DATE: 3/18/2008
KEY92 Plastic and Fiberglass Parts Cleaner
MATERIAL SAFETY DATA SHEET
THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this MSDS before handling and disposing of this product.
Pass this information on to employees, customers, & users of this product.
SECTION 1. CHEMICAL PRODUCTS & COMPANY IDENTIFICATION / HAZARD RATINGS
PRODUCT IDENTITY: KEY92 Plastic and Fiberglass Parts Cleaner HEALTH RATINGS:
SAP MATERIAL NO. 5036022 000 00B
COMPANY IDENTITY: Keystone Automotive Industries HEALTH (NFPA) = 1
COMPANY ADDRESS: 700 East Bonita Avenue HEALTH (HMIS) = 1
Pomona, CA 91767 FLAMMABILITY = 3
COMPANY PHONE: 1-800-772-5557 REACTIVITY = 0
CHEMTREC PHONE: 1-800-424-9300
2. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient(s) CAS Number % (by weight)
ISOBUTANOL 78-83-1 70.0 - 74.0
ALIPHATIC HYDROCARBONS (STODDARD TYPE) 64742-89-8 7.0 鈥? 11.0
3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Eye:
Can cause eye irritation. Symptoms include stinging, tearing, redness and swelling of eyes. Can injure eye tissue.
Skin:
Can cause skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning,
and drying and cracking of skin, and burns and other skin damage. Passage of this material into the body through the
skin is possible, but is unlikely that this would result in harmful effects during safe handling and use.
Swallowing:
Swallowing small amounts this material during normal handling is not likely to cause harmful effects. Swallowing large
amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung
inflammation and other lung injury.
Inhalation:
Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to
cause harmful effects. Breathing large amounts may be harmful. Symptoms usually occur at air concentrations
higher than the recommended exposure limits (See Section 8).
Symptoms of Exposure:
Signs and symptoms of exposure to this material through breathing, swallowing and/or passage of the material
through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat,
airways), cough, central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache,
unconsciousness).
1
Target Organ Effects:
Exposure to this material (or a component) has been found to cause kidney damage in male rats. The mechanism by
which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans.
Overexposure to this material (or it鈥檚 components) has been suggested as a cause of the following effects in
laboratory animals: mild, reversible liver effects.
Developmental Information:
No data.
Cancer Information:
Based on the available information, this material cannot be classified with regard to carcinogenicity. This material is
not listed as a carcinogen by the International Agency for Research on Cancer, the National Toxicology Program, or
the Occupational Safety and Health Administration. In studies with small numbers of animals, isobutyl alcohol caused
cancer when given through a stomach tube or when injected under skin. The relevance of these findings to humans is
unknown.
Other Health Effects:
No data.
Primary Route(s) of Entry:
Inhalation, skin absorption, skin contact, eye contact, ingestion.
4. FIRST AID MEASURES
Eyes:
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with
water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.
Skin:
Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is damaged, seek immediate
medical attention. If skin is not damaged and symptoms persist, seek medical attention. Launder clothing before
reuse.
Swallowing:
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the
left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to
induce vomiting. If possible, do not leave individual unattended.
Inhalation:
If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical
attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
Note to Physicians:
This material is an aspiration hazard. Potential danger from aspiration must be weighed against possible oral toxicity
(See Section 3 鈥? Swallowing) when deciding whether to induce vomiting. Preexisting disorders of the following organs
(or organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma-like conditions).
5. FIRE FIGHTING MEASURES
Flash Point:
80.0 - 90.0 F ( 26.6 鈥? 32.2 C) TCC
Explosive Limit:
(for component) Lower 1.0 Upper 20.0%
Auto ignition Temperature:
No data
Hazardous Products of Combustion:
May form: carbon dioxide and carbon monoxide, various hydrocarbons.
Fire and Explosion Hazards:
2
Vapors are heavier than air and may travel along the ground or be moved by ventilation and ignited by pilot lights,
other flames, sparks, heaters, smoking, electric motors, static discharge, or other ignition sources at locations distant
from material handling point. Never use welding or cutting torch on or near drum (even empty) because product (even
just residue) can ignite explosively.
Extinguishing Media:
Regular foam, water fog, carbon dioxide, dry chemical.
Fire Fighting Instructions:
Wear a self-contained breathing apparatus with a full-face piece operated in the positive pressure demand mode with
appropriate turn-out gear and chemical resistant personal protective equipment. Refer to the personal protective
equipment section of this MSDS.
NFPA Rating:
Health - 1, Flammability - 3, Reactivity - 0
6. ACCIDENTAL RELEASE MEASURES
Small Spill:
Eliminate all sources of ignition such as flares, flames (including pilot lights), and electrical sparks. Absorb liquid on
vermiculite, floor absorbent material. Persons not wearing proper personal protective equipment should be excluded
from area of spill.
Large Spill:
Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that
a spill has occurred. Persons not wearing proper personal protective equipment should be excluded from area of spill
until clean-up has been completed. Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks).
