DATE: 7/13/2006
KEY90 Wax and Grease Remover
MATERIAL SAFETY DATA SHEET
THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this MSDS before handling and disposing of this product.
Pass this information on to employees, customers, & users of this product.
SECTION 1. CHEMICAL PRODUCTS & COMPANY IDENTIFICATION / HAZARD RATINGS
PRODUCT IDENTITY: Blend #9906 KEY90 Wax and Grease Remover HEALTH RATINGS:
COMPANY IDENTITY: Keystone Automotive Industries HEALTH (NFPA) = 2
COMPANY ADDRESS: 700 East Bonita Avenue HEALTH (HMIS) = 2
Pomona, CA 91767 FLAMMABILITY = 3
COMPANY PHONE: 1-800-772-5557 REACTIVITY = 0
CHEMTREC PHONE: 1-800-424-9300
SECTION 2. INGREDIENT & REGULATORY INFORMATION
All components of this product are on the TSCA list.
SARA Title III Section 313 Supplier Notification
This product contains the indicated <*> toxic chemicals subject to the reporting requirements of Section 313 of
the Emergency Planning & Community Right-To-Know Act of 1986 & of 40 CFR 372. This information must be
included in all MSDSs that are copied and distributed for this material.
SARA TITLE III INGREDIENTS CAS# WT. % (REG.SECTION) RQ (LBS)
Light Aliphatic Solvent Naphtha *64742-89-8 Not Appl. (311, 312) None
Isopropanol 67-63-0 Not Appl. (311, 312) None
*Mixed Xylenes 1330-20-7 6 (311, 312, 313, RCRA) 100
*Ethylbenzene 67-56-1 <5 (311, 312, 313, RCRA) 1000
SARA SECTION 311/312 HAZARDS: Acute Health, Fire
MATERIAL CAS# TWA (OSHA) TLV (ACGIH) HAP
Light Aliphatic Solvent Naphtha *64742-89-8 500 ppm 300 ppm No
Isopropanol 67-63-0 400 ppm 400 ppm No
*Mixed Xylenes 1330-20-7 100 ppm 100 ppm Yes
*Ethylbenzene 67-56-1 100 ppm 100 ppm Yes
In addition to EPA Hazardous Air pollutants showing 鈥榊es鈥? under 鈥淗AP鈥? above, using manufacturers鈥? data, based on
EPA Method 311, the following EPA Hazardous Air Pollutants may be present in trace amounts (less than 0.1%) =
Benzene, Cumene
1
MATERIAL CAS# CEILING STEL (OSHA/ACGIH)
Light Aliphatic Solvent Naphtha *64742-89-8 None Known 5.3E3 ppm
Isopropanol 67-63-0 None Known 500 ppm
*Mixed Xylenes 1330-20-7 None Known 150 ppm
*Ethylbenzene 67-56-1 None Known 125 ppm
THIS PRODUCT MEETS REQUIREMENTS OF SOUTHERN
CALIFORNIA AQMD RULE 443.1 & SIMILAR REGULATIONS
CALIFORNIA PROPOSITION 65: This product contains the following chemicals known to the state of California to
cause cancer & reproductive toxicity: a trace of Benzene
IF > 1472 POUNDS OF THIS PRODUCT IS IN ONE CONTAINER THE 鈥淩Q鈥? IS EXCEEDED.
DOT SHIPPING NAME: Paint Related Material, 3, UN1263, PG II
DRUM LABEL: (FLAMMABLE LIQUID)
SECTION 3. HAZARDS IDENTIFICATION
MATERIAL CAS# LOWEST KNOW LETHAL DOSE DATA
LOWEST KNOWN LD50 (ORAL)
Xylene 1330-20-7 4000.0 mg/kg (Rats)
LOWEST KNOWN LC50 (VAPORS)
Super VM&P *64742-89-8 3400.0 mg/kg (Rats)
THRESHOLD LIMIT VALUE: 260 ppm (Evaporated Blend)
CONTAINS: LIGHT ALIPHATIC SOLVENT NAPHTHA, ISOPROPANOL, MIXED XYLENES, ETHYLBENZENE
WARNING!!
FLAMMABLE!!
ACUTE HAZARDS
EYE & SKIN CONTACT:
Primary irritation to skin, defatting, dermatitis.
Absorption thru skin increases exposure.
Primary irritation to eyes, redness, tearing, blurred vision.
Liquid can cause eye irritation. Wash thoroughly after handling.
INHALATION:
Anesthetic. Irritates respiratory tract. Acute overexposure can cause serious nervous system depression.
Vapor harmful.
Breathing vapor can cause irritation.
Acute overexposure can cause damage to kidneys, blood, nerves, liver & lungs.
SWALLOWING:
Harmful or fatal if swallowed.
Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
SUBCHRONIC HAZARDS / CONDITIONS AGGRAVATED
CONDITIONS AGGRAVATED
Chronic overexposure can cause damage to kidneys, blood, nerves, liver, & lungs.
Persons with severe skin, liver or kidney problems should avoid use.
2
CHRONIC HAZARDS
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
Due to metabolic differences, the results are not relevant in humans.
This product may contain less than 94 ppm of Benzene.
Not considered hazardous in such low concentrations.
Absorption through skin may be harmful. Studies with laboratory animals indicate this product can cause
damage to fetus.
SECTION 4. FIRST AID MEASURES PROCEDURES
EYE CONTACT:
For eyes, flush with plenty of water for 15 minutes & get medical attention.
SKIN CONTACT:
In case of contact with skin immediately remove contaminated clothing.
Wash thoroughly with soap & water. Wash contaminated clothing before reuse. (Discard contaminated shoes)
INHALATION:
After high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped
give artificial respiration. CALL A PHYSICIAN IMMEDIATELY!
