MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 1 of 10
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MAPEI PLANICRETE
SYNONYMS
"synthetic latex dispersion"
PRODUCT USE
Synthetic resin latex.
SUPPLIER
Company: Mapei Australia P/L
Address:
12 Parkview Drive
Archerfield
QLD, 4108
AUS
Telephone: +61 7 3276 5000
Fax: +61 7 3276 5076
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to
the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Ingestion may produce health damage*.
May produce discomfort of the eyes and skin*.
* (limited evidence).
SAFETY
Do not breathe gas/fumes/vapour/spray.
Wear eye/face protection.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
polymer dispersion 10-60
calcium chloride 10043-52-4 <5
water 7732-18-5 30-60
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 2 of 10
Section 4 - FIRST AID MEASURES
SWALLOWED
鈥? For advice, contact a Poisons Information Centre or a doctor at once.
鈥? Urgent hospital treatment is likely to be needed.
鈥? If swallowed do NOT induce vomiting.
鈥? If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
鈥? Observe the patient carefully.
鈥? Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
鈥? Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
鈥? Transport to hospital or doctor without delay.
EYE
If this product comes in contact with the eyes:
鈥? Wash out immediately with fresh running water.
鈥? Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
鈥? If pain persists or recurs seek medical attention.
鈥? Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
鈥? Immediately remove all contaminated clothing, including footwear
鈥? Flush skin and hair with running water (and soap if available).
鈥? Seek medical attention in event of irritation.
INHALED
鈥? If fumes or combustion products are inhaled remove from contaminated area.
鈥? Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
鈥? There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Wear breathing apparatus plus protective gloves for fire only.
鈥? Prevent, by any means available, spillage from entering drains or water
courses.
鈥? Use fire fighting procedures suitable for surrounding area.
鈥? DO NOT approach containers suspected to be hot.
鈥? Cool fire exposed containers with water spray from a protected location.
鈥? If safe to do so, remove containers from path of fire.
鈥? Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
鈥? Non combustible.
鈥? Not considered to be a significant fire risk.
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 3 of 10
Section 5 - FIRE FIGHTING MEASURES
鈥? Expansion or decomposition on heating may lead to violent rupture of
containers.
鈥? Decomposes on heating and may produce toxic/ irritating fumes.
鈥? May emit acrid smoke.
FIRE INCOMPATIBILITY
None known.
HAZCHEM
None
Personal Protective Equipment
PERSONAL PROTECTION EQUIPMENT
Gloves, boots (chemical resistant).
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
鈥? Clean up all spills immediately.
鈥? Avoid breathing vapours and contact with skin and eyes.
鈥? Control personal contact by using protective equipment.
鈥? Contain and absorb spill with sand, earth, inert material or vermiculite.
鈥? Wipe up.
鈥? Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
鈥? Clear area of personnel and move upwind.
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Wear breathing apparatus plus protective gloves.
鈥? Prevent, by any means available, spillage from entering drains or water
course.
鈥? Stop leak if safe to do so.
鈥? Contain spill with sand, earth or vermiculite.
鈥? Collect recoverable product into labelled containers for recycling.
鈥? Neutralise/decontaminate residue.
鈥? Collect solid residues and seal in labelled drums for disposal.
鈥? Wash area and prevent runoff into drains.
鈥? After clean up operations, decontaminate and launder all protective clothing
and equipment before storing and re-using.
鈥? If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
calcium chloride 400 mg/m鲁
water 500 mg/m鲁
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
calcium chloride 20 mg/m鲁
water 500 mg/m鲁
other than mild, transient adverse effects
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 4 of 10
Section 6 - ACCIDENTAL RELEASE MEASURES
without perceiving a clearly defined odour is:
calcium chloride 3.5 mg/m鲁
water 500 mg/m鲁
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
calcium chloride 1 mg/m鲁
water 500 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
鈥? Avoid all personal contact, including inhalation.
鈥? Wear protective clothing when risk of exposure occurs.
鈥? Use in a well-ventilated area.
鈥? Avoid contact with moisture.
鈥? Avoid contact with incompatible materials.
鈥? When handling, DO NOT eat, drink or smoke.
鈥? Keep containers securely sealed when not in use.
鈥? Avoid physical damage to containers.
鈥? Always wash hands with soap and water after handling.
鈥? Work clothes should be laundered separately. Launder contaminated clothing
before re-use.
鈥? Use good occupational work practice.
鈥? Observe manufacturer's storing and handling recommendations.
鈥? Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
DO NOT allow clothing wet with material to stay in contact with skin.
SUITABLE CONTAINER
鈥? Polyethylene or polypropylene container.
鈥? Packing as recommended by manufacturer
鈥? Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
None known.
STORAGE REQUIREMENTS
鈥? Store in original containers.
鈥? Keep containers securely sealed.