7. HANDLING AND STORAGE
Handling:
Containers of this material may be hazardous when emptied. Since emptied containers retain product residues
(vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. All five-gallon pails and
larger metal containers, including tank cars and tank trucks, should be grounded and/or bonded when material is
transferred. Precautions during use: avoid prolonged or frequently repeated skin contact with this material. Skin
contact can be minimized by wearing impervious protective gloves. As with all products of this nature, good personal
hygiene is essential. Hands and other exposed areas should be washed thoroughly with soap and water after contact
especially before eating and/or smoking. Regular laundering of contaminated clothing is essential to reduce indirect
skin contact with this material. Warning. Sudden release of hot organic chemical vapors or mists from process
equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may
result in ignitions without the presence of obvious ignition sources. Published 鈥渁uto ignition鈥? or 鈥渋gnition鈥? temperature
values cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process
conditions. Any use of this product in elevated temperature processes should be thoroughly evaluated to establish
and maintain safe operating conditions.
Storage:
Do not store near extreme heat, open flame, or sources of ignition.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection:
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit
other type safety glasses. Consult your safety representative.
Skin Protection:
Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear
impervious clothing and boots.
Respiratory Protections:
If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH/MSHA
3
approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit
other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your industrial hygienist).
Engineering or administrative controls should be implemented to reduce exposure.
Engineering Controls:
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s).
Exposure Guidelines:
Component
ISOBUTANOL (78-83-1)
OSHA PEL 100.000 ppm - TWA
OSHA VPEL 50.000 ppm - TWA
ACGIH TLV 50.000 ppm - TWA
ACGIH TLV 250.000 ppm - STEL (Skin)
ALIPHATIC HYDROCARBONS (STODDARD TYPE) (8052-41-3)
OSHA PEL 500.000 ppm - TWA
OSHA VPEL 100.000 ppm - TWA
ACGIH TLV 100.000 ppm - TWA
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point:
(for component) 226.0 F (107.7 C)
Vapor Pressure:
(for component) 8.800 mmHg
Specific Vapor Density:
> 1.000 @ AIR = 1
Specific Gravity:
.777 - .809 @ 68.00 F
Liquid Density:
6.610 lbs/gal @ 68.00 F
.777 - .809 kg/l @ 20.00 C
Percent Volatiles:
No data
Evaporation Rate:
SLOWER THAN ETHYL ETHER
Appearance:
CLEAR AND PARTICLE FREE
State:
LIQUID
Physical Form:
HOMOGENOUS SOLUTION
Color:
WATER CLEAR
Odor:
No data
pH:
Not applicable
10. STABILITY AND REACTIVITY
4
Hazardous Polymerization:
Product will not undergo hazardous polymerization.
Hazardous Decomposition:
May form: carbon dioxide and carbon monoxide, various hydrocarbons.
Chemical Stability:
Stable.
Incompatibility:
Avoid contact with: strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
No data.
12. ECOLOGICAL INFORMATION
No data.
13. DISPOSAL CONSIDERATION
Waste Management Information:
Dispose of in accordance with all applicable local, state and federal regulations. Do not discharge effluent containing
this product into lakes, streams, ponds or estuaries, oceans or other waters unless in accordance with the
requirements of a National Pollutant Discharge Elimination System (NPDES) permit, and the permitting authority has
been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without
previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or
Regional Office of the EPA. For assistance with your waste management needs 鈥? including disposal, recycling and
waste stream reduction, contact Ashland Distribution Company, IC&S Environmental Services Group at 800-637-
7922.
14. TRANSPORT INFORMATION
DOT Information - 49 CFR 172.101
DOT Description:
PAINT RELATED MATERIAL, 3, UN1263, III
Container/Mode:
55 gal drum/truck package
NOS Component:
Not Applicable
RQ (Reportable Quantity) - 49 CFR 172.101
Product Quantity (lbs) Component
6869 ISOBUTANOL
15. REGULATORY INFORMATION
US Federal Regulations:
TSCA (Toxic Substances Control Act) Status
TSCA (United States) The intentional ingredients of this product are listed.
CERCLA RQ - 40 CFR 302.4 (a):
Component RQ (lbs)
ISOBUTYL ALCOHOL 5000
SARA 302 Components - 40 CFR 355 Appendix A:
None
5
Section 311/312 Hazard Class - 40 CFR 370.2:
Immediate (X) Delayed (X) Fire (X) Reactive ( ) Sudden Release of Pressure ( )
SARA 313 Components - 40 CFR 372.65:
None
OSHA Process Safety Management - 29 CFR 1910:
None Listed
EPA Accidental Release Prevention - 40 CFR 68:
None Listed
International Regulations
Inventory Status:
Not determined
State and Local Regulations
California Proposition 65:
None
New Jersey RTK Label Information
ISOBUTYL ALCOHOL 78-83-1
STODDARD SOLVENT 8052-41-3
Pennsylvania RTK Label Information
1-PROPANOL, 2-METHYL- 78-83-1
STODDARD SOLVENT 8052-41-3
16. OTHER INFORMATION
The information accumulated herein is believed to be accurate but is not warranted to be whether originating with
the company or not. Recipients are advised to confirm in advance of need that the information is current,
applicable, and suitable to their circumstances.
6
|