SWALLOWING:
If swallowed, CALL A PHYSICIAN IMMEDIATELY! Do NOT induce vomiting.
Have patient lie down & keep warm. Vomiting may lead to pneumonitis, which may be fatal
SECTION 5. FIRE FIGHTING MEASURES
AUTO IGNITION TEMPERATURE: 287 C / 550 F (Lowest Component)
LOWER FLAMMABLE LIMIT IN AIR (% by vol): 1.3
FLASH POINT (TEST METHOD): 12 C / 54 F (TCC) (Lowest Component)
FLAMMABILITY CLASSIFICATION: Class I B
EXTINGUISHING MEDIA
NFPA Class B extinguishers (Carbon Dioxide or foam) for Class I B liquid fires.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray may be ineffective on fire but can protect fire fighters & cool closed containers. Use fog nozzles if
water is used.
Do not enter confined fire-space without full bunker gear. (Helmet with face shield, bunker coats, gloves &
rubber boots).
Use NIOSH approved positive-pressure self-contained breathing apparatus.
UNUSUAL EXPLOSION AND FIRE PROCEDURES
FLAMMABLE!!
Keep container tightly closed.
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Closed containers may explode if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
Empty container very hazardous! Continue all label precautions
SECTION 6. ACCIDENTAL RELEASE MEASURES
SPILL OR LEAK PROCEDURES
Stop spill at source. Dike area & contain. Clean up remainder with absorbent materials. Mop up & dispose of.
3
Persons without proper protection should be kept from area until cleaned up.
WASTE DISPOSAL METHOD
Recycle or dispose of observing local, state & Federal health, safety & pollution laws. If questions exist, contact
the appropriate agencies.
OTHER PRECAUTIONS
Vapors may ignite explosively & spread long distances. Prevent vapor buildup. Put out pilot lights & turn off
heaters, electric equipment & other ignition sources during use & until all vapors are gone.
SECTION 7. HANDLING AND STORAGE
HANDLING
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Use only with adequate ventilation. Avoid breathing of vapor or spray mist.
Avoid contact with skin & eyes.
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier.
Wear gloves, apron & footwear impervious to this material. Wash clothing before reuse.
Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, saw, drill, braze, or weld. Empty
container very hazardous! Continue all label precautions!
STORAGE
Do not store above 49 C / 120 F. Store large amounts in structures made for OSHA Class I B liquids.
Keep container tightly closed & upright when not in use to prevent leakage.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Ventilate to keep vapors of this material below 130 ppm. If over TLV, in accordance with 29 CFR 1910.134, use
NIOSH approved positive-pressure self-contained breathing apparatus. Consult Safety Equipment Supplier. Use
explosion-proof equipment.
VENTILATION
LOCAL EXHAUST = Necessary
MECHANICAL (GENERAL) = Acceptable
SPECIAL = None
OTHER = None
PERSONAL PROTECTIONS:
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier.
Wear gloves, apron & footwear impervious to this material. Wash clothing before reuse.
4
SECTION 9. PHYSICAL DATA
APPEARANCE: Liquid, Water-White
ODOR: Alcohol
BOILING RANGE: 83 127 143 C / 182 261 290 F
GRAVITY @ 60 F:
API: 52.6
SPECIFIC GRAVITY (Water = 1): .769
POUNDS / GALLON: 6.402
VOC鈥橲 (>0.44 LBS / SQ IN): 100.1 Vol. % / 769.5 g/L / 6.409 Lbs/Gal
TOTAL VOC鈥橲 (TVOC): 100.0 Vol. % / 768.6 g/L / 6.402 Lbs/Gal
NONEXEMPT VOC鈥橲 (CVOC): 100.0 Vol. % / 768.6 g/L / 6.402 Lbs/Gal
HAZARDOUS AIR POLLUTANTS (HAPS): 8.5 Wt. % / 65.3 g/L / .543 Lbs/Gal
VAPOR PRESSURE (mm of Hg) @ 20 C: 15.9
NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg) @ 20 C: 15.9
VAPOR DENSITY (air = 1): 3.7
WATER ABSORPTION: Moderate
SOLVENCY PARAMETERS:
HKB (Hydrogen Bonding): 16.8
PKB (Polarity): 34.1
DKB (Dispersion): 49.1
REFRACTIVE INDEX: 1.425
MIXED ANILINE POINT (Acid Insol): 56 C / 133 F
SECTION 10. REACTIVITY DATA
STABILITY
Stable
CONDITIONS TO AVOID
Isolate from oxidizers, heat, sparks, electric equipment, & open flame.
MATERIALS TO AVOID
Isolate from strong oxidizers such as permanganates, chromates, & peroxides.
HAZARDOUS DECOMPOSITION PRODUCTS
Carbon Monoxide, Carbon Dioxide from burning.
HAZARDOUS POLYMERIZATION
Will not occur.
NOTICE
The supplier disclaims all expressed or implied warranties of merchantability or fitness for a specific use, with respect to
the product or the information provided herein, except for conformation to contracted specifications. All information
appearing herein is based upon data obtained from manufacturers and / or recognized technical sources. While the
information is believed to be accurate, we make no representations as to its accuracy or sufficiency. Conditions of use
5
are beyond our control, and therefore users are responsible for verifying the data under their own operating conditions
to determine whether the product is suitable for their particular purposes and they assume all risks of their use,
handling, and disposal of the product. Users also assume all risks in regards to the publication or use of, or reliance
upon, information contained herein. This information relates only to the product designated herein, and does not relate
to its use in combination with any other material or process.
6
|