GFS CHEMICALS, INC.
P.O. Box 245 Powell, OH 43065
740-881-5501(Tel.) 740-881-5989(Fax)
1-800-424-9300(Chemtrec 24Hr. Info.)
MATERIAL SAFETY DATA SHEET
1611 (1 of 3)
1612
KF WATERMARK庐 VESSEL SOLUTION
CHEMICAL NAME & SYNONYMS DOT CLASS SARA TITLE 313
KF Watermark庐 Vessel Solution for coulometric 3/II Yes - Methanol
titrations, pyridine free and chloroform
TSCA listed - Yes
FORMULA REPORTABLE QUANTITY F.W. CAS#
Methyl alcohol 25-35% 2270 kg 32.04 67-56-1
Chloroform 40-50% 4.54 kg 119.38 67-66-3
proprietary amine iodide 15-25% N/A
Sulfur dioxide 2-10% 227 kg 64.06 7446-09-5
PHYSICAL DATA
Boiling point 61掳C; Density 1.2; Vapor pressure 100 mm @ 10掳C; percent volatile, 75%; vapor
density (air=1) 4.0; Water soluble.
APPEARANCE & ODOR
Clear to light brown liquid, characteristic odor.
REACTIVITY & CONDITIONS TO AVOID
Stable. Flammable, avoid oxidizers, ignition sources, heat.
FIRE HAZARDS
Flammable, will release toxic compounds when burning. Wear self-contained breathing apparatus
and protective clothing.
EXTINGUISHER FLASHPOINT LEL UEL
Water spray, Foam, CO 2, Dry chemical 11掳C 6% 36.5%
HEALTH HAZARDS
Toxic by ingestion or inhalation. Causes lethargy, headache, gastrointestinal upset, anemia,
damage to CNS, kidney, liver and blindness. Principal routes of absorption: dermal, inhalation,
oral. Chloroform is listed as a suspect carcinogen by NTP. OSHA PEL/ACGIH TLV TWA: 200 ppm;
ACGIH TLV STEL 250 ppm (methyl alcohol); OSHA PEL (ceiling) 50 ppm, ACGIH TLV TWA 2 ppm
(chloroform); OSHA PEL TWA 5 ppm, ACGIH TLV TWA 2 ppm, STEL 5 ppm (sulfur dioxide). Warning:
This product contains a chemical (chloroform) known to the state of California to cause cancer.
SPECIAL PRECAUTIONS
Goggles, rubber gloves must be worn. Use in well ventilated hood. Store at room temperature (15-
30掳C). Keep containers tightly closed.
FIRST AID
Eyes, skin: Wash with water for at least 15 minutes. If irritation persists, get medical
attention. Inhalation: Remove to fresh air, call physician. Ingestion: Give water to drink and
get immediate medical attention. Do NOT induce vomiting unless directed by a physician.
SPILLS & LEAKS
Eliminate ignition sources, take up with absorbent. Dispose by incineration or other method in
accordance with all local, state, and federal regulations.
CATALOG # PREPARED BY DATE
1612 MDM May 31, 2005
GFS CHEMICALS, INC.
P.O. Box 245 Powell, OH 43065
740-881-5501(Tel.) 740-881-5989(Fax)
1-800-424-9300(Chemtrec 24Hr. Info.)
MATERIAL SAFETY DATA SHEET
1611 (2 of 3)
1613
WATERMARK GENERATOR SOLUTION
CHEMICAL NAME & SYNONYMS DOT CLASS SARA TITLE 313
Watermark Generator solution for 3/III Yes,
coulometric titrations 2-methoxyethanol
TSCA listed - Yes
FORMULA REPORTABLE QUANTITY F.W. CAS#
2-methoxyethanol 50-70% N/A N/A 109-86-4
non-toxic proprietary amine 10-25% N/A
Sulfur dioxide <10% 227 kg 7446-09-5
Iodine 5-15% N/A 7553-56-2
PHYSICAL DATA
Boiling point 124掳C; Specific gravity 1.1; vapor pressure 50 mm @ 30掳C; percent volatile, about
60%; pH about 6; vapor density(air=1) 2.6; water soluble.
APPEARANCE & ODOR
Brown liquid with strong sulfur dioxide and iodine odor.
REACTIVITY & CONDITIONS TO AVOID
Stable, Avoid oxidizers, ignition sources, heat. Incompatible with water.
