MATERIAL SAFETY DATA SHEET
Page: 1
DATE PREPARED: 11/01/1999
MSDS No: A401
Cronox 230 Corrosion Inhibitor
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identi炉er: Cronox 230 Corrosion Inhibitor
Product Code: A401
Product Name: Cronox 230 Corrosion Inhibitor
MANUFACTURER: 24 HR. EMERGENCY TELEPHONE
HydroChem Industrial Services, Inc. NUMBERS:
900 Georgia Ave. Emergency Contact: HydroChem ER
Deer Park, TX 77536 Emergency Phone (800) 569-4889
Customer Service: (800) 934-9376
2. COMPOSITION/INFORMATION ON INGREDIENTS
wt.% CAS Registry #
Proprietary Blend of Chemicals (trade secret) Containing:
Heavy Aromatic Naphtha 64742-94-5
Propargyl alcohol <17 107-19-7
Ethylene glycol <17 107-21-1
Isopropyl alcohol <5 67-63-0
Naphthalene <3 91-20-3
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier
Propargyl alcohol 1 ppm
Ethylene glycol Not Listed 100 ppm STEL (ceiling)
Isopropyl alcohol 400 ppm 400 ppm
Naphthalene 10 ppm 10 ppm
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
Combustible liquid.
Irritating to eyes, respiratory system and skin.
Page: 2
DATE PREPARED: 11/01/1999
MSDS No: A401
Cronox 230 Corrosion Inhibitor
4. FIRST AID MEASURES
EYES:
Immediately 掳ush eyes with water for 30 minutes while holding eyelids open. Seek medical at-
tention.
SKIN:
Immediately wash with soap and water for 30 minutes. See a doctor if irritation occurs. Launder
contaminated shoes and clothing before reuse.
INGESTION:
DO NOT induce vomiting. Drink large quantities of milk (preferred) or water. Take to hospital
at once.
INHALATION:
Remove to fresh air. See a doctor if e庐ects occur.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: 108卤 F TAG CC
Flammable Limits: Not Determined
Autoignition Temperature: Not Determined
GENERAL HAZARD:
Vapors may travel along the ground and ignite when an ignition source is contacted.
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, dry chemical or water spray when 炉ghting 炉res involving this
material.
HAZARDOUS COMBUSTION PRODUCTS:
When heated to decomposition, ammonia, oxides of carbon and nitrogen, cyanides and harmful
organic fumes are released.
EXPLOSION HAZARDS:
Vapors may form explosive mixture with air.
FIRE FIGHTING PROCEDURES:
Use water fog to cool hot containers.
FIRE FIGHTING EQUIPMENT:
As in any 炉re, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH ap-
proved or equivalent) and full protective clothing to prevent contact with skin and eyes.
Page: 3
DATE PREPARED: 11/01/1999
MSDS No: A401
Cronox 230 Corrosion Inhibitor
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
Contain with dikes.
Use explosion proof equipment to recover.
Remove all sources of ignition.
Soak up residual on inert absorbant (dry sand, vermiculite or earth).
Put in steel or plastic drum approved for 掳ammables.
7. HANDLING AND STORAGE
GENERAL PROCEDURES:
Refer to Section 8.
STORAGE:
Keep away from heat, sparks, and 掳ame.
Keep container closed when not in use.
Use with adequate ventilation.
Store away from oxidizers.
Do not cut or weld on container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Ventilation - General and local ventilation are required.
PERSONAL PROTECTION
EYES AND FACE:
Chemical goggles required and an eye wash in work area.
RESPIRATORY:
Use NIOSH approved respirator with organic vapor/acid gas protection (color coded yellow) in
nonventilated area and/or exposure above TLV. Use SCBA (self-contained breathing apparatus)
in con炉ned areas and for emergencies.
PROTECTIVE CLOTHING:
Face shield, boots, protective suit and impervious (neoprene) gloves.
OTHER USE PRECAUTIONS:
Safety shower and eye wash in the work area.
Page: 4
DATE PREPARED: 11/01/1999
MSDS No: A401
Cronox 230 Corrosion Inhibitor
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Pleasant
Color: Dark
pH: 7.0
Percent Volatile: Not Determined
Vapor Pressure: Not Determined
Vapor Density: Not Determined
Boiling Point: Not Determined
Freezing Point: 0卤 F
Solubility in Water: Completely Miscible in All Proportions
Speci炉c Gravity: 0.971 at 60卤 F
COMMENTS:
pH: pH listed above is for a 5% solution
10. STABILITY AND REACTIVITY
STABLE: Yes
HAZARDOUS POLYMERIZATION: No
CONDITIONS TO AVOID:
Keep away from heat, sparks and 掳ame.
