MSDS Material Safety Data Sheet


File Name: jmcatalysts_com---468.asp
                               SAFETY DATA SHEET
Hydrogen Hexabromoplatinate (IV)
180040 Version Number 1.00

1. Identification of the substance/preparation and of the
Identification of the substance or preparation
Product name : Hydrogen Hexabromoplatinate (IV)
Chemical name : platinate(2-), hexabromo-, dihydrogen, (oc-6-11)-
Synonyms : Bromoplatinic Acid
Chemical formula : H2PtBr6
Company/undertaking identification
Manufacturer : Johnson Matthey Plc,
Orchard Road,
Herts SG8 5HE
Emergency telephone number : 01763 253000

2. Composition/information on ingredients
Substance/preparation : Substance
Ingredient name CAS % EC Number Classification

platinate(2-), hexabromo-, dihydrogen, (oc-6-11)- 20596-34-3 100 243-903-7 C; R34
N; R50/53
See section 16 for the full text of the R Phrases
declared above
* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The substance is classified as dangerous according to Directive 67/548/EEC and its amendments.
Classification : C; R34
N; R50/53
Human health hazards : Causes burns.
May cause sensitisation by inhalation and skin contact.
Environmental hazards : Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic

See section 11 for more detailed information on health effects and symptoms.

4. First aid measures
First aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Obtain medical attention immediately.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Obtain medical attention immediately.
Skin Contact : In case of contact, immediately flush skin copiously with water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse.
Clean shoes thoroughly before reuse. Obtain medical attention immediately.

Date of issue : 14/03/2005. Page: 1/5
Hydrogen Hexabromoplatinate (IV)
Eye contact : In case of contact, immediately flush eyes with a copious amount of water for at least
15 minutes. Obtain medical attention immediately.
See section 11 for more detailed information on health effects and symptoms.

5. Fire-fighting measures
Extinguishing media : Use an extinguishing agent suitable for surrounding fires.
Special exposure hazards : No specific hazard.
This material is very toxic to aquatic organisms. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway,
sewer or drain.
Special protective : Fire fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
Remark : The residue, ash or char left after a fire may have catalytic properties and may
promote the re-ignition of flammable materials and vapours.

6. Accidental release measures
Personal Precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (Section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up : If emergency personnel are unavailable vacuum or carefully scoop up spilled
materials and place in an appropriate container for disposal. Avoid creating dusty
conditions and prevent wind dispersal.

7. Handling and storage
Handling : Do not get in eyes, on skin or on clothing. Keep container closed. Use only with
adequate ventilation. Do not breathe dust. Avoid contact of spilled material and
runoff with soil and surface waterways. Wash thoroughly after handling.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended : Use original container.

8. Exposure controls/personal protection
Ingredient name Occupational exposure limits
platinate(2-), hexabromo-, dihydrogen, (oc- EH40-OES (United Kingdom (UK)). Sensitiser skin, Sensitiser
6-11)- inhalation Notes: Halogeno-Platinum Compounds
TWA: 0.002 mg/m3 8 hour(s). Form: As Pt
Exposure controls
Occupational exposure : Use process enclosures, local exhaust ventilation, or other engineering controls to
controls keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard
if a risk assessment indicates this is necessary.Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Hand protection : Chemical-resistant, impervious gloves or gauntlets complying with an approved
standard should be worn at all times when handling chemical products if a risk
assessment indicates this is necessary.
Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
Skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product.

Date of issue : 14/03/2005. Page: 2/5
Hydrogen Hexabromoplatinate (IV)

9. Physical and chemical properties
General information
Physical state : Solid. (hydroscopic crystals)
Colour : Red. Brown.
Important health, safety and environmental information
Melting point : 60掳C (140掳F)
Relative density : 2.431
Solubility : Easily soluble in cold water.
Partially soluble in diethyl ether.

10. Stability and reactivity
: The product is stable.
Hazardous Decomposition : These products are halogenated compounds.

11. Toxicological information
Potential acute health effects
Inhalation : Corrosive to the respiratory system. May cause sensitisation by inhalation.
Ingestion : May cause burns to mouth, throat and stomach.
Skin Contact : Corrosive to the skin. May cause sensitisation by skin contact.
Eye contact : Corrosive to eyes.
Persons with a history of allergic diseases, such as asthma or hay-fever, should not work with platinum salts. A history of
cardiac or pulmonary diseases may also preclude work with platinum salts - medical opinion should be sought. Any
workers experiencing untoward effects or symptoms should be removed from exposure and medically examined for
platinum sensitivity. Sensitisation is indicated by positive skin-prick test to low concentration solutions of platinum salts.
Potential chronic health effects

12. Ecological information
Ecotoxicity data
Ingredient name Species Period Result
platinate(2-), hexabromo-, Fish (LC50) 96 hour(s) 2.5 mg/l
0.13 ml/m3
dihydrogen, (oc-6-11)- Daphnia (EC50) 48 hour(s)
1.25 mg/m3
Algae (IC50) 72 hour(s)
* or similar material
Biodegradability Not available.
Other adverse effects : Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
based on data for: similar material

13. Disposal considerations
Methods of disposal : Return accumulated waste material to the refinery for metal recovery, or dispose of in
accordance with local and national regulations.

