MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 11/01/1999
MSDS No: A191
Corrosion Inhibitor A191
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: Corrosion Inhibitor A191
Product Description: Rodine 213/214
Product Code: A191
Product Name: Corrosion Inhibitor A191
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376
2. COMPOSITION/INFORMATION ON INGREDIENTS
wt.% CAS Registry #
Proprietary Blend of Chemicals (trade secret) Containing:
Complex substituted keto-amine 50 { 60 70776-86-2
Isopropyl alcohol 1 { 10 67-63-0
Propargyl alcohol 1 { 10 107-19-7
Hydrogen chloride <3 7647-01-0
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier
Isopropyl alcohol 400 ppm 400 ppm
Propargyl alcohol 1 ppm
Hydrogen chloride 5 mg/m3 (ceiling) 5 ppm STEL (ceiling)
COMMENTS:
Isopropanol STEL (ceiling) = 500 mg/m3
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
Flammable liquid.
Corrosive.
Do not get in eyes, on skin or clothing.
Do not breath vapors
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DATE PREPARED: 11/01/1999
MSDS No: A191
Corrosion Inhibitor A191
4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.
SKIN:
Immediately wash with soap and water. Rinse thoroughly. Seek medical attention if e庐ects occur.
Launder contaminated shoes and clothing before reuse.
INGESTION:
DO NOT induce vomiting. Drink large quantities of milk (preferred) or water. Take to hospital
at once.
INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: 68卤 F 20卤 C TAG CC
Flammable Limits: Not Determined
Autoignition Temperature: Not Determined
GENERAL HAZARD:
Vapors may travel along the ground and ignite when an ignition source is contacted.
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.
HAZARDOUS COMBUSTION PRODUCTS:
When heated to decomposition, ammonia, oxides of carbon and nitrogen, cyanides and harmful
organic fumes are released.
EXPLOSION HAZARDS:
Vapors may form explosive mixture with air.
FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.
FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.
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DATE PREPARED: 11/01/1999
MSDS No: A191
Corrosion Inhibitor A191
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Use explosion proof equipment to recover.
Remove all sources of ignition.
Soak up residual on inert absorbant (dry sand, vermiculite or earth).
Put in steel or plastic drum approved for 掳ammables.
7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
STORAGE:
Keep away from heat, sparks, and 掳ame.
Keep container closed when not in use.
Use with adequate ventilation.
Do not cut or weld on container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.
PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.
RESPIRATORY:
Use NIOSH approved respirator with organic vapor/acid gas protection (color coded yellow) in
nonventilated area and/or exposure above TLV. Use SCBA (self-contained breathing apparatus)
in con炉ned areas and for emergencies.
PROTECTIVE CLOTHING:
Face shield, boots, protective suit and impervious (neoprene) gloves.
OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.
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DATE PREPARED: 11/01/1999
MSDS No: A191
Corrosion Inhibitor A191
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Solvent
Color: 213 - Brown, 214 - Red
pH: <2
Percent Volatile: Not Determined
Vapor Pressure: Not Determined
Vapor Density: Not Determined
Boiling Point: Not Determined
Freezing Point: Not Determined
Solubility in Water: Appreciable
Evaporation Rate: Not Determined
Speci炉c Gravity: 1.0 to 1.1 (water=1) at 60卤 F
(VOC): 37.2 % EPA Method 24
10. STABILITY AND REACTIVITY
STABLE: Yes
HAZARDOUS POLYMERIZATION: No
HAZARDOUS DECOMPOSITION:
When heated to decomposition, ammonia, oxides of carbon and nitrogen, cyanides and harmful
organic fumes are released.
INCOMPATIBLE MATERIALS:
Oxidizing materials.
11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Corrosive. Rapidly causes pain, burns, corneal injury. May cause permanent damage and
blindness.
Skin: Irritant. May cause pain, redness, dermatitis. May be absorbed in toxic amounts.
Ingestion: Irritant. May cause pain or discomfort to mouth, throat and stomach. Harmful if
swallowed. Large amounts may cause illness or death.
Inhalation: Severe irritant. Causes pain, choking, coughing, burning sensation. Can cause soreness.
TARGET ORGANS:
Liver, Kidneys
GENERAL COMMENTS:
Carcinogens: Not listed by IARC, USA NTP, or USA OSHA.
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DATE PREPARED: 11/01/1999
MSDS No: A191
Corrosion Inhibitor A191
12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
Degradability: Partially biodegradable.
Fish Toxicity: No information available
13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Ship via permitted waste hauler to permitted hazardous waste disposal facility for incineration.
EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse with an
appropriate solvent, crush, and ship to sanitary land炉ll unless prohibited by local regulations.
RCRA/USEPA WASTE INFORMATION:
RCRA Hazardous Waste Number: D001 (ignitable), D002 (corrosive), P102 (propargyl alcohol)
COMMENTS:
Always follow ALL applicable federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: Flammable Liquids, Corrosive, N.O.S. (contains isopropanol, hydrochloric
acid)
Hazard Class: 3
NA/UN Number: UN2924
Packing Group: II
Reportable Quantity (RQ) Under CERCLA: 1090 gal
Placards: Flammable Liquid
Label: Flammable Liquid - 3, Corrosive - 8
SPECIAL SHIPPING NOTES:
If RQ is exceeded in a single container, material ia a HAZARDOUS MATERIAL AND HAZ-
ARDOUS SUBSTANCE; add the letters RQ to the begining of the shipping description.
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DATE PREPARED: 11/01/1999
MSDS No: A191
Corrosion Inhibitor A191
15. REGULATORY INFORMATION
DOT Label Symbol and Statement of Hazard
DOT Corrosive
DOT Flammable Liquid
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Fire: Yes Pressure Generating: No Reactivity: No Acute: Yes Chronic: Yes
313 Reportable Ingredients:
Propargyl Alcohol
Hydrochloric acid
Title III Notes: This product contains substances which are de炉ned as toxic chemicals under the
reporting requirements of Section 302 (40CFR355 Appendix A) and/or Section 313 (40 CFR
Part 372).
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: 1090 gal
EPA
EPA RQ Ingredient:
Hydrogen chloride (5000 lb)
Propargyl alcohol (1000 lb)
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.
STATE REGULATIONS
PROPOSITION 65 STATEMENT:
This product does not contain any substance(s) which are de炉ned by the state of California to
cause cancer, birth defects, or other reproductive e庐ects.
16. OTHER INFORMATION
Page: 7
DATE PREPARED: 11/01/1999
MSDS No: A191
Corrosion Inhibitor A191
Approved by: Charles M. Maddin, PhD, FAIC
Approval date: 11/01/1999
REVISION SUMMARY
Revision #: 6
This MSDS replaces the October 07, 1999 MSDS. Any changes in information are as follows:
In Section 1
Date Prepared
In Section 14
Reportable Quantity
NFPA CODES
Fire: 3 Health: 3 Reactivity: 0
HMIS CODES
Fire: 3 Health: 3 Reactivity: 0
MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.
The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.
HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.
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