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MSDS Material Safety Data Sheet
CAS

67859-45-4

File Name: jmcatalysts_com---490.asp
                                        Johnson Matthey
PALLADIUM DNS SOLUTION
151010 2.00 EC Current 15.09.2000

1. PRODUCT AND COMPANY IDENTIFICATION
151010
Product Code
PALLADIUM DNS SOLUTION
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
Potassiumdinitrosulfatopalladate solution, K [Pd(NO ) SO ]
Composition
1
JM Version Number
18/10/96
Date of First Issue

2. COMPOSITION/INFORMATION ON THE COMPONENTS
PALLADIUM DNS SOLUTION
Product Formal Name
.Not Specified
Product Chemical Family
67859-45-4
CAS Number

3. HAZARD IDENTIFICATION
There is no toxicological data available for this Palladium compound. The
principal hazard of this solution is the prescence of Sulfuric acid at a level of
approximately 5%. In accordance with the classification regulations this
solution is classified as a skin and eye irritant. 聽

4. FIRST AID MEASURES
Over-exposure may produce the following symptoms -
First Aid
Inhalation - irritation of the respiratory tract, producing coughing.
Ingestion - abdominal pain.
Eye contact - redness, irritation, blurred vision and pain.
Skin - redness and irritation. 聽 聽 聽

First Aid - Inhalation remove from exposure and allow to rest in fresh air. Seek medical attention. 聽
rinse mouth with clean water and give water or milk to drink. Seek medical
First Aid - Ingestion
attention.
irrigate with water or isotonic saline solution for 15 minutes. Seek medical
First Aid - Eyes
attention.
remove contaminated clothing and wash skin with soap and water. If
First Aid - Skin
symptoms persist, seek medical attention. 聽


5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽

6. ACCIDENTAL RELEASE MEASURES
Wearing chemical resistant gloves and eye protection, spread lime (calcium
hydroxide) or sodium carbonate liberally over the spillage to neutralise the
acid and mop up cautiously with plenty of water. Wash the area thoroughly
with water afterwards. 聽

\ Page 1
Johnson Matthey
PALLADIUM DNS SOLUTION
151010 2.00 EC Current 15.09.2000

7. HANDLING AND STORAGE
Good industrial hygiene practices should be observed. Use only under
Handling (JM)
conditions of good local ventilation. Avoid contact with the skin and eyes. Do
not eat, drink, smoke or apply cosmetics whilst using this material. 聽
Store in an air-tight container under vacuum or an inert atmosphere, in a cool
Storage (JM)
dry chemical store.
Keep separate from incompatible materials and flammable or combustible
materials.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No specific exposure control standards have been established for the
Palladium compound. The following standards have been established for
Sulfuric Acid.

UK HSE OES - 1 mg/m鈥?
USA ACGIH TLV - 1 mg/m鈥?
Germany MAK - 1 mg/m鈥?
France VME - 1 mg/m鈥?

Local exhaust extraction should be used. If a risk of inhalation exists, users
should wear appropriate respiratory protection. Chemical resistant gloves and
suitable eye protection should also be worn. 聽

9. PHYSICAL AND CHEMICAL PROPERTIES
red/gold solution.
Appearance
No odour.
Odour
3.5 - 4
pH
100掳C approximately.
Boiling Range/Point
0掳C approximately.
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
>1
Density
Water - soluble.
Solubility in Water
Fat - no data.
no data.
Partition Coefficient

10. STABILITY AND REACTIVITY
This material is supplied in a stable condition. No reactive hazards are known
for Palladium DNS solution. Many reactive hazards are reported for Sulphuric
acid, user are advised to refer to standard texts such as"Bretherick's" in case
of doubt.

11. TOXICOLOGICAL INFORMATION
There is no toxicological data available for this Palladium compound. The
solution is classified as a skin and eye irritant on the basis of the Sulfuric acid
content.

12. ECOLOGICAL INFORMATION



\ Page 2
Johnson Matthey
PALLADIUM DNS SOLUTION
151010 2.00 EC Current 15.09.2000

12. ECOLOGICAL INFORMATION (continued)
There have been no reports of adverse environmental effects due to
Palladium.
The following data is available for the Sulphuric acid component.
LC50 shrimp 80-90mg/lt/48hrs (aerated water), LC50 flounder 100-330mg/lt/
48hrs (aerated water), LC50 prawn 42.5ppm/48hrs (salt water).
The toxicity of Sulphuric acid to aquatic life is a function of the resulting pH. A
pH of 4.0 produced pronounced gill irritation and a pH of 3.5 caused death of
sunfish, bass and carp. 聽 聽

13. DISPOSAL
The slurry obtained following neutralisation with lime or soda ash can be dried
on a filter and disposed of to land-fill, in accordance with local and national
regulations.

14. TRANSPORT INFORMATION
U.N. No. 3264, Class 8.0, Packing Group III
ADR 2801 1(c)

15. REGULATORY INFORMATION
R36/38 Irritating to eyes and skin.
R phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and
S phrases
seek medical advice.
2673951
EINECS Number
Xi - Irritant
EC Annex I Classification

16. OTHER INFORMATION
30 July 1999
MSDS first issued
15 September 2000
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.


\ Page 3
Johnson Matthey
PALLADIUM DNS SOLUTION
151010 2.00 EC Current 15.09.2000

16. OTHER INFORMATION (continued)
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets.
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0208 8048111,
Fax:- 0208 8041918

S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061

Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01

Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733

Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674

Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02

Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807

Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795

Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933

Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701

Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12


17. 000000000




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