HAZARDOUS DECOMPOSITION:
When heated to decomposition, ammonia, oxides of carbon and nitrogen, cyanides and harmful
organic fumes are released.
INCOMPATIBLE MATERIALS:
Oxidizing materials.
11. TOXICOLOGICAL INFORMATION
ACUTE
Eyes: Irritant. May cause pain, redness, discomfort.
Skin: Irritant. May cause pain, redness, dermatitis. Not likely to be absorbed in toxic amounts.
Ingestion: Harmful if swallowed. Large amounts may cause illness or death.
Inhalation: Irritant. May cause pain and coughing.
TARGET ORGANS:
Skin, Eyes Liver, Kidneys, Centeral nervous system,
Page: 5
DATE PREPARED: 11/01/1999
MSDS No: A401
Cronox 230 Corrosion Inhibitor
COMMENTS:
Only selected Registry of Toxic E庐ects of Chemical Substances (RTECS) data is presented in this
document. See the actual entry in RTECS for complete information.
RTECS Number:
NT8050000 (isopropyl alcohol)
UK5075000 (propargyl alcohol)
KW297000 (ethylene glycol)
QJ0525000 (naphthalene)
12. ECOLOGICAL INFORMATION
GENERAL COMMENTS:
No environmental data for this material are currently available.
13. DISPOSAL CONSIDERATIONS
PRODUCT DISPOSAL:
Ship via permitted waste hauler to permitted hazardous waste disposal facility for incineration.
EMPTY CONTAINER:
Leave label on drum and sell drum to an approved drum reconditioner or triple rinse with an
appropriate solvent, crush, and ship to sanitary land炉ll unless prohibited by local regulations.
RCRA/USEPA WASTE INFORMATION:
RCRA Hazardous Waste Number: P102 (propargyl alcohol)
COMMENTS:
Always follow ALL applicable federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shipping Name: Alcohols, N.O.S.
Combustible Class: Yes
Hazard Class: 3
NA/UN Number: UN1987
Packing Group: III
Reportable Quantity (RQ) Under CERCLA: 412 gal
Placards: Flammable Liquid
Label: None
Page: 6
DATE PREPARED: 11/01/1999
MSDS No: A401
Cronox 230 Corrosion Inhibitor
SPECIAL SHIPPING NOTES:
This material is reclassi炉ed as a COMBUSTIBLE LIQUID and is not regulated by 49 CFR when
in package sizes of 119 gallons or less, a single container holds less than the RQ amount and when
transported soley by ground.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
Fire: Yes Pressure Generating: No Reactivity: No Acute: Yes Chronic: No
313 Reportable Ingredients:
Ethylene Glycol (<17%)
Propargyl Alcohol (17%)
Isopropanol (<5%)
Naphthalene (<3%)
Title III Notes: This product contains substances which are de炉ned as toxic chemicals under
the reporting requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (40 CFR Part 372).
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
Reportable Spill Quantity: 412 gal
EPA
EPA RQ Ingredient:
Naphthlene, Ethylene Glycol, Propagryl Alcohol
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA Status: All components of this material are on the TSCA inventory.
16. OTHER INFORMATION
Approved by: Charles M. Maddin, PhD. FAIC
Approval date: 11/01/1999
REVISION SUMMARY
Revision #: 11
This MSDS replaces the November 01, 1999 MSDS. Any changes in information are as follows:
In Section 14
Proper Shipping Name DOT Hazard Class UN/NA Number Placards Special Shipping Notes
Page: 7
DATE PREPARED: 11/01/1999
MSDS No: A401
Cronox 230 Corrosion Inhibitor
NFPA CODES
Fire: 2 Health: 2 Reactivity: 0
HMIS CODES
Fire: 2 Health: 2 Reactivity: 0
MANUFACTURER DISCLAIMER:
[TM ] Indicates a trade or service mark of HydroChem Industrial Services, Inc.
The information herein is believed to be accurate and is presented in good faith; however, no
warranties or representations are made by HydroChem Industrial Services, Inc. regarding the
accuracy or completeness of the information.
HydroChem Industrial Services, Inc. shall not be held liable for any damage resulting from the
handling, or from contact with the above product.
|