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MSDS Material Safety Data Sheet
CAS

10025-99-7

File Name: jmcatalysts_com---462.asp
                               SAFETY DATA SHEET
Potassium Tetrachloroplatinate (II)
180095 Version Number 1.00

1. Identification of the substance/preparation and of the
company/undertaking
Identification of the substance or preparation
Product name : Potassium Tetrachloroplatinate (II)
Chemical name : Dipotassium tetrachloroplatinate
Synonyms : platinous potassium chloride; potassium chloroplatinite; potassium platinochloride;
potassium tetrachloroplatinate(ii); potassium tetrachlorplatinate(ii)
Chemical formula : K2PtCl4
Company/undertaking identification
Manufacturer : Johnson Matthey Plc,
Orchard Road,
Royston,
Herts SG8 5HE
Emergency telephone number : 01763 253000

2. Composition/information on ingredients
Substance/preparation : Substance
Ingredient name CAS % EC Number Classification
number

Dipotassium tetrachloroplatinate 10025-99-7 100 233-050-9 T; R25
Xi; R41
R42/43
See section 16 for the full text of the R Phrases
declared above
* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The substance is classified as dangerous according to Directive 67/548/EEC and its amendments.
Classification : T; R25
Xi; R41
R42/43
Human health hazards : Toxic if swallowed.
Risk of serious damage to eyes.
May cause sensitisation by inhalation and skin contact.



See section 11 for more detailed information on health effects and symptoms.

4. First aid measures
First aid measures
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Inhalation :
Obtain medical attention immediately.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
Ingestion :
unconscious person. Obtain medical attention immediately.
In case of contact, immediately flush skin copiously with water for at least 15 minutes while removing contaminated
Skin Contact :
clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain medical attention
immediately.

: In case of contact, immediately flush eyes with a copious amount of water for at least 15 minutes. Obtain
Eye contact
medical attention immediately.


See section 11 for more detailed information on health effects and symptoms.
Page: 1/5
Date of issue : 08/03/2005.
Potassium Tetrachloroplatinate (II)

5. Fire-fighting measures
Extinguishing media : Use an extinguishing agent suitable for surrounding fires.
Special exposure hazards : No specific hazard.
Hazardous thermal : These products are halogenated compounds, hydrogen chloride. Some metallic
decomposition products oxides.
Special protective : Fire fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Remark : The residue, ash or char left after a fire may have catalytic properties and may
promote the re-ignition of flammable materials and vapours.

6. Accidental release measures
Personal Precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (Section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up : If emergency personnel are unavailable vacuum or carefully scoop up spilled
materials and place in an appropriate container for disposal. Avoid creating dusty
conditions and prevent wind dispersal.

7. Handling and storage
Handling : Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed.
Use only with adequate ventilation. Do not breathe dust. Wash thoroughly after
handling.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended : Use original container.

8. Exposure controls/personal protection
Ingredient name Occupational exposure limits
Dipotassium tetrachloroplatinate EH40-OES (United Kingdom (UK)). Sensitiser skin, Sensitiser
inhalation Notes: As Pt
TWA: 0.002 mg/m3 8 hour(s). Form: Halogeno-Platinum
Compounds
Exposure controls
Occupational exposure : Use process enclosures, local exhaust ventilation, or other engineering controls to
controls keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard
if a risk assessment indicates this is necessary.Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Hand protection : Chemical-resistant, impervious gloves or gauntlets complying with an approved
standard should be worn at all times when handling chemical products if a risk
assessment indicates this is necessary.
Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before
handling this product.




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Date of issue : 08/03/2005.
Potassium Tetrachloroplatinate (II)

9. Physical and chemical properties
General information
Appearance
Physical state : Solid.
Colour : Brownish-red.
Important health, safety and environmental information
Melting point : Decomposes.
Solubility : Very slightly soluble in cold water.

10. Stability and reactivity
: The product is stable.
Stability
Hazardous Decomposition : These products are halogenated compounds, hydrogen chloride.
Products

11. Toxicological information
Potential acute health effects
Inhalation : May cause sensitisation by inhalation.
Ingestion : Toxic if swallowed.
Skin Contact : May cause sensitisation by skin contact.
Eye contact : Severely irritating to eyes.
Acute toxicity
Product/ingredient name Test Result Route Species
Dipotassium tetrachloroplatinate LD50 <200 mg/kg Oral Rat
LDLo 400 mg/kg Oral child
Persons with a history of allergic diseases, such as asthma or hay-fever, should not work with platinum salts. A history of
cardiac or pulmonary diseases may also preclude work with platinum salts - medical opinion should be sought. Any
workers experiencing untoward effects or symptoms should be removed from exposure and medically examined for
platinum sensitivity. Sensitisation is indicated by positive skin-prick test to low concentration solutions of platinum salts.

12. Ecological information
Biodegradability Not available.
Other adverse effects : No known significant effects or critical hazards.
Not available.

