MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 10/08/1999
MSDS No: F306
PEN 6 Surfactant
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: PEN 6 Surfactant
Product Code: F306
Product Name: PEN 6 Surfactant
Chemical Family: Surface active agent
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376
2. COMPOSITION/INFORMATION ON INGREDIENTS
wt.% CAS Registry #
Proprietary Surfactant Formulation (trade secret) Containing:
Isopropyl alcohol 11 { 30 67-63-0
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier
Isopropyl alcohol 400 ppm 400 ppm
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
Flammable liquid and vapor.
4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.
SKIN:
Immediately wash with soap and water. Rinse thoroughly. Seek medical attention if e庐ects occur.
Launder contaminated shoes and clothing before reuse.
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DATE PREPARED: 10/08/1999
MSDS No: F306
PEN 6 Surfactant
INGESTION:
DO NOT induce vomiting. Drink large quantities of milk (preferred) or water. Take to hospital
at once.
INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: 86卤 F 30卤 C TAG CC
Flammable Limits: Not determined
Autoignition Temperature: Not Determined
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.
HAZARDOUS COMBUSTION PRODUCTS:
Oxides of carbon and harmful organic chemical fumes.
EXPLOSION HAZARDS:
Vapors may form explosive mixture with air.
FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.
FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Use explosion proof equipment to recover.
Remove all sources of ignition.
Soak up residual on inert absorbant (dry sand, vermiculite or earth).
Put in steel or plastic drum approved for 掳ammables.
7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
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DATE PREPARED: 10/08/1999
MSDS No: F306
PEN 6 Surfactant
STORAGE:
Keep away from heat, sparks, and 掳ame.
Keep container closed when not in use.
Use with adequate ventilation.
Store away from oxidizers.
Do not cut or weld on container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.
PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.
RESPIRATORY:
Use NIOSH approved respirator with organic vapor/acid gas protection (color coded yellow) in
nonventilated area and/or exposure above TLV. Use SCBA (self-contained breathing apparatus)
in con炉ned areas and for emergencies.
PROTECTIVE CLOTHING:
Clean body covering and chemical resistant gloves.
OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Alcoholic
Color: Light yellow
pH: 10 to 11
Percent Volatile: 15
Vapor Pressure: Not Determined
Vapor Density: Not Determined
Boiling Point: Not Determined
Freezing Point: -25卤 F -31卤 C
Solubility in Water: Soluble
Speci炉c Gravity: 1.027 (water=1)
COMMENTS:
pH: pH listed above is for a 5% solution
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DATE PREPARED: 10/08/1999
MSDS No: F306
PEN 6 Surfactant
10. STABILITY AND REACTIVITY
STABLE: Yes
HAZARDOUS POLYMERIZATION: No
HAZARDOUS DECOMPOSITION:
When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are
released.
INCOMPATIBLE MATERIALS:
Oxidizing materials.
11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Severe irritant. Causes pain and redness. Prolonged or repeated contact may cause mild
burn.
Skin: Irritant. May cause pain, redness, dermatitis.
Ingestion: Can be fatal or cause blindness.
Cannot be made non-toxic; 100 mL can kill humans.
May cause narcosis, headache.
Inhalation: High concentrations cause narcosis. Harmful if inhaled repeatedly or for long periods.
May cause dizziness or headache.
TARGET ORGANS:
May a庐ect liver, nervous system.
May cause blindness.
Eliminated from the body slowly so should be treated as a cumulative poison.
E庐ects may be delayed.
GENERAL COMMENTS:
Carcinogens: Not listed by IARC, USA NTP, or USA OSHA.
12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
Degradability: Partially biodegradable.
Fish Toxicity: Toxic to 炉sh. Do not allow to enter waterways.
13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Ship via permitted waste hauler to permitted hazardous waste disposal facility for incineration.
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DATE PREPARED: 10/08/1999
MSDS No: F306
PEN 6 Surfactant
EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse with an
appropriate solvent, crush, and ship to sanitary land炉ll unless prohibited by local regulations.
RCRA/USEPA WASTE INFORMATION:
RCRA Hazardous Waste Number: D001
COMMENTS:
Always follow ALL applicable federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: Isopropanol Solution
Hazard Class: 3
NA/UN Number: UN1219
Packing Group: II
Reportable Quantity (RQ) Under CERCLA: None
Placards: Flammable Liquid
Label: Flammable Liquid - 3
15. REGULATORY INFORMATION
DOT Label Symbol and Statement of Hazard
DOT Flammable Liquid
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Fire: Yes Pressure Generating: No Reactivity: No Acute: Yes Chronic: No
313 Reportable Ingredients: isopropanol (11 - 30%)
Title III Notes: This product contains substances which are de炉ned as toxic chemicals under
the reporting requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (40 CFR Part 372).
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: Not established
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DATE PREPARED: 10/08/1999
MSDS No: F306
PEN 6 Surfactant
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.
STATE REGULATIONS
PROPOSITION 65 STATEMENT:
This product does not contain any substance(s) which are de炉ned by the state of California to
cause cancer, birth defects, or other reproductive e庐ects.
16. OTHER INFORMATION
REASON FOR ISSUE:
Biannual review
Approved by: Charles M. Maddin, PhD, FAIC
Approval date: 10/08/1999
REVISION SUMMARY
Revision #: 3
This MSDS replaces the November 13, 1998 MSDS. Any changes in information are as follows:
In Section 16
Reason for Issue Date Prepared
In Section 4
Firstaid - Ingestion
In Section 8
Clothing Protection
In Section 9
Odor (Group Field) for (pH) (pH) (from) (pH) (to) (pH) Comments (Group Field) for Vapor
Pressure
In Section 11
Acute Skin
NFPA CODES
Fire: 3 Health: 2 Reactivity: 0
HMIS CODES
Fire: 3 Health: 2 Reactivity: 0
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DATE PREPARED: 10/08/1999
MSDS No: F306
PEN 6 Surfactant
MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.
The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.
HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.
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