MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 10/07/1999
MSDS No: A254
Corrosion Inhibitor A254
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: Corrosion Inhibitor A254
Product Code: A254
Product Name: Corrosion Inhibitor A254
Chemical Family: Inhibitor
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376
2. COMPOSITION/INFORMATION ON INGREDIENTS
wt.% CAS Registry #
Proprietary Blend of Organic Chemicals (trade secret) Including
Isopropyl alcohol 21 67-63-0
Formic acid 12 64-18-6
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier
Isopropyl alcohol 400 ppm 400 ppm
Formic acid 5 ppm 5 ppm
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
Flammable liquid.
Corrosive.
Do not get in eyes, on skin or clothing.
Do not breath vapors
4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.
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DATE PREPARED: 10/07/1999
MSDS No: A254
Corrosion Inhibitor A254
SKIN:
Immediately wash with soap and water. Rinse for 30 minutes. See a doctor at once. Destroy
contaminated shoes and clothing.
INGESTION:
DO NOT induce vomiting. Drink large quantities of milk (preferred) or water and give milk of
magnesia. Take to hospital at once.
INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: 50卤 F 10卤 C SETA Flash CC
Flammable Limits: Not Determined
Autoignition Temperature: Not Determined
GENERAL HAZARD:
Vapors may travel along the ground and ignite when an ignition source is contacted.
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.
HAZARDOUS COMBUSTION PRODUCTS:
When heated strongly or burned, ammonia, hydrogen chloride, oxides of carbon and nitrogen,
cyanides and harmful organic fumes are released.
EXPLOSION HAZARDS:
Vapors may form explosive mixture with air.
FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.
FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Use explosion proof equipment to recover.
Remove all sources of ignition.
Soak up residual on inert absorbant (dry sand, vermiculite or earth).
Put in steel or plastic drum approved for 掳ammables.
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DATE PREPARED: 10/07/1999
MSDS No: A254
Corrosion Inhibitor A254
7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
STORAGE:
Keep away from heat, sparks, and 掳ame.
Keep container closed when not in use.
Use with adequate ventilation.
Do not cut or weld on container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.
PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.
RESPIRATORY:
Use NIOSH approved respirator with organic vapor/acid gas protection (color coded yellow) in
nonventilated area and/or exposure above TLV. Use SCBA (self-contained breathing apparatus)
in con炉ned areas and for emergencies.
PROTECTIVE CLOTHING:
Face shield, boots, protective suit and impervious (neoprene) gloves.
OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Pungent
Color: Amber
pH: <1
Percent Volatile: 65
Vapor Pressure: Not Determined
Vapor Density: >1 (Air = 1)
Boiling Point: 220卤 F 104卤 C
Freezing Point: <-60卤 F -51卤 C
Solubility in Water: 禄45 at 77卤 F
Speci炉c Gravity: 1.0
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DATE PREPARED: 10/07/1999
MSDS No: A254
Corrosion Inhibitor A254
COMMENTS:
Freezing Point: Equals Pour Point
Water Solubility: Solubility listed above is grams per 100 grams.
10. STABILITY AND REACTIVITY
STABLE: Yes
HAZARDOUS POLYMERIZATION: No
HAZARDOUS DECOMPOSITION:
When heated strongly or burned, ammonia, hydrogen chloride, oxides of carbon and nitrogen,
cyanides and harmful organic fumes are released.
INCOMPATIBLE MATERIALS:
Oxidizing materials.
11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Corrosive. Rapidly causes pain, burns, corneal injury. May cause permanent damage and
blindness.
Skin: Corrosive. Rapidly causes pain, burns, redness, swelling and damage to tissue. Not likely
to be absorbed in toxic amounts.
Ingestion: Corrosive. Causes pain and severe burns to mouth, throat and stomach.
Inhalation: Irritant. May cause pain and coughing.
TARGET ORGANS:
Liver, Kidneys
GENERAL COMMENTS:
Carcinogens: Not listed by IARC, USA NTP, or USA OSHA.
COMMENTS:
Only selected Registry of Toxic E庐ects of Chemical Substances (RTECS) data is presented in this
document. See the actual entry(s) in RTECS for complete information.
12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
Degradability: Biodegradable.
Fish Toxicity: No information available
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DATE PREPARED: 10/07/1999
MSDS No: A254
Corrosion Inhibitor A254
13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Ship via permitted waste hauler to permitted hazardous waste disposal facility for incineration.
EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse, crush, and
ship to sanitary land炉ll unless prohibited by local regulations.
RCRA/USEPA WASTE INFORMATION:
RCRA Hazardous Waste Number: D001, D002
COMMENTS:
Always follow ALL applicable federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: Flammable Liquid, Corrosive, N.O.S. (contains isopropanol and formic
acid)
Hazard Class: 3
NA/UN Number: UN2924
Packing Group: II
Reportable Quantity (RQ) Under CERCLA: 5000 gal
Placards: Flammable Liquid
SPECIAL SHIPPING NOTES:
Material is a HAZARDOUS MATERIAL AND HAZARDOUS SUBSTANCE. Add the letters
RQ to the beginning of the shipping description if RQ is exceeded in a single container.
15. REGULATORY INFORMATION
DOT Label Symbol and Statement of Hazard
DOT Corrosive
DOT Flammable Liquid
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DATE PREPARED: 10/07/1999
MSDS No: A254
Corrosion Inhibitor A254
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Fire: Yes Pressure Generating: No Reactivity: No Acute: Yes Chronic: No
313 Reportable Ingredients: None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: 5000 gal
EPA
EPA RQ Ingredient: formic acid
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.
STATE REGULATIONS
PROPOSITION 65 STATEMENT:
This product does not contain any substance(s) which are de炉ned by the state of California to
cause cancer, birth defects, or other reproductive e庐ects.
16. OTHER INFORMATION
Approved by: Charles M. Maddin, PhD, FAIC
Approval date: 10/07/1999
REVISION SUMMARY
Revision #: 6
This MSDS replaces the August 24, 1999 MSDS. Any changes in information are as follows:
In Section 1
Date Prepared
NFPA CODES
Fire: 3 Health: 3 Reactivity: 0
HMIS CODES
Fire: 3 Health: 3 Reactivity: 0
MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.
The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.
HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.
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