13. Disposal considerations
Methods of disposal : Return accumulated waste material to the refinery for metal recovery, or dispose of in
accordance with local and national regulations.

14. Transport information
International transport regulations
Regulatory UN number Proper shipping name Class Packing group Label Additional
information Information

ADR/RID Class UN3288 TOXIC SOLID, 6.1 III Hazard identification
INORGANIC, N.O.S. number
(Dipotassium 60
6
tetrachloroplatinate)
Limited quantity
LQ9

CEFIC Tremcard
61GT5-III
IMDG Class UN3288 TOXIC SOLID, 6.1 III Emergency
INORGANIC, N.O.S. schedules (EmS)
(Dipotassium F-A, S-A
6
tetrachloroplatinate)




Page: 3/5
Date of issue : 08/03/2005.
Potassium Tetrachloroplatinate (II)
IATA Class UN3288 Toxic solid, inorganic, n.o.s. 6.1 III Quantity limitation -
(Dipotassium Passenger Aircraft -
tetrachloroplatinate) Limited quantity
6
10 kg

Quantity limitation -
Passenger Aircraft
100 kg

Quantity limitation -
Cargo Aircraft
200 kg


15. Regulatory information
EU Regulations
Hazard symbol(s) :




Toxic
Risk Phrases : R25- Toxic if swallowed.
R41- Risk of serious damage to eyes.
R42/43- May cause sensitisation by inhalation and skin contact.
Safety Phrases : S22- Do not breathe dust.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
: Dipotassium tetrachloroplatinate Not available.
Contains
Product use : Classification and labelling have been performed according to EU directives
67/548/EEC, 1999/45/EC, including amendments and the intended use.
- Industrial applications.

16. Other information
Full text of R phrases : R25- Toxic if swallowed.
referred to in sections 2 and R41- Risk of serious damage to eyes.
3 - United Kingdom (UK) R42/43- May cause sensitisation by inhalation and skin contact.
Full text of classifications : T - Toxic
referred to in sections 2 and Xi - Irritant
3 - United Kingdom (UK)
History
Date of printing : 08/03/2005.
: 08/03/2005.
Date of issue
Date of previous issue : No Previous Validation.
Version : 0.01
Notice to reader
This information relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process. Such information is given in good faith, being based on the latest information available to Johnson Matthey PLC
and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at the time of preparation. However, no
representation, warranty or guarantee is made as to the accuracy, liability or completness and Johnson Matthey PLC assumes no
responsibility therefore, and disclaims any liability for any loss, damage or injury howsoever arising (including in respect of any claim
brought by any third party) incurred using this information. The product is supplied on the condition that the user accepts responsibility to
satisfy himself as to the suitability and completeness of such information for his own particular use. Freedom from patent or any other
proprietary rights of any third party must not be assumed.
Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)
Johnson Matthey National Sales Offices
Johnson Matthey .PLC Orchard Road, Royston Hertfordshire, SG8 5HE England Tel:+44(0)1763 253000 Fax: +44
(0)1763 253668
Johnson Matthey PLC 33 Jeffreys Road, Brimsdown, Enfield, Middlesex, EN3 7PW United Kingdom Tel: 0208 8048 8111
Fax: 020 8804 1918
Johnson Matthey& Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich Tel:877 98 90 Fax: 877 98 933
S.A. Johnson Matthey N.V 8 Avenue de Bale, 1140 Brussel,Belgi毛 / Belgique Tel:2 729 0711 Fax:2 216 9061
Johnson Matthey A/S Frederikssundsvej 274 D,Br垄nsh垄j 2700, Denmark Tel:38 89 62 00 Fax:38 89 62 01
Oy Johnson Matthey A.B Kielotie 7A 4KRS, 01300 Bantaa, Soumi Tel:08574 800 Fax: 08574 807
Page: 4/5
Date of issue : 08/03/2005.
Potassium Tetrachloroplatinate (II)
Johnson Matthey GmbH Alfa Products. Zeppelinstrasse 7, Postfach 6540,D-7500 Karlsruhe 1, Deutschland Tel:721
8400 70 Fax: 721 849674
Johnson Matthey SA 13 Rue de la Perdrix, Z1 Paris Nord 11, BP 50240, 95996 Roissy,CDG Cedix France Tel:1 48 63
22 99 Fax:1 48 63 27 02
Johnson Matthey GmbH Otto-Volger-Strasse 9B, D-65843 Sulzbach/Ts, Deutschland Tel:(0 61 96)70 38-21 Fax:(0 61
96)70 38 12
Johnson Matthey. PLC Unit 1-2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15 Republic
of Ireland Tel 1 820 7722 Fax:1 820 7733
Johnson Matthey A.B. Victor Hasselblads Gata 8, S-421 31 V盲stra Fr枚lunda, Sverige Tel:031 891390 Fax: 031 477795
Johnson Matthey & Brandenberger A.G. Glattalstrasse 18, CH-8052 Zurich, Switzerland Tel:01 307 1919 Fax:01 307
1920




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Date of issue : 08/03/2005.

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