鈥? Store in a cool, dry, well-ventilated area.
鈥? Store away from incompatible materials and foodstuff containers.
鈥? Protect containers against physical damage and check regularly for leaks.
鈥? Observe manufacturer's storing and handling recommendations.
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 5 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available for calcium chloride as (CAS: 10043-52-4)
No data available for water as (CAS: 7732-18-5)
Not available. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :10 mg/m鲁.
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) (mg/m鲁):
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%).
Component Breathing Zone Mixture Conc
(mg/m鲁) (%)
calcium chloride 10.0000 5.0
INGREDIENT DATA
CALCIUM CHLORIDE:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁.
WATER:
No exposure limits set by NOHSC or ACGIH.
PERSONAL PROTECTION
EYE
鈥? Safety glasses with side shields.
鈥? Chemical goggles.
鈥? Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens
or restrictions on use, should be created for each workplace or task. This
should include a review of lens absorption and adsorption for the class of
chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be
readily available. In the event of chemical exposure, begin eye irrigation
immediately and remove contact lens as soon as practicable. Lens should be
removed at the first signs of eye redness or irritation - lens should be removed
in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
鈥? Overalls.
鈥? P.V.C. apron.
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
鈥? Barrier cream.
鈥? Skin cleansing cream.
鈥? Eye wash unit.
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection: water
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Protective Material CPI *.
________________________________
BUTYL A
NEOPRENE A
VITON A
PVA C
NATURAL RUBBER C
________________________________
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Protective Material CPI *.
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove,
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
of gloves which might otherwise be unsuitable following long-term or frequent
use. A qualified practitioner should be consulted.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 -AUS P -
1000 50 - -AUS P
5000 50 Airline * -
5000 100 - -2 P
10000 100 - -3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use
determine the type of personal protective equipment required.
For further information consult site specific CHEMWATCH data (if
available), or your Occupational Health and Safety Advisor.
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of very high rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood-local control only
motion
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
White liquid with a typical odour; disperses in water.
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 8 of 10
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Molecular Weight: Not applicable Boiling Range (掳C): 100
Melting Range (掳C): Not available Specific Gravity (water=1): 1.01
Solubility in water (g/L): dispersable pH (as supplied): 10
pH (1% solution): Not available Vapour Pressure (kPa): Not available
Volatile Component (%vol): Not available Evaporation Rate: Not available
Relative Vapour Density (air=1): Not available Flash Point (掳C): Not available
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (掳C): Not available Decomposition Temp (掳C): Not available
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
鈥? Presence of incompatible materials.
鈥? Product is considered stable.
鈥? Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the
individual.
EYE
There is some evidence to suggest that this material can cause eye irritation
and damage in some persons.
SKIN
There is some evidence to suggest that this material can cause inflammation of
the skin on contact in some persons.
Skin contact is not thought to have harmful health effects (as classified under
EC Directives); the material may still produce health damage following entry
through wounds, lesions or abrasions.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
The material may cause skin irritation after prolonged or repeated exposure and
may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
INHALED
The material is not thought to produce either adverse health effects or
irritation of the respiratory tract following inhalation (as classified by EC
Directives using animal models). Nevertheless, adverse systemic effects have
been produced following exposure of animals by at least one other route and good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 9 of 10
Section 11 - TOXICOLOGICAL INFORMATION
CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects
adverse to the health (as classified by EC Directives using animal models);
nevertheless exposure by all routes should be minimised as a matter of course.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
CALCIUM CHLORIDE:
TOXICITY IRRITATION
Oral (rat) LD50: 1000 mg/kg Skin (unknown): Moderate*
Eye (unknown): severe* [ICI]
WATER:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
CALCIUM CHLORIDE:
Fish LC50 (96hr.) (mg/l): 8.4 (24hr)
Section 13 - DISPOSAL CONSIDERATIONS
鈥? Recycle wherever possible.
鈥? Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility
can be identified.
鈥? Dispose of by: Burial in a licenced land-fill or Incineration in a licenced
apparatus (after admixture with suitable combustible material)
鈥? Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Dangerous Goods Class: None
Subrisk: None
UN/NA Number: None
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO Dangerous Goods class: None
IMO Packing group: None
IATA Dangerous goods class: None
Cargo Instructions:
Cargo Max:
Passenger Instructions:
Passenger Max:
Special Provisions: None, None
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MAPEI PLANICRETE
Chemwatch Material Safety Data Sheet CHEMWATCH 5046-26
Issue Date: Fri 1-Apr-2005 CD 2005/3 Page 10 of 10
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
calcium chloride (CAS: 10043-52-4) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
Australia High Volume Industrial Chemical List (HVICL)
water (CAS: 7732-18-5) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Fri 1-Apr-2005
Print Date: Tue 15-Nov-2005
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