annex I Classification

16. OTHER INFORMATION
30 July 1999
MSDS first issued
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.


\ Page 3
Johnson Matthey
TETRAMMINE PLATINUM(II)CHLORIDE SOLUTION
184010 1.00 EC Current 30.07.1999

16. OTHER INFORMATION (continued)
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets. JMAC Approved applications -
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0181 8048111,
Fax:- 0181 8041918

S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061

Johnson Matthey S.A., Vallespir, 193-195, 08014 BARCELONA, Espa帽a, Tel:- (93) 490 86 86, Fax:- (93) 490 68 98

Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01

Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733

Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674

Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02

Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807

Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795

Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933

Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701

Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12


17. 000000000




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