Johnson Matthey
SODIUM HEXAHYDROXYPLATINATE(IV)
186185 1.00 EC Current 30.07.1999
1. PRODUCT AND COMPANY IDENTIFICATION
186185
Product Code
SODIUM HEXAHYDROXYPLATINATE(IV)
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
Sodium hexahydroxyplatinate(IV), Na Pt(OH)鈥?
Composition
1
JM Version Number
06/08/92
Date of First Issue
2. COMPOSITION/INFORMATION ON THE COMPONENTS
SODIUM HEXAHYDROXYPLATINATE(IV)
Product Formal Name
.Not Specified
Product Chemical Family
12325-31-4
CAS Number
3. HAZARD IDENTIFICATION
This material is harmful by ingestion and is a severe skin and eye irritant,
inhalation will produce irritation of the respiratory tract. It is not thought to be a
sensitizer, but users should note that, if ionic Platinum halogeno compounds
are prepared from this material, they will be highly allergenic.
Persons with a history of allergic diseases should not be exposed to Platinum
compounds. A history of cardiac or pulmonary disease may preclude
exposure to Platinum compounds - medical opinion should be sought. Any
person experiencing untoward effects or symptoms whilst using Platinum
compounds should be removed from exposure and medically examined for
Platinum sensitization. 聽 聽 聽 聽
4. FIRST AID MEASURES
First Aid Over-exposure may produce the following symptoms -
Inhalation - irritating to the eyes, nose, throat and respiratory tract, producing
coughing.
Ingestion - nausea and vomiting.
Eye contact - redness, irritation, blurred vision and pain.
Skin - redness and irritation with possible tissue damage. 聽 聽
remove from exposure and allow to rest in fresh air. Seek medical advice. 聽
First Aid - Inhalation
rinse mouth with clean water and give water or milk to drink. Seek medical
First Aid - Ingestion
attention.
irrigate with water or isotonic saline solution for 15 minutes. Seek medical
First Aid - Eyes
attention.
remove contaminated clothing and wash skin with soap and water. If
First Aid - Skin
symptoms persist or tissue damage is evident, seek medical attention.
Launder clothing before re-use. 聽
5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽
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Johnson Matthey
SODIUM HEXAHYDROXYPLATINATE(IV)
186185 1.00 EC Current 30.07.1999
6. ACCIDENTAL RELEASE MEASURES
Evacuate non-protected personnel. Wear protective clothing, impervious
gloves, eye protection and filter-type respiratory protection when dealing with
spillages. Solid spills should be carefully collected into a sealable, plastic
lined drum. Solutions should be absorbed in sand or other inert absorbant
and carefully transferred to a plastic lined drum. The site of the spillage may
be treated with an aqueous solution of a reducing agent, to convert any
remaining platinum compounds to the metal. Store accumulated rags, wipes,
mops, sand, vermiculite etc. in suitably labelled containers for return to the
refinery for precious metal recovery. Afterwards, wash the site of the spillage
with copious amounts of water. If the spill has resulted in the dispersion of
dust through the air, the area must be decontaminated by thorough washing
with water. 聽 聽 聽
7. HANDLING AND STORAGE
Good industrial hygiene practices should be observed. Avoid direct contact.
Handling (JM)
Do not eat, drink, smoke or apply cosmetics whilst handling. Exposure to air-
borne particulates must be kept within permissible limits. Use only under
conditions of good local ventilation. 聽 聽 聽 聽 聽 聽
Keep in a secure store, in a sealed, plastic container, away from incompatible
Storage (JM)
materials such as reducing agents. 聽 聽 聽
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
The following exposure controls have been established for Platinum
compounds -
UK HSE MEL - Halogeno-platinum compounds,(as Pt) - 0.002 mg/m鈥?
UK HSE OES - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?
USA ACGIH TLV - Platinum, soluble salts (as Pt) - 0.002 mg/m鈥?
Germany MAK - Platinum compounds (total dust) - 0.002 mg/m鈥?
Denmark ELV - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?
If a risk of inhalation exists, users should wear an appropriate filter type
respirator. Suitable gloves and eye protection should also be worn. 聽
9. PHYSICAL AND CHEMICAL PROPERTIES
Yellow crystals.
Appearance
no specific odour.
Odour
pH not applicable
not applicable.
Boiling Range/Point
Decomposes upon heating.
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
Vapour Pressure no data.
no data.
Density
Water - Soluble.
Solubility in Water
Fat - No data.
no data.
Partition Coefficient
聽
General
10. STABILITY AND REACTIVITY
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Johnson Matthey
SODIUM HEXAHYDROXYPLATINATE(IV)
186185 1.00 EC Current 30.07.1999
10. STABILITY AND REACTIVITY (continued)
The material is supplied in a stable condition and no reactive hazards are
known.
11. TOXICOLOGICAL INFORMATION
The only data available is -
Acute toxicity - LD50 (oral rat) 500-2000 mg/kg
Irritation - skin irritation, severe.
12. ECOLOGICAL INFORMATION
The reproduction of daphnids is impaired (16%) by 0.014 ppm Pt in 3 weeks.
Hydrogen hexachloroplatinate is reported to be lethal to certain freshwater
species. The complex may persist for some time in the environment. 聽 聽
13. DISPOSAL
Return accumulated waste material to the refinery for metal recovery, or
dispose of in accordance with local and national regulations. 聽
14. TRANSPORT INFORMATION
Not restricted.
15. REGULATORY INFORMATION
R22 Harmful if swallowed.
R phrases
R36/37/38 Irritating to eyes, respiratory system and skin.
S22 Do not breathe dust.
S phrases
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
2355900
EINECS Number
Xn - Harmful
EC Annex I Classification
16. OTHER INFORMATION
30 July 1999
MSDS first issued
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
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Johnson Matthey
SODIUM HEXAHYDROXYPLATINATE(IV)
186185 1.00 EC Current 30.07.1999
16. OTHER INFORMATION (continued)
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets. JMAC Approved applications -
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0181 8048111,
Fax:- 0181 8041918
S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061
Johnson Matthey S.A., Vallespir, 193-195, 08014 BARCELONA, Espa帽a, Tel:- (93) 490 86 86, Fax:- (93) 490 68 98
Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01
Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733
Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674
Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807
Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795
Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933
Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701
Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12
17. 000000000
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