MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 11/01/1999
MSDS No: A400
Corrosion Inhibitor A400
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: Corrosion Inhibitor A400
Product Description: Low-surfactant formulation of A224 (OSI 1A)
Product Code: A400
Product Name: Corrosion Inhibitor A400
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376
2. COMPOSITION/INFORMATION ON INGREDIENTS
wt.% CAS Registry #
Proprietary Organic Amine Formulation (trade secret) Containing
Ethylene glycol 11 { 30 107-21-1
Aromatic Petroleum Solvent 11 { 30 64741-67-9
Naphthalene 1{3 91-20-3
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier
Ethylene glycol Not Listed 100 ppm STEL (ceiling)
Naphthalene 10 ppm 10 ppm
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
Combustible liquid.
4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.
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DATE PREPARED: 11/01/1999
MSDS No: A400
Corrosion Inhibitor A400
SKIN:
Immediately wash with soap and water. Rinse thoroughly. Seek medical attention if e庐ects occur.
Launder contaminated clothing before reuse. Destroy contaminated shoes.
INGESTION:
DO NOT induce vomiting. Drink large quantities of milk (preferred) or water. Take to hospital
at once.
INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: 168卤 F 76卤 C TAG CC
Flammable Limits: Not Determined
Autoignition Temperature: Not Determined
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.
HAZARDOUS COMBUSTION PRODUCTS:
When heated to decomposition or burned, ammonia, nitrogen oxides, cyanides, oxides of carbon
and harmful organic fumes may be generated.
EXPLOSION HAZARDS:
Combustible Liquid. Can form explosive mixtures at temperatures at or above the 掳ash point.
FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.
FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Use explosion proof equipment to recover.
Remove all sources of ignition.
Soak up residual on inert absorbant (dry sand, vermiculite or earth).
Put in steel or plastic drum approved for 掳ammables.
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DATE PREPARED: 11/01/1999
MSDS No: A400
Corrosion Inhibitor A400
7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
STORAGE:
Keep away from heat, sparks, and 掳ame.
Keep container closed when not in use.
Use with adequate ventilation.
Do not cut or weld on container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.
PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.
RESPIRATORY:
Use NIOSH approved respirator with organic vapor/acid gas protection (color coded yellow) in
nonventilated area and/or exposure above TLV. Use SCBA (self-contained breathing apparatus)
in con炉ned areas and for emergencies.
PROTECTIVE CLOTHING:
Face shield, boots, protective suit and impervious (neoprene) gloves.
OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Amine
Color: Brown
pH: 4.5
Percent Volatile: 20
Vapor Pressure: Not Determined
Vapor Density: >1 (Air = 1)
Boiling Point: 350 to 750卤 F 177 to 399卤 C
Freezing Point: 30卤 F -1卤 C
Solubility in Water: Disperses
Speci炉c Gravity: 1.04 (water=1)
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DATE PREPARED: 11/01/1999
MSDS No: A400
Corrosion Inhibitor A400
COMMENTS:
pH: pH listed above is for a 10% solution in water
10. STABILITY AND REACTIVITY
STABLE: Yes
HAZARDOUS POLYMERIZATION: No
CONDITIONS TO AVOID:
Keep away from heat, sparks and 掳ame.
HAZARDOUS DECOMPOSITION:
When heated to decomposition or burned, ammonia, nitrogen oxides, cyanides, oxides of carbon
and harmful organic fumes may be generated.
INCOMPATIBLE MATERIALS:
Oxidizing materials.
11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Severe irritant. Causes pain and redness. Prolonged or repeated contact may cause mild
burn.
Skin: Irritant. May cause pain, redness, dermatitis. Not likely to be absorbed in toxic amounts.
Ingestion: Irritant. May cause pain or discomfort to mouth, throat and stomach. Harmful if
swallowed. Large amounts may cause illness or death.
Inhalation: No e庐ect expected. Prolonged or repeated exposure may cause mild irritation. Mist
is irritating.
TARGET ORGANS:
Skin, Eyes, Respiratory Tract, Liver, Kidneys
GENERAL COMMENTS:
Carcinogens: Not listed by IARC, USA NTP, or USA OSHA.
COMMENTS:
Only selected Registry of Toxic E庐ects of Chemical Substances (RTECS) data is presented in this
document. See the actual entry(s) in RTECS for complete information.
12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
No environmental data for this material are currently available.
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DATE PREPARED: 11/01/1999
MSDS No: A400
Corrosion Inhibitor A400
13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Dispose of in accordance with ALL applicable federal, state and local regulations.
EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse with an
appropriate solvent, crush, and ship to sanitary land炉ll unless prohibited by local regulations.
RCRA/USEPA WASTE INFORMATION:
This material is not a RCRA regulated material.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: Petroleum Products, N.O.S.
Combustible Class: Yes
NA/UN Number: UN1268
Packing Group: III
Reportable Quantity (RQ) Under CERCLA: 384 gal
Placards: Combustible Liquid
Label: None
SPECIAL SHIPPING NOTES:
This material is not regulated in packages of 119 gallons or less.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Fire: Yes Pressure Generating: No Reactivity: No Acute: Yes Chronic: Yes
313 Reportable Ingredients: Ethylene Glycol (<27%)
Naphthalene (<3%)
Title III Notes: This product contains substances which are de炉ned as toxic chemicals under
the reporting requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (40 CFR Part 372).
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: 384 gal
EPA
EPA RQ Ingredient: Naphthalene
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DATE PREPARED: 11/01/1999
MSDS No: A400
Corrosion Inhibitor A400
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.
STATE REGULATIONS
PROPOSITION 65 STATEMENT:
This product does not contain any substance(s) which are de炉ned by the state of California to
cause cancer, birth defects, or other reproductive e庐ects.
16. OTHER INFORMATION
Approval date: 11/01/1999
REVISION SUMMARY
Revision #: 10
This MSDS replaces the October 07, 1999 MSDS. Any changes in information are as follows:
In Section 1
Date Prepared
In Section 14
DOT Hazard Class UN/NA Number Placards
NFPA CODES
Fire: 2 Health: 2 Reactivity: 0
HMIS CODES
Fire: 2 Health: 2 Reactivity: 0
MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.
The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.
HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.
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