FIRE HAZARDS
Will release toxic compounds when burning. Wear self-contained breathing apparatus and
protective clothing.
EXTINGUISHER FLASHPOINT LEL UEL
Water spray, Foam, CO 2, dry chemical. 46掳C 2% 14%
HEALTH HAZARDS
Toxic by ingestion or inhalation. Causes lethargy, headache, gastrointestinal upset, anemia,
damage to CNS, kidney, liver and testes. Principal routes of absorption: dermal, inhalation,
oral. Repeated exposure can have cumulative effect. OSHA PEL 25 ppm, ACGIH TLV 5 ppm (2-
methoxyethanol); PEL 5 ppm, TWA 2 ppm, STEL 5 ppm (sulfur dioxide); PEL 0.1 ppm, TLV 0.1 ppm
(iodine). Experimental mutagenic, teratogenic and reproductive effects. Warning: This product
contains a chemical (2-methoxyethanol) known to the state of California to cause birth defects
or other reproductive harm.
SPECIAL PRECAUTIONS
Goggles, rubber gloves must be worn. Use in well ventilated hood. Store at room temperature (15-
30掳C). Keep containers tightly closed.
FIRST AID
Eyes, skin: Wash with water for at least 15 minutes. If irritation persists contact physician.
Inhalation: Remove to fresh air, call physician. Ingestion: Give water to drink and get
immediate medical attention. Do NOT induce vomiting unless directed by a physician.
SPILLS & LEAKS
Eliminate ignition sources, neutralize with soda ash or take up with absorbent. Dispose in to
hazardous waste in accordance to all local, state, and federal regulations.
CATALOG # PREPARED BY DATE
1613 MDM May 31, 2005
GFS CHEMICALS, INC.
P.O. Box 245 Powell, OH 43065
740-881-5501(Tel.) 740-881-5989(Fax)
1-800-424-9300(Chemtrec 24Hr. Info.)
MATERIAL SAFETY DATA SHEET
1611 (3 of 3)
1614
WATERMARK NEUTRALIZING SOLUTION
CHEMICAL NAME & SYNONYMS DOT CLASS SARA TITLE 313
WaterMark Neutralizing Solution;Methyl Alcohol; 3/II Yes
Methanol; Wood Alcohol TSCA listed - Yes
FORMULA REPORTABLE QUANTITY F.W. CAS#
CH 3OH 99% 2270 kg 32.04 67-56-1
H 2O 1% N/A 18.02 7732-18-5
PHYSICAL DATA
Density 0.79; Melting point -97.8掳C; Boiling point 64.8掳C; Vapor pressure 100 mm at 21掳C; Vapor
density 1.1; 100% volatile. Miscible with water, ethanol or ether.
APPEARANCE & ODOR
Clear colorless liquid. Slight odor of alcohol.
REACTIVITY & CONDITIONS TO AVOID
Stable. No spontaneous self-reactions. Incompatible with oxidants.
FIRE HAZARDS
Flammable with heat spark or flame. Flame is nearly invisible. NFPA # 3-3-1.
EXTINGUISHER FLASHPOINT LEL UEL
Dry chemical, foam, CO 2. 12掳C 6.0% 36.5%
HEALTH HAZARDS
Irritating to skin, eyes and on inhalation. Toxic effects on CNS, narcotic properties. Toxic
internally LD 50 (oral-rat) 5628 mg/kg; LC 50 (inhal-rat) 64,000 ppm/4 H. 50-250 ml is fatal dose
to humans. Smaller doses may cause blindness. Other symptoms include dizziness, blurring of
vision, headaches, nausea, unconsciousness and intoxication. May be absorbed through the skin.
OSHA PEL/ACGIH TLV: TWA: 200 ppm. ACGIH STEL 250 ppm. No evidence of carcinogenicity.
SPECIAL PRECAUTIONS
Wear goggles and rubber gloves while handling. Use with good ventilation. Keep away from
ignition sources.
FIRST AID
Wash skin and eyes thoroughly with water. Get medical assistance if irritation develops.
Inhalation: remove to fresh air. If swallowed, give water to drink and get immediate medical
assistance. Do NOT induce vomiting unless directed by a physician.
SPILLS & LEAKS
Take up spill in absorbent and incinerate. Wash up with water. Small amounts may be disposed
of to sanitary drain. Check local regulations.
CATALOG # PREPARED BY DATE
1614 MDM August 5, 2004
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