14. Transport information
International transport regulations
Regulatory UN number Proper shipping name Class Packing group Label Additional
information Information

ADR/RID Class UN3260 CORROSIVE SOLID, 8 II Hazard identification
N.O.S. (platinate(2-), 80
hexabromo-, dihydrogen,
(oc-6-11)-) Limited quantity

CEFIC Tremcard

Date of issue : 14/03/2005. Page: 3/5
Hydrogen Hexabromoplatinate (IV)
IMDG Class UN3260 CORROSIVE SOLID, 8 II Emergency
ACIDIC, INORGANIC, schedules (EmS)
N.O.S. (platinate(2-), F-A, S-B
hexabromo-, dihydrogen,
IATA Class UN3260 Corrosive solid, acidic, 8 II Quantity limitation -
inorganic, n.o.s. (platinate Passenger Aircraft -
(2-), hexabromo-, Limited quantity
dihydrogen, (oc-6-11)-) 5 kg

Quantity limitation -
Passenger Aircraft
15 kg

Quantity limitation -
Cargo Aircraft
50 kg

15. Regulatory information
EU Regulations
Hazard symbol(s) :

Corrosive, Dangerous for the environment.
Risk Phrases : R34- Causes burns.
R42/43- May cause sensitisation by inhalation and skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety Phrases : S22- Do not breathe dust.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
S57- Use appropriate containment to avoid environmental contamination.
S61- Avoid release to the environment. Refer to special instructions/Safety data
Not available.
: platinate(2-), hexabromo-, dihydrogen, (oc-6-11)-
Product use : Classification and labelling have been performed according to EU directives
67/548/EEC, 1999/45/EC, including amendments and the intended use.
- Industrial applications.

16. Other information
Full text of R phrases : R34- Causes burns.
referred to in sections 2 and R42/43- May cause sensitisation by inhalation and skin contact.
3 - United Kingdom (UK) R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Full text of classifications : C - Corrosive
referred to in sections 2 and N - Dangerous for the environment.
3 - United Kingdom (UK)
Date of printing : 15/03/2005.
: 14/03/2005.
Date of issue
Date of previous issue : No Previous Validation.
Version : 0.01
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process. Such information is given in good faith, being based on the latest information available to Johnson Matthey PLC
and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at the time of preparation. However, no
representation, warranty or guarantee is made as to the accuracy, liability or completness and Johnson Matthey PLC assumes no
responsibility therefore, and disclaims any liability for any loss, damage or injury howsoever arising (including in respect of any claim
brought by any third party) incurred using this information. The product is supplied on the condition that the user accepts responsibility to
satisfy himself as to the suitability and completeness of such information for his own particular use. Freedom from patent or any other
proprietary rights of any third party must not be assumed.
Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

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Hydrogen Hexabromoplatinate (IV)
Johnson Matthey National Sales Offices
Johnson Matthey .PLC Orchard Road, Royston Hertfordshire, SG8 5HE England Tel:+44(0)1763 253000 Fax: +44
(0)1763 253668
Johnson Matthey PLC 33 Jeffreys Road, Brimsdown, Enfield, Middlesex, EN3 7PW United Kingdom Tel: 0208 8048 8111
Fax: 020 8804 1918
Johnson Matthey& Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich Tel:877 98 90 Fax: 877 98 933
S.A. Johnson Matthey N.V 8 Avenue de Bale, 1140 Brussel,Belgi毛 / Belgique Tel:2 729 0711 Fax:2 216 9061
Johnson Matthey A/S Frederikssundsvej 274 D,Br垄nsh垄j 2700, Denmark Tel:38 89 62 00 Fax:38 89 62 01
Oy Johnson Matthey A.B Kielotie 7A 4KRS, 01300 Bantaa, Soumi Tel:08574 800 Fax: 08574 807
Johnson Matthey GmbH Alfa Products. Zeppelinstrasse 7, Postfach 6540,D-7500 Karlsruhe 1, Deutschland Tel:721
8400 70 Fax: 721 849674
Johnson Matthey SA 13 Rue de la Perdrix, Z1 Paris Nord 11, BP 50240, 95996 Roissy,CDG Cedix France Tel:1 48 63
22 99 Fax:1 48 63 27 02
Johnson Matthey GmbH Otto-Volger-Strasse 9B, D-65843 Sulzbach/Ts, Deutschland Tel:(0 61 96)70 38-21 Fax:(0 61
96)70 38 12
Johnson Matthey. PLC Unit 1-2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15 Republic
of Ireland Tel 1 820 7722 Fax:1 820 7733
Johnson Matthey A.B. Victor Hasselblads Gata 8, S-421 31 V盲stra Fr枚lunda, Sverige Tel:031 891390 Fax: 031 477795
Johnson Matthey & Brandenberger A.G. Glattalstrasse 18, CH-8052 Zurich, Switzerland Tel:01 307 1919 Fax:01 307

Date of issue : 14/03/2005. Page: 5/5

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