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MSDS Material Safety Data Sheet
CAS

14913-33-8

File Name: jmcatalysts_com---477.asp
                                     Johnson Matthey
PT-03 TRANS-DIAMMINEDICHLOROPLATINUM(II)
189003 1.00 EC Current 30.07.1999

1. PRODUCT AND COMPANY IDENTIFICATION
189003
Product Code
PT-03 TRANS-DIAMMINEDICHLOROPLATINUM(II)
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
trans-Diammindichloroplatinum(II), Pt-03, trans-[PtCl (NH ) ]
Composition
1
JM Version Number
08/06/93
Date of First Issue

2. COMPOSITION/INFORMATION ON THE COMPONENTS
PT-03 TRANS-DIAMMINEDICHLOROPLATINUM(II)
Product Formal Name
.Not Specified
Product Chemical Family
14913-33-8
CAS Number

3. HAZARD IDENTIFICATION
This material is of very low acute toxicity, LD50 > 5000mg/kg, and is non-
irritating to the skin but is corrosive to the eyes.
This compound is not ionisable and does not produce an allergic response
when administered to persons sensitised to platinum-halogeno compounds.
This material is reported as producing mutagenic effects in bacteria and in
isolated mammalian (including human) cells. Users should note that the cis
isomer is very toxic and has marked mutagenic properties. 聽 聽

4. FIRST AID MEASURES
Over-exposure to this material may produce the following symptoms -
First Aid
Inhalation : irritation of the respiratory system with coughing. Ingestion :
abdominal pain and vomiting. Eye contact : severe pain, blurred vision and
possible blindness. 聽 聽 聽 聽

remove from exposure and allow to rest in fresh air, if symptoms persist seek
First Aid - Inhalation
medical attention. 聽
First Aid - Ingestion rinse mouth with clean water and give clean water or milk to drink. Seek
medical advice.
rinse with clean water or isotonic saline solution for 15 minutes, seek medical
First Aid - Eyes
attention urgently. 聽 聽
First Aid - Skin wash skin with soap and water.


5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽

6. ACCIDENTAL RELEASE MEASURES
Wearing gloves and eye protection, sweep up the spillage and store in
sealed, plastic containers, ready for disposal. Wash the area with water. 聽 聽


\ Page 1
Johnson Matthey
PT-03 TRANS-DIAMMINEDICHLOROPLATINUM(II)
189003 1.00 EC Current 30.07.1999

7. HANDLING AND STORAGE
Good industrial hygiene practices should be observed. Avoid direct contact.
Handling (JM)
Do not eat, drink, smoke or apply cosmetics whilst handling. Exposure to air-
borne particulates must be kept within permissible limits. Use only under
conditions of good local ventilation. 聽 聽 聽 聽 聽 聽
Keep in a secure store, in a sealed, plastic container, away from incompatible
Storage (JM)
materials such as reducing agents. 聽 聽 聽

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
The following exposure controls have been established for Platinum
compounds -

UK HSE MEL - Halogeno-platinum compounds,(as Pt) - 0.002 mg/m鈥?
UK HSE OES - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?
USA ACGIH TLV - Platinum, soluble salts (as Pt) - 0.002 mg/m鈥?
Germany MAK - Platinum compounds (total dust) - 0.002 mg/m鈥?
Denmark ELV - Platinum compounds, soluble (as Pt) - 0.002 mg/m鈥?

If a risk of inhalation exists, users should wear an appropriate filter type
respirator. Suitable gloves and eye protection should also be worn. 聽

9. PHYSICAL AND CHEMICAL PROPERTIES
Yellow crystals or powder.
Appearance
no specific odour.
Odour
not applicable
pH
not applicable.
Boiling Range/Point
Decomposes 340掳C.
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
no data.
Density
Water - very slightly soluble, 0.036gm/100ml at 25掳C.
Solubility in Water
Soluble in Dimethylformamide and in Dimethylacetamide.
Insoluble in Acetone.
Fat - no data.
no data.
Partition Coefficient

10. STABILITY AND REACTIVITY
This material is supplied in an air stable condition. No specific reactive
hazards are known to Johnson Matthey.

11. TOXICOLOGICAL INFORMATION
LD50 (oral-rat) >5110mg/kg, LD50 (ipr mouse) 27mg/kg,
Eye rabbit - corrosive, skin rabbit (4 hours) - non irritant.
Users should note that a solution of this material in Dimethylformamide will
probably be readily absorbed through the skin, the effects of such absorbtion
are not known.
Tumourigenic effects are reported after administering this material inter-
peritoneally, mutagenic results are also reported in a wide range of bacteria
and isolated mammalian cells (including human) following exposure to this
material.



\ Page 2
Johnson Matthey
PT-03 TRANS-DIAMMINEDICHLOROPLATINUM(II)
189003 1.00 EC Current 30.07.1999

12. ECOLOGICAL INFORMATION
No specific data is available for this material. Platinum impairs the
reproduction of Daphnids when present at very low levels. Do not allow this
material to enter natural watercourses. 聽

13. DISPOSAL
Return accumulated waste material to the refinery for metal recovery, or
dispose of in accordance with local and national regulations. 聽

14. TRANSPORT INFORMATION
Not restricted.


15. REGULATORY INFORMATION
R41 Risk of serious damage to eyes.
R phrases
S phrases S25 Avoid contact with eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
2389809
EINECS Number
Xi - Irritant
EC Annex I Classification

16. OTHER INFORMATION
30 July 1999
MSDS first issued
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.

\ Page 3
Johnson Matthey
PT-03 TRANS-DIAMMINEDICHLOROPLATINUM(II)
189003 1.00 EC Current 30.07.1999

16. OTHER INFORMATION (continued)
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets. JMAC Approved applications -
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0181 8048111,
Fax:- 0181 8041918

S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061

Johnson Matthey S.A., Vallespir, 193-195, 08014 BARCELONA, Espa帽a, Tel:- (93) 490 86 86, Fax:- (93) 490 68 98

Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01

Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733

Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674

Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02

Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807

Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795

Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933

Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701

Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12


17. 000000000




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