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File Name: jmcatalysts_com---493.asp
                                SAFETY DATA SHEET
Tetrammine Palladium Sulfate
170234 Version Number 1.00

1. Identification of the substance/preparation and of the
company/undertaking
Identification of the substance or preparation
Product name : Tetrammine Palladium Sulfate
Chemical formula : Pd(NH3)4SO4
Company/undertaking identification
Manufacturer : Johnson Matthey Plc,
Orchard Road,
Royston,
Herts SG8 5HE
Emergency telephone number : 01763 253000

2. Composition/information on ingredients
Substance/preparation : Substance
Ingredient name CAS % EC Number Classification
number

Tetrammine Palladium Sulfate 100 Xn; R22
Xi; R36
See section 16 for the full text of the R Phrases
declared above
* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The substance is classified as dangerous according to Directive 67/548/EEC and its amendments.
Classification : Xn; R22
Xi; R36
Human health hazards : Harmful if swallowed.
Irritating to eyes.



See section 11 for more detailed information on health effects and symptoms.

4. First aid measures
First aid measures
Inhalation : If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing,
give artificial respiration. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Obtain medical attention.
Skin Contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated
clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before
reuse. Obtain medical attention if symptoms occur.
Eye contact : In case of contact, immediately flush eyes with a copious amount of water for at least
15 minutes. Obtain medical attention immediately.
See section 11 for more detailed information on health effects and symptoms.




Date of issue : 09/03/2005. Page: 1/4
Tetrammine Palladium Sulfate

5. Fire-fighting measures
Extinguishing media : Use an extinguishing agent suitable for surrounding fires.
Special exposure hazards : No specific hazard.
Hazardous thermal : These products are nitrogen oxides (NO, NO2...), sulphur oxides (SO2, SO3, etc.).
decomposition products Some metallic oxides.
Special protective : Fire fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Remark : The residue, ash or char left after a fire may have catalytic properties and may
promote the re-ignition of flammable materials and vapours.

6. Accidental release measures
Personal Precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (Section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up : If emergency personnel are unavailable vacuum or carefully scoop up spilled
materials and place in an appropriate container for disposal. Avoid creating dusty
conditions and prevent wind dispersal.

7. Handling and storage
Handling : Do not ingest. Avoid contact with eyes. Wash thoroughly after handling.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended : Use original container.

8. Exposure controls/personal protection
Exposure limit values : Not available.
Exposure controls
Occupational exposure : Use process enclosures, local exhaust ventilation, or other engineering controls to
controls keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard
if a risk assessment indicates this is necessary.Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Hand protection : Chemical-resistant, impervious gloves or gauntlets complying with an approved
standard should be worn at all times when handling chemical products if a risk
assessment indicates this is necessary.
Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product.

9. Physical and chemical properties
General information
Appearance
Physical state : Solid. (Crystalline solid.)
Colour : Yellow.
Important health, safety and environmental information
Solubility : Partially soluble in cold water.




Date of issue : 09/03/2005. Page: 2/4
Tetrammine Palladium Sulfate

10. Stability and reactivity
: The product is stable.
Stability

11. Toxicological information
Potential acute health effects
Ingestion : Harmful if swallowed.
Eye contact : Irritating to eyes.
Acute toxicity
Product/ingredient name Test Result Route Species
Tetrammine Palladium Sulfate LD50 455 mg/kg Oral Rat
similar material

12. Ecological information
Biodegradability Not available.
Other adverse effects : No known significant effects or critical hazards.
Not available.

13. Disposal considerations
Methods of disposal : Return accumulated waste material to the refinery for metal recovery, or dispose of in
accordance with local and national regulations.

14. Transport information
International transport regulations
Regulatory UN number Proper shipping name Class Packing group Label Additional
information Information

Not available. Not available. Not - -
ADR/RID Class
available.

Not available. Not available. Not - -
IMDG Class
available.
Not available. Not available. Not - -
IATA Class
available.


15. Regulatory information
EU Regulations
Hazard symbol(s) :




Harmful
Risk Phrases : R22- Harmful if swallowed.
R36- Irritating to eyes.
Safety Phrases : S22- Do not breathe dust.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
Contains : Tetrammine Palladium Sulfate Not available.
Product use : Classification and labelling have been performed according to EU directives
67/548/EEC, 1999/45/EC, including amendments and the intended use.
- Industrial applications.
Additional warning phrases : Caution - substance not yet fully tested.




Date of issue : 09/03/2005. Page: 3/4
Tetrammine Palladium Sulfate

16. Other information
Full text of R phrases : R22- Harmful if swallowed.
referred to in sections 2 and R36- Irritating to eyes.
3 - United Kingdom (UK)
Full text of classifications : Xn - Harmful
referred to in sections 2 and Xi - Irritant
3 - United Kingdom (UK)
History
Date of printing : 09/03/2005.
: 09/03/2005.
Date of issue
Date of previous issue : No Previous Validation.
Version : 0.01
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process. Such information is given in good faith, being based on the latest information available to Johnson Matthey PLC
and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at the time of preparation. However, no
representation, warranty or guarantee is made as to the accuracy, liability or completness and Johnson Matthey PLC assumes no
responsibility therefore, and disclaims any liability for any loss, damage or injury howsoever arising (including in respect of any claim
brought by any third party) incurred using this information. The product is supplied on the condition that the user accepts responsibility to
satisfy himself as to the suitability and completeness of such information for his own particular use. Freedom from patent or any other
proprietary rights of any third party must not be assumed.
Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)
Johnson Matthey National Sales Offices
Johnson Matthey .PLC Orchard Road, Royston Hertfordshire, SG8 5HE England Tel:+44(0)1763 253000 Fax: +44
(0)1763 253668
Johnson Matthey PLC 33 Jeffreys Road, Brimsdown, Enfield, Middlesex, EN3 7PW United Kingdom Tel: 0208 8048 8111
Fax: 020 8804 1918
Johnson Matthey& Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich Tel:877 98 90 Fax: 877 98 933
S.A. Johnson Matthey N.V 8 Avenue de Bale, 1140 Brussel,Belgi毛 / Belgique Tel:2 729 0711 Fax:2 216 9061
Johnson Matthey A/S Frederikssundsvej 274 D,Br垄nsh垄j 2700, Denmark Tel:38 89 62 00 Fax:38 89 62 01
Oy Johnson Matthey A.B Kielotie 7A 4KRS, 01300 Bantaa, Soumi Tel:08574 800 Fax: 08574 807
Johnson Matthey GmbH Alfa Products. Zeppelinstrasse 7, Postfach 6540,D-7500 Karlsruhe 1, Deutschland Tel:721
8400 70 Fax: 721 849674
Johnson Matthey SA 13 Rue de la Perdrix, Z1 Paris Nord 11, BP 50240, 95996 Roissy,CDG Cedix France Tel:1 48 63
22 99 Fax:1 48 63 27 02
Johnson Matthey GmbH Otto-Volger-Strasse 9B, D-65843 Sulzbach/Ts, Deutschland Tel:(0 61 96)70 38-21 Fax:(0 61
96)70 38 12
Johnson Matthey. PLC Unit 1-2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15 Republic
of Ireland Tel 1 820 7722 Fax:1 820 7733
Johnson Matthey A.B. Victor Hasselblads Gata 8, S-421 31 V盲stra Fr枚lunda, Sverige Tel:031 891390 Fax: 031 477795
Johnson Matthey & Brandenberger A.G. Glattalstrasse 18, CH-8052 Zurich, Switzerland Tel:01 307 1919 Fax:01 307
1920




Date of issue : 09/03/2005. Page: 4/4

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