Wednesday, November 17, 2004
Page 1 of 4
MSDS - Material Safety Data Sheet
Product Name: Butane Fuel Canister
MSDS No.: SCW103/5
I. Basic Information:
Manufacturer: Sirchie Finger Print Laboratories, Inc.
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Address: 100 Hunter Place
City, ST Zip: Youngsville, NC 27596
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Emergency Contact: CHEMTREC
Emergency Telephone Number: 800-424-9300
Contact: Premier Crown Tech Support
Information Telephone Number: 919-554-2244
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Last Update: 11/08/2004 Expiration Date:
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X Liquid Gas Solid
Chemical State:
B
Pure Mixture
Chemical Type: X
II. Ingredients:
Trade Secret
EHS IARC SARA
313 OSHA ACGIH Other
% Range NTP SUB Z PEL TLV Limits
CAS No. Chemical Name
106978 Butane <2.5 800 ppm 800 ppm
75081 Ethanethiol 0-50 ppm 0.5 ppm 0.5 ppm
74986 Propane >90 1,000 ppm 1,000 ppm -156 F
X
115071 Propylene <5 NE NE
III. Hazardous Identification:
Hazard Category:
X Acute X Chronic X Fire Pressure Reactive
Hazardous Identification Information:
Respiratory tract irritant. Skin and eye irritant. May cause central nervous system depression. May cause narcosis based on
animal testing.
This material is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
IV. First Aid Measures:
Route(s) of Entry:
Inhalation, ingestion, skin, eyes
Health Hazards (Acute and Chronic):
Acute: Freeze-burns to the skin and eyes
Signs and Symptoms:
Inhalation: Dizziness, headache, disorientation, excitation, fatigue, inability to concentrate, vomiting, coughing, anesthesia,
unconsciousness, death
Medical Conditions Generally Aggravated by Exposure:
Skin, eye, respiratory diseases
Wednesday, November 17, 2004
Page 2 of 4
MSDS - Material Safety Data Sheet
Product Name: Butane Fuel Canister
MSDS No.: SCW103/5
Emergency and First Aid Procedures:
Inhalation: Remove to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen (To be
administered by qualified medical personnel only!) Get medical attention.
Ingestion: If victim is conscious and alert, give 2 cups of water. (Never give anything by mouth to an unconscious person!)
Induce vomiting. Get medical attention immediately.
Skin: Flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing. Seek medical attention if
condition warrants.
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Seek medical attention
if condition warrants.
Other Health Warnings:
V. Fire Fighting Measures:
Flash Point: -156 F Lower Explosive Limit: 2.1 Upper Explosive Limit: 9.5
F.P. Method:
Fire Extinguishing Media: Dry chemical, foam, carbon dioxide
Special Fire Fighting Procedures:
Wear self-contained breathing apparatus and protective clothing. Shut off source, if possible. Water fog or spray may be used to
cool fire-exposed containers. Allow fire to burn until gas flow is shut off, if possible.
Unusual Fire and Explosion:
Vapors from this product may travel some distance from original point to an ignition source and flash back. Heated containers may
rupture violently and suddenly without warning due to vessel over-pressure (BLEVE). Fragmentation of the container should be
anticipated. If flame is against the container, withdraw immediately on hearing a rising sound, if venting increases in volume or
intensity, or if there is discoloration of the container due to fire.
VI. Accidental Release Measures:
Steps to be Taken in Case Material is Released or Spilled:
Shut off source, if possible. Wear vapor respirator, safety goggles, and rubber gloves. Remove sources of ignition (i.e. open
flames, sparks). Contain spill. Soak up with dry, inert absorbent material (sand or clay recommended; do not use flammable
substances such as sawdust). Scoop up with non-sparking equipment. Dispose according to local, state, and federal regulations.
VII. Handling and Storage:
Precautions to be Taken:
Keep in tightly closed container. Secure container to prevent damage. Do not puncture or incinerate container. Avoid
incompatible materials. Avoid all ignition sources (heat, open flame, spark). Bond and ground during transfer. Use only in
well-ventilated areas. Avoid contact with skin, eyes, and clothing. Avoid breathing vapor. Wash thoroughly after handling.
Other Precautions:
Store in containers that have been properly purged and passified. (Oxidation of ethanethiol may occur in the presence of rust, air,
or water.)
VIII. Exposure Controls/Personal Protection:
Ventilation Requirements:
Use only in well-ventilated areas.
Personal Protective Equipment:
Wednesday, November 17, 2004
Page 3 of 4
MSDS - Material Safety Data Sheet
Product Name: Butane Fuel Canister
MSDS No.: SCW103/5
Safety goggles, gloves
IX. Physical and Chemical Properties:
Boiling Point: -44 F Melting Point: NE
Evaporation Rate (Butyl Acetate = 1): >1 Vapor Pressure (mm Hg.): 5,585
Specific Gravity (H20 = 1): 0.50800 Vapor Density (AIR = 1): 1.5
Solubility In Water: Negligible Appearance and Odor: Colorless liquefied petroleum gas
Other Information: Odor: Odorless, but repulsive if odorant (ethanethiol) has been added
X. Stability and Reactivity:
Stability:
Stable
Incompatibility (Materials to Avoid):
Ignition sources (heat, open flame, spark), oxygen, strong oxidizing agents, rust, moisture
Decomposition/By Products:
Carbon and sulfur dioxides
Hazardous Polymerization:
Does not occur.
XI. Toxicological Information:
XII. Ecological Information:
Prevent from entering sewers or waterways.
XIII. Disposal Considerations:
Dispose according to local, state, and federal regulations.
RCRA classification: Ignitable (D001)
Prior to disposal, consult your environmental contact to determine if TCLP (Toxicity Characteristic Leaching Procedure, EPA Test
Method 1311) is required. Reference 40 CFR Part 261.
XIV. Transport Information:
Keep in tightly closed container. Secure container to prevent damage. Do not puncture or incinerate container. Avoid incompatible
materials. Avoid all ignition sources (heat, open flame, spark). Bond and ground during transfer. Avoid contact with skin, eyes, and
clothing. Avoid breathing vapor. Wash thoroughly after handling.
IATA
Shipping name: Receptacles, small, compressed gas
Hazard class: 2.1
UN no.: 2037
Flammable gas!
Wednesday, November 17, 2004
Page 4 of 4
MSDS - Material Safety Data Sheet
Product Name: Butane Fuel Canister
MSDS No.: SCW103/5
XV. Regulatory Information:
This product meets the following hazard definitions as defined by the Occupational Safety and Health Hazard Communication
Standard (29 CFR Section 1910.1200): compressed gas, flammable gas, health hazard.
This material is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
XVI. Other Information:
Be aware that with odorized product, the intensity of ethanethiol stench (its odor) may fade due to chemical oxidation (in the
presence of rust, air, or moisture), adsorption, or absorption. Some people have nasal perception problems and may not be able to
smell the ethanethiol stench. Other odors may mask or hide the ethanethiol stench. While ethanethiol may not impart the warning
of the presence of propane in every instance, it is generally effective in a majority of situations. Familiarize yourself with this
warning, and other facts associated with the so-called "odor-fade phenomenon."
Using this product under normal, properly instructed procedures should not be hazardous.
The information above is believed to be accurate and represents the best information currently available to us. However, we make
no warranty of merchantability or any other warranty, expressed or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigation to determine the suitability of the information for their
particular purposes.
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